Organic electroluminescent materials and devices

ABSTRACT

Provided is an Ir compound including a ligand LA ofwherein the variables are defined herein.

CROSS-REFERENCE TO RELATED APPLICATIONS

This application claims priority under 35 U.S.C. § 119(e) to U.S.Provisional Application No. 62/958,370, filed on Jan. 8, 2020, theentire contents of which are incorporated herein by reference.

FIELD

The present disclosure generally relates to organoiridium compounds andformulations and their various uses including as emitters in devicessuch as organic light emitting diodes and related electronic devices.

BACKGROUND

Opto-electronic devices that make use of organic materials are becomingincreasingly desirable for various reasons. Many of the materials usedto make such devices are relatively inexpensive, so organicopto-electronic devices have the potential for cost advantages overinorganic devices. In addition, the inherent properties of organicmaterials, such as their flexibility, may make them well suited forparticular applications such as fabrication on a flexible substrate.Examples of organic opto-electronic devices include organic lightemitting diodes/devices (OLEDs), organic phototransistors, organicphotovoltaic cells, and organic photodetectors. For OLEDs, the organicmaterials may have performance advantages over conventional materials.

OLEDs make use of thin organic films that emit light when voltage isapplied across the device. OLEDs are becoming an increasinglyinteresting technology for use in applications such as flat paneldisplays, illumination, and backlighting.

One application for phosphorescent emissive molecules is a full colordisplay. Industry standards for such a display call for pixels adaptedto emit particular colors, referred to as “saturated” colors. Inparticular, these standards call for saturated red, green, and bluepixels. Alternatively, the OLED can be designed to emit white light. Inconventional liquid crystal displays emission from a white backlight isfiltered using absorption filters to produce red, green and blueemission. The same technique can also be used with OLEDs. The white OLEDcan be either a single emissive layer (EML) device or a stack structure.Color may be measured using CIE coordinates, which are well known to theart.

SUMMARY

A series of novel Ir(III) phosphors are disclosed. In one aspect, thepresent disclosure provides an Ir compound comprising a ligand L_(A) of

In Formula I, X¹-X¹⁰ are each independently CR′ or N; the maximum numberof N atoms that can connect to each other within a ring is two; R′ foreach occurrence is independently a hydrogen or a substituent selectedfrom the group consisting of the general substituents defined herein; atleast two adjacent R′ substituents are joined to form a fused 5-memberedcarbocyclic or heterocyclic ring; and additional substituents can bejoined or fused to form a ring, wherein Ir is coordinated to the ligandL_(A) of Formula I by the two dashed lines, and can be coordinated toadditional ligands; and wherein the ligand L_(A) can be joined withadditional ligands to form a tridentate, tetradentate, pentadentate, orhexadentate ligand.

In another aspect, the present disclosure provides a formulation of anIr compound comprising a ligand L_(A) of Formula I as described herein.

In yet another aspect, the present disclosure provides an OLED having anorganic layer comprising an Ir compound comprising a ligand L_(A) ofFormula I as described herein.

In yet another aspect, the present disclosure provides a consumerproduct comprising an OLED with an organic layer comprising an Ircompound comprising a ligand L_(A) of Formula I as described herein.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 shows an organic light emitting device.

FIG. 2 shows an inverted organic light emitting device that does nothave a separate electron transport layer.

DETAILED DESCRIPTION A. Terminology

Unless otherwise specified, the below terms used herein are defined asfollows:

As used herein, the term “organic” includes polymeric materials as wellas small molecule organic materials that may be used to fabricateorganic opto-electronic devices. “Small molecule” refers to any organicmaterial that is not a polymer, and “small molecules” may actually bequite large. Small molecules may include repeat units in somecircumstances. For example, using a long chain alkyl group as asubstituent does not remove a molecule from the “small molecule” class.Small molecules may also be incorporated into polymers, for example as apendent group on a polymer backbone or as a part of the backbone. Smallmolecules may also serve as the core moiety of a dendrimer, whichconsists of a series of chemical shells built on the core moiety. Thecore moiety of a dendrimer may be a fluorescent or phosphorescent smallmolecule emitter. A dendrimer may be a “small molecule,” and it isbelieved that all dendrimers currently used in the field of OLEDs aresmall molecules.

As used herein, “top” means furthest away from the substrate, while“bottom” means closest to the substrate. Where a first layer isdescribed as “disposed over” a second layer, the first layer is disposedfurther away from substrate. There may be other layers between the firstand second layer, unless it is specified that the first layer is “incontact with” the second layer. For example, a cathode may be describedas “disposed over” an anode, even though there are various organiclayers in between.

As used herein, “solution processable” means capable of being dissolved,dispersed, or transported in and/or deposited from a liquid medium,either in solution or suspension form.

A ligand may be referred to as “photoactive” when it is believed thatthe ligand directly contributes to the photoactive properties of anemissive material. A ligand may be referred to as “ancillary” when it isbelieved that the ligand does not contribute to the photoactiveproperties of an emissive material, although an ancillary ligand mayalter the properties of a photoactive ligand.

As used herein, and as would be generally understood by one skilled inthe art, a first “Highest Occupied Molecular Orbital” (HOMO) or “LowestUnoccupied Molecular Orbital” (LUMO) energy level is “greater than” or“higher than” a second HOMO or LUMO energy level if the first energylevel is closer to the vacuum energy level.

Since ionization potentials (IP) are measured as a negative energyrelative to a vacuum level, a higher HOMO energy level corresponds to anIP having a smaller absolute value (an IP that is less negative).Similarly, a higher LUMO energy level corresponds to an electronaffinity (EA) having a smaller absolute value (an EA that is lessnegative). On a conventional energy level diagram, with the vacuum levelat the top, the LUMO energy level of a material is higher than the HOMOenergy level of the same material. A “higher” HOMO or LUMO energy levelappears closer to the top of such a diagram than a “lower” HOMO or LUMOenergy level.

As used herein, and as would be generally understood by one skilled inthe art, a first work function is “greater than” or “higher than” asecond work function if the first work function has a higher absolutevalue. Because work functions are generally measured as negative numbersrelative to vacuum level, this means that a “higher” work function ismore negative. On a conventional energy level diagram, with the vacuumlevel at the top, a “higher” work function is illustrated as furtheraway from the vacuum level in the downward direction. Thus, thedefinitions of HOMO and LUMO energy levels follow a different conventionthan work functions.

The terms “halo,” “halogen,” and “halide” are used interchangeably andrefer to fluorine, chlorine, bromine, and iodine.

The term “acyl” refers to a substituted carbonyl radical (C(O)—R_(s)).

The term “ester” refers to a substituted oxycarbonyl (—O—C(O)—R_(s) or—C(O)—O—R_(s)) radical.

The term “ether” refers to an —OR_(s) radical.

The terms “sulfanyl” or “thio-ether” are used interchangeably and referto a —SR_(s) radical.

The term “sulfinyl” refers to a —S(O)—R_(s) radical.

The term “sulfonyl” refers to a —SO₂—R_(s) radical.

The term “phosphino” refers to a —P(R_(s))₃ radical, wherein each R_(s)can be same or different.

The term “silyl” refers to a —Si(R_(s))₃ radical, wherein each R_(s) canbe same or different.

The term “boryl” refers to a —B(R_(s))₂ radical or its Lewis adduct—B(R_(s))₃ radical, wherein R_(s) can be same or different.

In each of the above, R_(s) can be hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, andcombination thereof. Preferred R_(s) is selected from the groupconsisting of alkyl, cycloalkyl, aryl, heteroaryl, and combinationthereof.

The term “alkyl” refers to and includes both straight and branched chainalkyl radicals. Preferred alkyl groups are those containing from one tofifteen carbon atoms and includes methyl, ethyl, propyl, 1-methylethyl,butyl, 1-methylpropyl, 2-methylpropyl, pentyl, 1-methylbutyl,2-methylbutyl, 3-methylbutyl, 1,1-dimethylpropyl, 1,2-dimethylpropyl,2,2-dimethylpropyl, and the like. Additionally, the alkyl group may beoptionally substituted.

The term “cycloalkyl” refers to and includes monocyclic, polycyclic, andspiro alkyl radicals. Preferred cycloalkyl groups are those containing 3to 12 ring carbon atoms and includes cyclopropyl, cyclopentyl,cyclohexyl, bicyclo[3.1.1]heptyl, spiro[4.5]decyl, spiro[5.5]undecyl,adamantyl, and the like. Additionally, the cycloalkyl group may beoptionally substituted.

The terms “heteroalkyl” or “heterocycloalkyl” refer to an alkyl or acycloalkyl radical, respectively, having at least one carbon atomreplaced by a heteroatom. Optionally the at least one heteroatom isselected from O, S, N, P, B, Si and Se, preferably, O, S or N.Additionally, the heteroalkyl or heterocycloalkyl group may beoptionally substituted.

The term “alkenyl” refers to and includes both straight and branchedchain alkene radicals. Alkenyl groups are essentially alkyl groups thatinclude at least one carbon-carbon double bond in the alkyl chain.Cycloalkenyl groups are essentially cycloalkyl groups that include atleast one carbon-carbon double bond in the cycloalkyl ring.

The term “heteroalkenyl” as used herein refers to an alkenyl radicalhaving at least one carbon atom replaced by a heteroatom. Optionally theat least one heteroatom is selected from O, S, N, P, B, Si, and Se,preferably, O, S, or N. Preferred alkenyl, cycloalkenyl, orheteroalkenyl groups are those containing two to fifteen carbon atoms.Additionally, the alkenyl, cycloalkenyl, or heteroalkenyl group may beoptionally substituted.

The term “alkynyl” refers to and includes both straight and branchedchain alkyne radicals. Alkynyl groups are essentially alkyl groups thatinclude at least one carbon-carbon triple bond in the alkyl chain.Preferred alkynyl groups are those containing two to fifteen carbonatoms. Additionally, the alkynyl group may be optionally substituted.

The terms “aralkyl” or “arylalkyl” are used interchangeably and refer toan alkyl group that is substituted with an aryl group. Additionally, thearalkyl group may be optionally substituted.

The term “heterocyclic group” refers to and includes aromatic andnon-aromatic cyclic radicals containing at least one heteroatom.Optionally the at least one heteroatom is selected from O, S, N, P, B,Si, and Se, preferably, O, S, or N. Hetero-aromatic cyclic radicals maybe used interchangeably with heteroaryl. Preferred hetero-non-aromaticcyclic groups are those containing 3 to 7 ring atoms which includes atleast one hetero atom, and includes cyclic amines such as morpholino,piperidino, pyrrolidino, and the like, and cyclic ethers/thio-ethers,such as tetrahydrofuran, tetrahydropyran, tetrahydrothiophene, and thelike. Additionally, the heterocyclic group may be optionallysubstituted.

The term “aryl” refers to and includes both single-ring aromatichydrocarbyl groups and polycyclic aromatic ring systems. The polycyclicrings may have two or more rings in which two carbons are common to twoadjoining rings (the rings are “fused”) wherein at least one of therings is an aromatic hydrocarbyl group, e.g., the other rings can becycloalkyls, cycloalkenyls, aryl, heterocycles, and/or heteroaryls.Preferred aryl groups are those containing six to thirty carbon atoms,preferably six to twenty carbon atoms, more preferably six to twelvecarbon atoms. Especially preferred is an aryl group having six carbons,ten carbons or twelve carbons. Suitable aryl groups include phenyl,biphenyl, triphenyl, triphenylene, tetraphenylene, naphthalene,anthracene, phenalene, phenanthrene, fluorene, pyrene, chrysene,perylene, and azulene, preferably phenyl, biphenyl, triphenyl,triphenylene, fluorene, and naphthalene. Additionally, the aryl groupmay be optionally substituted.

The term “heteroaryl” refers to and includes both single-ring aromaticgroups and polycyclic aromatic ring systems that include at least oneheteroatom. The heteroatoms include, but are not limited to O, S, N, P,B, Si, and Se. In many instances, O, S, or N are the preferredheteroatoms. Hetero-single ring aromatic systems are preferably singlerings with 5 or 6 ring atoms, and the ring can have from one to sixheteroatoms. The hetero-polycyclic ring systems can have two or morerings in which two atoms are common to two adjoining rings (the ringsare “fused”) wherein at least one of the rings is a heteroaryl, e.g.,the other rings can be cycloalkyls, cycloalkenyls, aryl, heterocycles,and/or heteroaryls. The hetero-polycyclic aromatic ring systems can havefrom one to six heteroatoms per ring of the polycyclic aromatic ringsystem. Preferred heteroaryl groups are those containing three to thirtycarbon atoms, preferably three to twenty carbon atoms, more preferablythree to twelve carbon atoms. Suitable heteroaryl groups includedibenzothiophene, dibenzofuran, dibenzoselenophene, furan, thiophene,benzofuran, benzothiophene, benzoselenophene, carbazole,indolocarbazole, pyridylindole, pyrrolodipyridine, pyrazole, imidazole,triazole, oxazole, thiazole, oxadiazole, oxatriazole, dioxazole,thiadiazole, pyridine, pyridazine, pyrimidine, pyrazine, triazine,oxazine, oxathiazine, oxadiazine, indole, benzimidazole, indazole,indoxazine, benzoxazole, benzisoxazole, benzothiazole, quinoline,isoquinoline, cinnoline, quinazoline, quinoxaline, naphthyridine,phthalazine, pteridine, xanthene, acridine, phenazine, phenothiazine,phenoxazine, benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine,preferably dibenzothiophene, dibenzofuran, dibenzoselenophene,carbazole, indolocarbazole, imidazole, pyridine, triazine,benzimidazole, 1,2-azaborine, 1,3-azaborine, 1,4-azaborine, borazine,and aza-analogs thereof. Additionally, the heteroaryl group may beoptionally substituted.

Of the aryl and heteroaryl groups listed above, the groups oftriphenylene, naphthalene, anthracene, dibenzothiophene, dibenzofuran,dibenzoselenophene, carbazole, indolocarbazole, imidazole, pyridine,pyrazine, pyrimidine, triazine, and benzimidazole, and the respectiveaza-analogs of each thereof are of particular interest.

The terms alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aralkyl, heterocyclic group, aryl,and heteroaryl, as used herein, are independently unsubstituted, orindependently substituted, with one or more general substituents.

In many instances, the general substituents are selected from the groupconsisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl,heteroalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, andcombinations thereof.

In some instances, the preferred general substituents are selected fromthe group consisting of deuterium, fluorine, alkyl, cycloalkyl, alkoxy,aryloxy, amino, silyl, aryl, heteroaryl, sulfanyl, and combinationsthereof.

In yet other instances, the more preferred general substituents areselected from the group consisting of deuterium, fluorine, alkyl,cycloalkyl, aryl, heteroaryl, and combinations thereof.

The terms “substituted” and “substitution” refer to a substituent otherthan H that is bonded to the relevant position, e.g., a carbon ornitrogen. For example, when R¹ represents mono-substitution, then one R¹must be other than H (i.e., a substitution). Similarly, when R¹represents di-substitution, then two of R¹ must be other than H.Similarly, when R¹ represents zero or no substitution, R, for example,can be a hydrogen for available valencies of ring atoms, as in carbonatoms for benzene and the nitrogen atom in pyrrole, or simply representsnothing for ring atoms with fully filled valencies, e.g., the nitrogenatom in pyridine. The maximum number of substitutions possible in a ringstructure will depend on the total number of available valencies in thering atoms.

As used herein, “combinations thereof” indicates that one or moremembers of the applicable list are combined to form a known orchemically stable arrangement that one of ordinary skill in the art canenvision from the applicable list. For example, an alkyl and deuteriumcan be combined to form a partial or fully deuterated alkyl group; ahalogen and alkyl can be combined to form a halogenated alkylsubstituent; and a halogen, alkyl, and aryl can be combined to form ahalogenated arylalkyl. In one instance, the term substitution includes acombination of two to four of the listed groups. In another instance,the term substitution includes a combination of two to three groups. Inyet another instance, the term substitution includes a combination oftwo groups. Preferred combinations of substituent groups are those thatcontain up to fifty atoms that are not hydrogen or deuterium, or thosewhich include up to forty atoms that are not hydrogen or deuterium, orthose that include up to thirty atoms that are not hydrogen ordeuterium. In many instances, a preferred combination of substituentgroups will include up to twenty atoms that are not hydrogen ordeuterium.

The “aza” designation in the fragments described herein, i.e.aza-dibenzofuran, aza-dibenzothiophene, etc. means that one or more ofthe C—H groups in the respective aromatic ring can be replaced by anitrogen atom, for example, and without any limitation, azatriphenyleneencompasses both dibenzo[f,h]quinoxaline and dibenzo[f,h]quinoline. Oneof ordinary skill in the art can readily envision other nitrogen analogsof the aza-derivatives described above, and all such analogs areintended to be encompassed by the terms as set forth herein.

As used herein, “deuterium” refers to an isotope of hydrogen. Deuteratedcompounds can be readily prepared using methods known in the art. Forexample, U.S. Pat. No. 8,557,400, Patent Pub. No. WO 2006/095951, andU.S. Pat. Application Pub. No. US 2011/0037057, which are herebyincorporated by reference in their entireties, describe the making ofdeuterium-substituted organometallic complexes. Further reference ismade to Ming Yan, et al., Tetrahedron 2015, 71, 1425-30 and Atzrodt etal., Angew. Chem. Int. Ed. (Reviews) 2007, 46, 7744-65, which areincorporated by reference in their entireties, describe the deuterationof the methylene hydrogens in benzyl amines and efficient pathways toreplace aromatic ring hydrogens with deuterium, respectively.

It is to be understood that when a molecular fragment is described asbeing a substituent or otherwise attached to another moiety, its namemay be written as if it were a fragment (e.g. phenyl, phenylene,naphthyl, dibenzofuryl) or as if it were the whole molecule (e.g.benzene, naphthalene, dibenzofuran). As used herein, these differentways of designating a substituent or attached fragment are considered tobe equivalent.

In some instance, a pair of adjacent substituents can be optionallyjoined or fused into a ring. The preferred ring is a five, six, orseven-membered carbocyclic or heterocyclic ring, includes both instanceswhere the portion of the ring formed by the pair of substituents issaturated and where the portion of the ring formed by the pair ofsubstituents is unsaturated. As used herein, “adjacent” means that thetwo substituents involved can be on the same ring next to each other, oron two neighboring rings having the two closest available substitutablepositions, such as 2,2′ positions in a biphenyl, or 1,8 position in anaphthalene, as long as they can form a stable fused ring system.

B. The Compounds of the Present Disclosure

In one aspect, the present disclosure provides an Ir compound comprisinga ligand L_(A) of

wherein: X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of the general substituents defined herein; atleast two adjacent R′ substituents are joined to form a fused 5-memberedcarbocyclic or heterocyclic ring; and additional substituents can bejoined or fused to form a ring, wherein Ir is coordinated to the ligandL_(A) of Formula I by the two dash lines, and can be coordinated toadditional ligands; and wherein the ligand L_(A) can be joined withadditional ligands to form a tridentate, tetradentate, pentadentate, orhexadentate ligand.

In some embodiments, R′ for each occurrence can be independently ahydrogen or a substituent selected from the group consisting of thepreferred general substituents defined herein.

In some embodiments, the at least two adjacent R′ substituents can bejoined to form a fused 5-membered heterocyclic ring. In someembodiments, the at least two adjacent R′ substituents can be joined toform a fused 5-membered heterocyclic aromatic ring.

In some embodiments, X⁵ and X⁶ can both be both CR′. In theseembodiments, the two R′ substituents can be joined to form a 5-memberedheterocyclic ring fused to ring B. In these embodiments, the two R′substituents can be joined to form a 5-membered carbocyclic ring fusedto ring B. In these embodiments, the 5-membered carbocyclic orheterocyclic ring can be further fused to form an extended fused ring.In these embodiments, the extended fused ring can be a 6-memberedaromatic ring. In these embodiments, the extended fused ring can befurther fused to form an additional ring.

In some embodiments, X⁴ and X⁵ can both be CR′. In these embodiments,the two R′ substituents can be joined to form a 5-membered heterocyclicring fused to ring B. In these embodiments, the two R′ substituents canbe joined to form a 5-membered carbocyclic ring fused to ring B. Inthese embodiments, the 5-membered carbocyclic or heterocyclic ring canbe further fused to form an extended fused ring. In these embodiments,the extended fused ring can be a 6-membered aromatic ring. In theseembodiments, the extended fused ring can be further fused to form anadditional ring.

In some embodiments, X⁶ and X⁷ can both be CR′. In these embodiments,the two R′ substituents can be joined to form a 5-membered heterocyclicring fused to ring B. In these embodiments, the two R′ substituents canbe joined to form a 5-membered carbocyclic ring fused to ring B. Inthese embodiments, the 5-membered carbocyclic or heterocyclic ring canbe further fused to form an extended fused ring. In these embodiments,the extended fused ring can be a 6-membered aromatic ring. In theseembodiments, the extended fused ring can be further fused to form anadditional ring.

In some embodiments, X⁸ and X⁹ can both be CR′. In these embodiments,the two R′ substituents can be joined to form a 5-membered heterocyclicring fused to ring C. In these embodiments, the two R′ substituents canbe joined to form a 5-membered carbocyclic ring fused to ring B. Inthese embodiments, the 5-membered carbocyclic or heterocyclic ring canbe further fused to form an extended fused ring. In these embodiments,the extended fused ring can be a 6-membered aromatic ring. In theseembodiments, the extended fused ring can be further fused to form anadditional ring.

In some of the above embodiments, the fused 5-membered carbocyclic orheterocyclic ring can have a structure of

wherein Y can be selected from the group consisting of O, S, Se, NR″,CR″R′″, and SiR′R′″; R^(D), R″, and R′″ can each be independently ahydrogen or a substituent selected from the group consisting of thegeneral substituents defined herein; R^(D) can represent zero, mono, orup to the maximum allowed number of substitutions to ring D; and twoR^(D) can be joined to form a fused ring.

In some of the above embodiments, R^(D) for each occurrence can beindependently a hydrogen or a substituent selected from the groupconsisting of deuterium, fluorine, alkyl, cycloalkyl, heteroalkyl,alkoxy, aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl,heteroalkenyl, aryl, heteroaryl, nitrile, isonitrile, sulfanyl, andcombinations thereof. In some of the embodiments, Y can be O or S.

In some embodiments, X¹-X¹⁰ can each be C. In some embodiments, X² ofX¹-X¹⁰ can be N, and the remainder can all be C. In some embodiments, X³of X¹-X¹⁰ can be N, and the remainder can all be C.

In some embodiments, the compound can further comprise twophenylpyridine ligands, which are independently substituted orunsubstituted.

In some embodiments, the ligand L_(A) of Formula I can be selected fromthe group consisting of:

wherein X¹¹-X¹³ are each independently CR′ or N; R^(A), R^(B), R^(C),and R^(D) are each independently a hydrogen or a substituent selectedfrom the group consisting of the general substituents defined herein;Q¹, and Q² are each independently selected from the group consisting ofBR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂, CR_(e)R_(f),SiR_(e)R_(f), and GeR_(e)R_(f); wherein R_(e) and R_(f) can be fused orjoined to form a ring; each of R_(e) and R_(f) is independently hydrogenor a substituent selected from the group consisting of the generalsubstituents defined herein; and X¹-X¹⁰ are all defined the same aspreviously.

In some embodiments, the ligand L_(A) of Formula I can be selected fromthe group consisting of L_(A1-1) to L_(A1116-48) with the generalnumbering scheme L_(Ah-m), wherein h is an integer from 1 to 1116, m isan integer from 1 to 48, and the structure of each ligand L_(Ah-m) isdefined in LIST 1 below:

wherein for each L_(Ah) in L_(Ah-m), R^(X), R^(Y) and R^(Z) areindependently defined in LIST 2 below:

L_(Ah) R^(X) R^(Y) R^(Z) L_(A1) R¹ R¹ R¹ L_(A2) R² R² R¹ L_(A3) R³ R³ R¹L_(A4) R⁴ R⁴ R¹ L_(A5) R⁵ R⁵ R¹ L_(A6) R⁶ R⁶ R¹ L_(A7) R⁷ R⁷ R¹ L_(A8)R⁸ R⁸ R¹ L_(A9) R⁹ R⁹ R¹ L_(A10) R¹⁰ R¹⁰ R¹ L_(A11) R¹¹ R¹¹ R¹ L_(A12)R¹² R¹² R¹ L_(A13) R¹³ R¹³ R¹ L_(A14) R¹⁴ R¹⁴ R¹ L_(A15) R¹⁵ R¹⁵ R¹L_(A16) R¹⁶ R¹⁶ R¹ L_(A17) R¹⁷ R¹⁷ R¹ L_(A18) R¹⁸ R¹⁸ R¹ L_(A19) R¹⁹ R¹⁹R¹ L_(A20) R²⁰ R²⁰ R¹ L_(A21) R²¹ R²¹ R¹ L_(A22) R²² R²² R¹ L_(A23) R²³R²³ R¹ L_(A24) R²⁴ R²⁴ R¹ L_(A25) R²⁵ R²⁵ R¹ L_(A26) R²⁶ R²⁶ R¹ L_(A27)R²⁷ R²⁷ R¹ L_(A28) R²⁸ R²⁸ R¹ L_(A29) R²⁹ R²⁹ R¹ L_(A30) R³⁰ R³⁰ R¹L_(A31) R³¹ R³¹ R¹ L_(A32) R³² R³² R¹ L_(A33) R³³ R³³ R¹ L_(A34) R³⁴ R³⁴R¹ L_(A35) R³⁵ R³⁵ R¹ L_(A36) R³⁶ R³⁶ R¹ L_(A37) R³⁷ R³⁷ R¹ L_(A38) R³⁸R³⁸ R¹ L_(A39) R³⁹ R³⁹ R¹ L_(A40) R⁴⁰ R⁴⁰ R¹ L_(A41) R⁴¹ R⁴¹ R¹ L_(A42)R⁴² R⁴² R¹ L_(A43) R⁴³ R⁴³ R¹ L_(A44) R⁴⁴ R⁴⁴ R¹ L_(A45) R⁴⁵ R⁴⁵ R¹L_(A46) R⁴⁶ R⁴⁶ R¹ L_(A47) R⁴⁷ R⁴⁷ R¹ L_(A48) R⁴⁸ R⁴⁸ R¹ L_(A49) R⁴⁹ R⁴⁹R¹ L_(A50) R⁵⁰ R⁵⁰ R¹ L_(A51) R⁵¹ R⁵¹ R¹ L_(A52) R⁵² R⁵² R¹ L_(A53) R⁵³R⁵³ R¹ L_(A54) R⁵⁴ R⁵⁴ R¹ L_(A55) R² R¹ R¹ L_(A56) R³ R¹ R¹ L_(A57) R⁴R¹ R¹ L_(A58) R⁵ R¹ R¹ L_(A59) R⁶ R¹ R¹ L_(A60) R⁷ R¹ R¹ L_(A61) R⁸ R¹R¹ L_(A62) R⁹ R¹ R¹ L_(A63) R¹⁰ R¹ R¹ L_(A64) R¹¹ R¹ R¹ L_(A65) R¹² R¹R¹ L_(A66) R¹³ R¹ R¹ L_(A67) R¹⁴ R¹ R¹ L_(A68) R¹⁵ R¹ R¹ L_(A69) R¹⁶ R¹R¹ L_(A70) R¹⁷ R¹ R¹ L_(A71) R¹⁸ R¹ R¹ L_(A72) R¹⁹ R¹ R¹ L_(A73) R²⁰ R¹R¹ L_(A74) R²¹ R¹ R¹ L_(A75) R²² R¹ R¹ L_(A76) R²³ R¹ R¹ L_(A77) R²⁴ R¹R¹ L_(A78) R²⁵ R¹ R¹ L_(A79) R²⁶ R¹ R¹ L_(A80) R²⁷ R¹ R¹ L_(A81) R²⁸ R¹R¹ L_(A82) R²⁹ R¹ R¹ L_(A83) R³⁰ R¹ R¹ L_(A84) R³¹ R¹ R¹ L_(A85) R³² R¹R¹ L_(A86) R³³ R¹ R¹ L_(A87) R³⁴ R¹ R¹ L_(A88) R³⁵ R¹ R¹ L_(A89) R³⁶ R¹R¹ L_(A90) R³⁷ R¹ R¹ L_(A91) R³⁸ R¹ R¹ L_(A92) R³⁹ R¹ R¹ L_(A93) R⁴⁰ R¹R¹ L_(A94) R⁴¹ R¹ R¹ L_(A95) R⁴² R¹ R¹ L_(A96) R⁴³ R¹ R¹ L_(A97) R⁴⁴ R¹R¹ L_(A98) R⁴⁵ R¹ R¹ L_(A99) R⁴⁶ R¹ R¹ L_(A100) R⁴⁷ R¹ R¹ L_(A101) R⁴⁸R¹ R¹ L_(A102) R⁴⁹ R¹ R¹ L_(A103) R⁵⁰ R¹ R¹ L_(A104) R⁵¹ R¹ R¹ L_(A105)R⁵² R¹ R¹ L_(A106) R⁵³ R¹ R¹ L_(A107) R⁵⁴ R¹ R¹ L_(A108) R¹ R³² R¹L_(A109) R² R³² R¹ L_(A110) R³ R³² R¹ L_(A111) R⁴ R³² R¹ L_(A112) R⁵ R³²R¹ L_(A113) R⁶ R³² R¹ L_(A114) R⁷ R³² R¹ L_(A115) R⁸ R³² R¹ L_(A116) R⁹R³² R¹ L_(A117) R¹⁰ R³² R¹ L_(A118) R¹¹ R³² R¹ L_(A119) R¹² R³² R¹L_(A120) R¹³ R³² R¹ L_(A121) R¹⁴ R³² R¹ L_(A122) R¹⁵ R³² R¹ L_(A123) R¹⁶R³² R¹ L_(A124) R¹⁷ R³² R¹ L_(A125) R¹⁸ R³² R¹ L_(A126) R¹⁹ R³² R¹L_(A127) R²⁰ R³² R¹ L_(A128) R²¹ R³² R¹ L_(A129) R²² R³² R¹ L_(A130) R²³R³² R¹ L_(A131) R²⁴ R³² R¹ L_(A132) R²⁵ R³² R¹ L_(A133) R²⁶ R³² R¹L_(A134) R²⁷ R³² R¹ L_(A135) R²⁸ R³² R¹ L_(A136) R²⁹ R³² R¹ L_(A137) R³⁰R³² R¹ L_(A138) R³¹ R³² R¹ L_(A139) R³³ R³² R¹ L_(A140) R³⁴ R³² R¹L_(A141) R³⁵ R³² R¹ L_(A142) R³⁶ R³² R¹ L_(A143) R³⁷ R³² R¹ L_(A144) R³⁸R³² R¹ L_(A145) R³⁹ R³² R¹ L_(A146) R⁴⁰ R³² R¹ L_(A147) R⁴¹ R³² R¹L_(A148) R⁴² R³² R¹ L_(A149) R⁴³ R³² R¹ L_(A150) R⁴⁴ R³² R¹ L_(A151) R⁴⁵R³² R¹ L_(A152) R⁴⁶ R³² R¹ L_(A153) R⁴⁷ R³² R¹ L_(A154) R⁴⁸ R³² R¹L_(A155) R⁴⁹ R³² R¹ L_(A156) R⁵⁰ R³² R¹ L_(A157) R⁵¹ R³² R¹ L_(A158) R⁵²R³² R¹ L_(A159) R⁵³ R³² R¹ L_(A160) R⁵⁴ R³² R¹ L_(A161) R¹ R³⁶ R¹L_(A162) R² R³⁶ R¹ L_(A163) R³ R³⁶ R¹ L_(A164) R⁴ R³⁶ R¹ L_(A165) R⁵ R³⁶R¹ L_(A166) R⁶ R³⁶ R¹ L_(A167) R⁷ R³⁶ R¹ L_(A168) R⁸ R³⁶ R¹ L_(A169) R⁹R³⁶ R¹ L_(A170) R¹⁰ R³⁶ R¹ L_(A171) R¹¹ R³⁶ R¹ L_(A172) R¹² R³⁶ R¹L_(A173) R¹³ R³⁶ R¹ L_(A174) R¹⁴ R³⁶ R¹ L_(A175) R¹⁵ R³⁶ R¹ L_(A176) R¹⁶R³⁶ R¹ L_(A177) R¹⁷ R³⁶ R¹ L_(A178) R¹⁸ R³⁶ R¹ L_(A179) R¹⁹ R³⁶ R¹L_(A180) R²⁰ R³⁶ R¹ L_(A181) R²¹ R³⁶ R¹ L_(A182) R²² R³⁶ R¹ L_(A183) R²³R³⁶ R¹ L_(A184) R²⁴ R³⁶ R¹ L_(A185) R²⁵ R³⁶ R¹ L_(A186) R²⁶ R³⁶ R¹L_(A187) R²⁷ R³⁶ R¹ L_(A188) R²⁸ R³⁶ R¹ L_(A189) R²⁹ R³⁶ R¹ L_(A190) R³⁰R³⁶ R¹ L_(A191) R³¹ R³⁶ R¹ L_(A192) R³² R³⁶ R¹ L_(A193) R³³ R³⁶ R¹L_(A194) R³⁴ R³⁶ R¹ L_(A195) R³⁵ R³⁶ R¹ L_(A196) R³⁷ R³⁶ R¹ L_(A197) R³⁸R³⁶ R¹ L_(A198) R³⁹ R³⁶ R¹ L_(A199) R⁴⁰ R³⁶ R¹ L_(A200) R⁴¹ R³⁶ R¹L_(A201) R⁴² R³⁶ R¹ L_(A202) R⁴³ R³⁶ R¹ L_(A203) R⁴⁴ R³⁶ R¹ L_(A204) R⁴⁵R³⁶ R¹ L_(A205) R⁴⁶ R³⁶ R¹ L_(A206) R⁴⁷ R³⁶ R¹ L_(A207) R⁴⁸ R³⁶ R¹L_(A208) R⁴⁹ R³⁶ R¹ L_(A209) R⁵⁰ R³⁶ R¹ L_(A210) R⁵¹ R³⁶ R¹ L_(A211) R⁵²R³⁶ R¹ L_(A212) R⁵³ R³⁶ R¹ L_(A213) R⁵⁴ R³⁶ R¹ L_(A214) R¹ R² R¹L_(A215) R¹ R³ R¹ L_(A216) R¹ R⁴ R¹ L_(A217) R¹ R⁵ R¹ L_(A218) R¹ R⁶ R¹L_(A219) R¹ R⁷ R¹ L_(A220) R¹ R⁸ R¹ L_(A221) R¹ R⁹ R¹ L_(A222) R¹ R¹⁰ R¹L_(A223) R¹ R¹¹ R¹ L_(A224) R¹ R¹² R¹ L_(A225) R¹ R¹³ R¹ L_(A226) R¹ R¹⁴R¹ L_(A227) R¹ R¹⁵ R¹ L_(A228) R¹ R¹⁶ R¹ L_(A229) R¹ R¹⁷ R¹ L_(A230) R¹R¹⁸ R¹ L_(A231) R¹ R¹⁹ R¹ L_(A232) R¹ R²⁰ R¹ L_(A233) R¹ R²¹ R¹ L_(A234)R¹ R²² R¹ L_(A235) R¹ R²³ R¹ L_(A236) R¹ R²⁴ R¹ L_(A237) R¹ R²⁵ R¹L_(A238) R¹ R²⁶ R¹ L_(A239) R¹ R²⁷ R¹ L_(A240) R¹ R²⁸ R¹ L_(A241) R¹ R²⁹R¹ L_(A242) R¹ R³⁰ R¹ L_(A243) R¹ R³¹ R¹ L_(A244) R¹ R³² R¹ L_(A245) R¹R³³ R¹ L_(A246) R¹ R³⁴ R¹ L_(A247) R¹ R³⁵ R¹ L_(A248) R¹ R³⁶ R¹ L_(A249)R¹ R³⁷ R¹ L_(A250) R¹ R³⁸ R¹ L_(A251) R¹ R³⁹ R¹ L_(A252) R¹ R⁴⁰ R¹L_(A253) R¹ R⁴¹ R¹ L_(A254) R¹ R⁴² R¹ L_(A255) R¹ R⁴³ R¹ L_(A256) R¹ R⁴⁴R¹ L_(A257) R¹ R⁴⁵ R¹ L_(A258) R¹ R⁴⁶ R¹ L_(A259) R¹ R⁴⁷ R¹ L_(A260) R¹R⁴⁸ R¹ L_(A261) R¹ R⁴⁹ R¹ L_(A262) R¹ R⁵⁰ R¹ L_(A263) R¹ R⁵¹ R¹ L_(A264)R¹ R⁵² R¹ L_(A265) R¹ R⁵³ R¹ L_(A266) R¹ R⁵⁴ R¹ L_(A267) R³² R¹ R¹L_(A268) R³² R² R¹ L_(A269) R³² R³ R¹ L_(A270) R³² R⁴ R¹ L_(A271) R³² R⁵R¹ L_(A272) R³² R⁶ R¹ L_(A273) R³² R⁷ R¹ L_(A274) R³² R⁸ R¹ L_(A275) R³²R⁹ R¹ L_(A276) R³² R¹⁰ R¹ L_(A277) R³² R¹¹ R¹ L_(A278) R³² R¹² R¹L_(A279) R³² R¹³ R¹ L_(A280) R³² R¹⁴ R¹ L_(A281) R³² R¹⁵ R¹ L_(A282) R³²R¹⁶ R¹ L_(A283) R³² R¹⁷ R¹ L_(A284) R³² R¹⁸ R¹ L_(A285) R³² R¹⁹ R¹L_(A286) R³² R²⁰ R¹ L_(A287) R³² R²¹ R¹ L_(A288) R³² R²² R¹ L_(A289) R³²R²³ R¹ L_(A290) R³² R²⁴ R¹ L_(A291) R³² R²⁵ R¹ L_(A292) R³² R²⁶ R¹L_(A293) R³² R²⁷ R¹ L_(A294) R³² R²⁸ R¹ L_(A295) R³² R²⁹ R¹ L_(A296) R³²R³⁰ R¹ L_(A297) R³² R³¹ R¹ L_(A298) R³² R³³ R¹ L_(A299) R³² R³⁴ R¹L_(A300) R³² R³⁵ R¹ L_(A301) R³² R³⁶ R¹ L_(A302) R³² R³⁷ R¹ L_(A303) R³²R³⁸ R¹ L_(A304) R³² R³⁹ R¹ L_(A305) R³² R⁴⁰ R¹ L_(A306) R³² R⁴¹ R¹L_(A307) R³² R⁴² R¹ L_(A308) R³² R⁴³ R¹ L_(A309) R³² R⁴⁴ R¹ L_(A310) R³²R⁴⁵ R¹ L_(A311) R³² R⁴⁶ R¹ L_(A312) R³² R⁴⁷ R¹ L_(A313) R³² R⁴⁸ R¹L_(A314) R³² R⁴⁹ R¹ L_(A315) R³² R⁵⁰ R¹ L_(A316) R³² R⁵¹ R¹ L_(A317) R³²R⁵² R¹ L_(A318) R³² R⁵³ R¹ L_(A319) R³² R⁵⁴ R¹ L_(A320) R³⁶ R¹ R¹L_(A321) R³⁶ R² R¹ L_(A322) R³⁶ R³ R¹ L_(A323) R³⁶ R⁴ R¹ L_(A324) R³⁶ R⁵R¹ L_(A325) R³⁶ R⁶ R¹ L_(A326) R³⁶ R⁷ R¹ L_(A327) R³⁶ R⁸ R¹ L_(A328) R³⁶R⁹ R¹ L_(A329) R³⁶ R¹⁰ R¹ L_(A330) R³⁶ R¹¹ R¹ L_(A331) R³⁶ R¹² R¹L_(A332) R³⁶ R¹³ R¹ L_(A333) R³⁶ R¹⁴ R¹ L_(A334) R³⁶ R¹⁵ R¹ L_(A335) R³⁶R¹⁶ R¹ L_(A336) R³⁶ R¹⁷ R¹ L_(A337) R³⁶ R¹⁸ R¹ L_(A338) R³⁶ R¹⁹ R¹L_(A339) R³⁶ R²⁰ R¹ L_(A340) R³⁶ R²¹ R¹ L_(A341) R³⁶ R²² R¹ L_(A342) R³⁶R²³ R¹ L_(A343) R³⁶ R²⁴ R¹ L_(A344) R³⁶ R²⁵ R¹ L_(A345) R³⁶ R²⁶ R¹L_(A346) R³⁶ R²⁷ R¹ L_(A347) R³⁶ R²⁸ R¹ L_(A348) R³⁶ R²⁹ R¹ L_(A349) R³⁶R³⁰ R¹ L_(A350) R³⁶ R³¹ R¹ L_(A351) R³⁶ R³² R¹ L_(A352) R³⁶ R³³ R¹L_(A353) R³⁶ R³⁴ R¹ L_(A354) R³⁶ R³⁵ R¹ L_(A355) R³⁶ R³⁷ R¹ L_(A356) R³⁶R³⁸ R¹ L_(A357) R³⁶ R³⁹ R¹ L_(A358) R³⁶ R⁴⁰ R¹ L_(A359) R³⁶ R⁴¹ R¹L_(A360) R³⁶ R⁴² R¹ L_(A361) R³⁶ R⁴³ R¹ L_(A362) R³⁶ R⁴⁴ R¹ L_(A363) R³⁶R⁴⁵ R¹ L_(A364) R³⁶ R⁴⁶ R¹ L_(A365) R³⁶ R⁴⁷ R¹ L_(A366) R³⁶ R⁴⁸ R¹L_(A367) R³⁶ R⁴⁹ R¹ L_(A368) R³⁶ R⁵⁰ R¹ L_(A369) R³⁶ R⁵¹ R¹ L_(A370) R³⁶R⁵² R¹ L_(A371) R³⁶ R⁵³ R¹ L_(A372) R³⁶ R⁵⁴ R¹ L_(A373) R¹ R¹ R³²L_(A374) R² R² R³² L_(A375) R³ R³ R³² L_(A376) R⁴ R⁴ R³² L_(A377) R⁵ R⁵R³² L_(A378) R⁶ R⁶ R³² L_(A379) R⁷ R⁷ R³² L_(A380) R⁸ R⁸ R³² L_(A381) R⁹R⁹ R³² L_(A382) R¹⁰ R¹⁰ R³² L_(A383) R¹¹ R¹¹ R³² L_(A384) R¹² R¹² R³²L_(A385) R¹³ R¹³ R³² L_(A386) R¹⁴ R¹⁴ R³² L_(A387) R¹⁵ R¹⁵ R³² L_(A388)R¹⁶ R¹⁶ R³² L_(A389) R¹⁷ R¹⁷ R³² L_(A390) R¹⁸ R¹⁸ R³² L_(A391) R¹⁹ R¹⁹R³² L_(A392) R²⁰ R²⁰ R³² L_(A393) R²¹ R²¹ R³² L_(A394) R²² R²² R³²L_(A395) R²³ R²³ R³² L_(A396) R²⁴ R²⁴ R³² L_(A397) R²⁵ R²⁵ R³² L_(A398)R²⁶ R²⁶ R³² L_(A399) R²⁷ R²⁷ R³² L_(A400) R²⁸ R²⁸ R³² L_(A401) R²⁹ R²⁹R³² L_(A402) R³⁰ R³⁰ R³² L_(A403) R³¹ R³¹ R³² L_(A404) R³² R³² R³²L_(A405) R³³ R³³ R³² L_(A406) R³⁴ R³⁴ R³² L_(A407) R³⁵ R³⁵ R³² L_(A408)R³⁶ R³⁶ R³² L_(A409) R³⁷ R³⁷ R³² L_(A410) R³⁸ R³⁸ R³² L_(A411) R³⁹ R³⁹R³² L_(A412) R⁴⁰ R⁴⁰ R³² L_(A413) R⁴¹ R⁴¹ R³² L_(A414) R⁴² R⁴² R³²L_(A415) R⁴³ R⁴³ R³² L_(A416) R⁴⁴ R⁴⁴ R³² L_(A417) R⁴⁵ R⁴⁵ R³² L_(A418)R⁴⁶ R⁴⁶ R³² L_(A419) R⁴⁷ R⁴⁷ R³² L_(A420) R⁴⁸ R⁴⁸ R³² L_(A421) R⁴⁹ R⁴⁹R³² L_(A422) R⁵⁰ R⁵⁰ R³² L_(A423) R⁵¹ R⁵¹ R³² L_(A424) R⁵² R⁵² R³²L_(A425) R⁵³ R⁵³ R³² L_(A426) R⁵⁴ R⁵⁴ R³² L_(A427) R² R¹ R³² L_(A428) R³R¹ R³² L_(A429) R⁴ R¹ R³² L_(A430) R⁵ R¹ R³² L_(A431) R⁶ R¹ R³² L_(A432)R⁷ R¹ R³² L_(A433) R⁸ R¹ R³² L_(A434) R⁹ R¹ R³² L_(A435) R¹⁰ R¹ R³²L_(A436) R¹¹ R¹ R³² L_(A437) R¹² R¹ R³² L_(A438) R¹³ R¹ R³² L_(A439) R¹⁴R¹ R³² L_(A440) R¹⁵ R¹ R³² L_(A441) R¹⁶ R¹ R³² L_(A442) R¹⁷ R¹ R³²L_(A443) R¹⁸ R¹ R³² L_(A444) R¹⁹ R¹ R³² L_(A445) R²⁰ R¹ R³² L_(A446) R²¹R¹ R³² L_(A447) R²² R¹ R³² L_(A448) R²³ R¹ R³² L_(A449) R²⁴ R¹ R³²L_(A450) R²⁵ R¹ R³² L_(A451) R²⁶ R¹ R³² L_(A452) R²⁷ R¹ R³² L_(A453) R²⁸R¹ R³² L_(A454) R²⁹ R¹ R³² L_(A455) R³⁰ R¹ R³² L_(A456) R³¹ R¹ R³²L_(A457) R³² R¹ R³² L_(A458) R³³ R¹ R³² L_(A459) R³⁴ R¹ R³² L_(A460) R³⁵R¹ R³² L_(A461) R³⁶ R¹ R³² L_(A462) R³⁷ R¹ R³² L_(A463) R³⁸ R¹ R³²L_(A464) R³⁹ R¹ R³² L_(A465) R⁴⁰ R¹ R³² L_(A466) R⁴¹ R¹ R³² L_(A467) R⁴²R¹ R³² L_(A468) R⁴³ R¹ R³² L_(A469) R⁴⁴ R¹ R³² L_(A470) R⁴⁵ R¹ R³²L_(A471) R⁴⁶ R¹ R³² L_(A472) R⁴⁷ R¹ R³² L_(A473) R⁴⁸ R¹ R³² L_(A474) R⁴⁹R¹ R³² L_(A475) R⁵⁰ R¹ R³² L_(A476) R⁵¹ R¹ R³² L_(A477) R⁵² R¹ R³²L_(A478) R⁵³ R¹ R³² L_(A479) R⁵⁴ R¹ R³² L_(A480) R¹ R³² R³² L_(A481) R²R³² R³² L_(A482) R³ R³² R³² L_(A483) R⁴ R³² R³² L_(A484) R⁵ R³² R³²L_(A485) R⁶ R³² R³² L_(A486) R⁷ R³² R³² L_(A487) R⁸ R³² R³² L_(A488) R⁹R³² R³² L_(A489) R¹⁰ R³² R³² L_(A490) R¹¹ R³² R³² L_(A491) R¹² R³² R³²L_(A492) R¹³ R³² R³² L_(A493) R¹⁴ R³² R³² L_(A494) R¹⁵ R³² R³² L_(A495)R¹⁶ R³² R³² L_(A496) R¹⁷ R³² R³² L_(A497) R¹⁸ R³² R³² L_(A498) R¹⁹ R³²R³² L_(A499) R²⁰ R³² R³² L_(A500) R²¹ R³² R³² L_(A501) R²² R³² R³²L_(A502) R²³ R³² R³² L_(A503) R²⁴ R³² R³² L_(A504) R²⁵ R³² R³² L_(A505)R²⁶ R³² R³² L_(A506) R²⁷ R³² R³² L_(A507) R²⁸ R³² R³² L_(A508) R²⁹ R³²R³² L_(A509) R³⁰ R³² R³² L_(A510) R³¹ R³² R³² L_(A511) R³³ R³² R³²L_(A512) R³⁴ R³² R³² L_(A513) R³⁵ R³² R³² L_(A514) R³⁶ R³² R³² L_(A515)R³⁷ R³² R³² L_(A516) R³⁸ R³² R³² L_(A517) R³⁹ R³² R³² L_(A518) R⁴⁰ R³²R³² L_(A519) R⁴¹ R³² R³² L_(A520) R⁴² R³² R³² L_(A521) R⁴³ R³² R³²L_(A522) R⁴⁴ R³² R³² L_(A523) R⁴⁵ R³² R³² L_(A524) R⁴⁶ R³² R³² L_(A525)R⁴⁷ R³² R³² L_(A526) R⁴⁸ R³² R³² L_(A527) R⁴⁹ R³² R³² L_(A528) R⁵⁰ R³²R³² L_(A529) R⁵¹ R³² R³² L_(A530) R⁵² R³² R³² L_(A531) R⁵³ R³² R³²L_(A532) R⁵⁴ R³² R³² L_(A533) R¹ R³⁶ R³² L_(A534) R² R³⁶ R³² L_(A535) R³R³⁶ R³² L_(A536) R⁴ R³⁶ R³² L_(A537) R⁵ R³⁶ R³² L_(A538) R⁶ R³⁶ R³²L_(A539) R⁷ R³⁶ R³² L_(A540) R⁸ R³⁶ R³² L_(A541) R⁹ R³⁶ R³² L_(A542) R¹⁰R³⁶ R³² L_(A543) R¹¹ R³⁶ R³² L_(A544) R¹² R³⁶ R³² L_(A545) R¹³ R³⁶ R³²L_(A546) R¹⁴ R³⁶ R³² L_(A547) R¹⁵ R³⁶ R³² L_(A548) R¹⁶ R³⁶ R³² L_(A549)R¹⁷ R³⁶ R³² L_(A550) R¹⁸ R³⁶ R³² L_(A551) R¹⁹ R³⁶ R³² L_(A552) R²⁰ R³⁶R³² L_(A553) R²¹ R³⁶ R³² L_(A554) R²² R³⁶ R³² L_(A555) R²³ R³⁶ R³²L_(A556) R²⁴ R³⁶ R³² L_(A557) R²⁵ R³⁶ R³² L_(A558) R²⁶ R³⁶ R³² L_(A559)R²⁷ R³⁶ R³² L_(A560) R²⁸ R³⁶ R³² L_(A561) R²⁹ R³⁶ R³² L_(A562) R³⁰ R³⁶R³² L_(A563) R³¹ R³⁶ R³² L_(A564) R³² R³⁶ R³² L_(A565) R³³ R³⁶ R³²L_(A566) R³⁴ R³⁶ R³² L_(A567) R³⁵ R³⁶ R³² L_(A568) R³⁷ R³⁶ R³² L_(A569)R³⁸ R³⁶ R³² L_(A570) R³⁹ R³⁶ R³² L_(A571) R⁴⁰ R³⁶ R³² L_(A572) R⁴¹ R³⁶R³² L_(A573) R⁴² R³⁶ R³² L_(A574) R⁴³ R³⁶ R³² L_(A575) R⁴⁴ R³⁶ R³²L_(A576) R⁴⁵ R³⁶ R³² L_(A577) R⁴⁶ R³⁶ R³² L_(A578) R⁴⁷ R³⁶ R³² L_(A579)R⁴⁸ R³⁶ R³² L_(A580) R⁴⁹ R³⁶ R³² L_(A581) R⁵⁰ R³⁶ R³² L_(A582) R⁵¹ R³⁶R³² L_(A583) R⁵² R³⁶ R³² L_(A584) R⁵³ R³⁶ R³² L_(A585) R⁵⁴ R³⁶ R³²L_(A586) R¹ R² R³² L_(A587) R¹ R³ R³² L_(A588) R¹ R⁴ R³² L_(A589) R¹ R⁵R³² L_(A590) R¹ R⁶ R³² L_(A591) R¹ R⁷ R³² L_(A592) R¹ R⁸ R³² L_(A593) R¹R⁹ R³² L_(A594) R¹ R¹⁰ R³² L_(A595) R¹ R¹¹ R³² L_(A596) R¹ R¹² R³²L_(A597) R¹ R¹³ R³² L_(A598) R¹ R¹⁴ R³² L_(A599) R¹ R¹⁵ R³² L_(A600) R¹R¹⁶ R³² L_(A601) R¹ R¹⁷ R³² L_(A602) R¹ R¹⁸ R³² L_(A603) R¹ R¹⁹ R³²L_(A604) R¹ R²⁰ R³² L_(A605) R¹ R²¹ R³² L_(A606) R¹ R²² R³² L_(A607) R¹R²³ R³² L_(A608) R¹ R²⁴ R³² L_(A609) R¹ R²⁵ R³² L_(A610) R¹ R²⁶ R³²L_(A611) R¹ R²⁷ R³² L_(A612) R¹ R²⁸ R³² L_(A613) R¹ R²⁹ R³² L_(A614) R¹R³⁰ R³² L_(A615) R¹ R³¹ R³² L_(A616) R¹ R³² R³² L_(A617) R¹ R³³ R³²L_(A618) R¹ R³⁴ R³² L_(A619) R¹ R³⁵ R³² L_(A620) R¹ R³⁶ R³² L_(A621) R¹R³⁷ R³² L_(A622) R¹ R³⁸ R³² L_(A623) R¹ R³⁹ R³² L_(A624) R¹ R⁴⁰ R³²L_(A625) R¹ R⁴¹ R³² L_(A626) R¹ R⁴² R³² L_(A627) R¹ R⁴³ R³² L_(A628) R¹R⁴⁴ R³² L_(A629) R¹ R⁴⁵ R³² L_(A630) R¹ R⁴⁶ R³² L_(A631) R¹ R⁴⁷ R³²L_(A632) R¹ R⁴⁸ R³² L_(A633) R¹ R⁴⁹ R³² L_(A634) R¹ R⁵⁰ R³² L_(A635) R¹R⁵¹ R³² L_(A636) R¹ R⁵² R³² L_(A637) R¹ R⁵³ R³² L_(A638) R¹ R⁵⁴ R³²L_(A639) R³² R¹ R³² L_(A640) R³² R² R³² L_(A641) R³² R³ R³² L_(A642) R³²R⁴ R³² L_(A643) R³² R⁵ R³² L_(A644) R³² R⁶ R³² L_(A645) R³² R⁷ R³²L_(A646) R³² R⁸ R³² L_(A647) R³² R⁹ R³² L_(A648) R³² R¹⁰ R³² L_(A649)R³² R¹¹ R³² L_(A650) R³² R¹² R³² L_(A651) R³² R¹³ R³² L_(A652) R³² R¹⁴R³² L_(A653) R³² R¹⁵ R³² L_(A654) R³² R¹⁶ R³² L_(A655) R³² R¹⁷ R³²L_(A656) R³² R¹⁸ R³² L_(A657) R³² R¹⁹ R³² L_(A658) R³² R²⁰ R³² L_(A659)R³² R²¹ R³² L_(A660) R³² R²² R³² L_(A661) R³² R²³ R³² L_(A662) R³² R²⁴R³² L_(A663) R³² R²⁵ R³² L_(A664) R³² R²⁶ R³² L_(A665) R³² R²⁷ R³²L_(A666) R³² R²⁸ R³² L_(A667) R³² R²⁹ R³² L_(A668) R³² R³⁰ R³² L_(A669)R³² R³¹ R³² L_(A670) R³² R³³ R³² L_(A671) R³² R³⁴ R³² L_(A672) R³² R³⁵R³² L_(A673) R³² R³⁶ R³² L_(A674) R³² R³⁷ R³² L_(A675) R³² R³⁸ R³²L_(A676) R³² R³⁹ R³² L_(A677) R³² R⁴⁰ R³² L_(A678) R³² R⁴¹ R³² L_(A679)R³² R⁴² R³² L_(A680) R³² R⁴³ R³² L_(A681) R³² R⁴⁴ R³² L_(A682) R³² R⁴⁵R³² L_(A683) R³² R⁴⁶ R³² L_(A684) R³² R⁴⁷ R³² L_(A685) R³² R⁴⁸ R³²L_(A686) R³² R⁴⁹ R³² L_(A687) R³² R⁵⁰ R³² L_(A688) R³² R⁵¹ R³² L_(A689)R³² R⁵² R³² L_(A690) R³² R⁵³ R³² L_(A691) R³² R⁵⁴ R³² L_(A692) R³⁶ R¹R³² L_(A693) R³⁶ R² R³² L_(A694) R³⁶ R³ R³² L_(A695) R³⁶ R⁴ R³² L_(A696)R³⁶ R⁵ R³² L_(A697) R³⁶ R⁶ R³² L_(A698) R³⁶ R⁷ R³² L_(A699) R³⁶ R⁸ R³²L_(A700) R³⁶ R⁹ R³² L_(A701) R³⁶ R¹⁰ R³² L_(A702) R³⁶ R¹¹ R³² L_(A703)R³⁶ R¹² R³² L_(A704) R³⁶ R¹³ R³² L_(A705) R³⁶ R¹⁴ R³² L_(A706) R³⁶ R¹⁵R³² L_(A707) R³⁶ R¹⁶ R³² L_(A708) R³⁶ R¹⁷ R³² L_(A709) R³⁶ R¹⁸ R³²L_(A710) R³⁶ R¹⁹ R³² L_(A711) R³⁶ R²⁰ R³² L_(A712) R³⁶ R²¹ R³² L_(A713)R³⁶ R²² R³² L_(A714) R³⁶ R²³ R³² L_(A715) R³⁶ R²⁴ R³² L_(A716) R³⁶ R²⁵R³² L_(A717) R³⁶ R²⁶ R³² L_(A718) R³⁶ R²⁷ R³² L_(A719) R³⁶ R²⁸ R³²L_(A720) R³⁶ R²⁹ R³² L_(A721) R³⁶ R³⁰ R³² L_(A722) R³⁶ R³¹ R³² L_(A723)R³⁶ R³² R³² L_(A724) R³⁶ R³³ R³² L_(A725) R³⁶ R³⁴ R³² L_(A726) R³⁶ R³⁵R³² L_(A727) R³⁶ R³⁷ R³² L_(A728) R³⁶ R³⁸ R³² L_(A729) R³⁶ R³⁹ R³²L_(A730) R³⁶ R⁴⁰ R³² L_(A731) R³⁶ R⁴¹ R³² L_(A732) R³⁶ R⁴² R³² L_(A733)R³⁶ R⁴³ R³² L_(A734) R³⁶ R⁴⁴ R³² L_(A735) R³⁶ R⁴⁵ R³² L_(A736) R³⁶ R⁴⁶R³² L_(A737) R³⁶ R⁴⁷ R³² L_(A738) R³⁶ R⁴⁸ R³² L_(A739) R³⁶ R⁴⁹ R³²L_(A740) R³⁶ R⁵⁰ R³² L_(A741) R³⁶ R⁵¹ R³² L_(A742) R³⁶ R⁵² R³² L_(A743)R³⁶ R⁵³ R³² L_(A744) R³⁶ R⁵⁴ R³² L_(A745) R¹ R¹ R³⁶ L_(A746) R² R² R³⁶L_(A747) R³ R³ R³⁶ L_(A748) R⁴ R⁴ R³⁶ L_(A749) R⁵ R⁵ R³⁶ L_(A750) R⁶ R⁶R³⁶ L_(A751) R⁷ R⁷ R³⁶ L_(A752) R⁸ R⁸ R³⁶ L_(A753) R⁹ R⁹ R³⁶ L_(A754)R¹⁰ R¹⁰ R³⁶ L_(A755) R¹¹ R¹¹ R³⁶ L_(A756) R¹² R¹² R³⁶ L_(A757) R¹³ R¹³R³⁶ L_(A758) R¹⁴ R¹⁴ R³⁶ L_(A759) R¹⁵ R¹⁵ R³⁶ L_(A760) R¹⁶ R¹⁶ R³⁶L_(A761) R¹⁷ R¹⁷ R³⁶ L_(A762) R¹⁸ R¹⁸ R³⁶ L_(A763) R¹⁹ R¹⁹ R³⁶ L_(A764)R²⁰ R²⁰ R³⁶ L_(A765) R²¹ R²¹ R³⁶ L_(A766) R²² R²² R³⁶ L_(A767) R²³ R²³R³⁶ L_(A768) R²⁴ R²⁴ R³⁶ L_(A769) R²⁵ R²⁵ R³⁶ L_(A770) R²⁶ R²⁶ R³⁶L_(A771) R²⁷ R²⁷ R³⁶ L_(A772) R²⁸ R²⁸ R³⁶ L_(A773) R²⁹ R²⁹ R³⁶ L_(A774)R³⁰ R³⁰ R³⁶ L_(A775) R³¹ R³¹ R³⁶ L_(A776) R³² R³² R³⁶ L_(A777) R³³ R³³R³⁶ L_(A778) R³⁴ R³⁴ R³⁶ L_(A779) R³⁵ R³⁵ R³⁶ L_(A780) R³⁶ R³⁶ R³⁶L_(A781) R³⁷ R³⁷ R³⁶ L_(A782) R³⁸ R³⁸ R³⁶ L_(A783) R³⁹ R³⁹ R³⁶ L_(A784)R⁴⁰ R⁴⁰ R³⁶ L_(A785) R⁴¹ R⁴¹ R³⁶ L_(A786) R⁴² R⁴² R³⁶ L_(A787) R⁴³ R⁴³R³⁶ L_(A788) R⁴⁴ R⁴⁴ R³⁶ L_(A789) R⁴⁵ R⁴⁵ R³⁶ L_(A790) R⁴⁶ R⁴⁶ R³⁶L_(A791) R⁴⁷ R⁴⁷ R³⁶ L_(A792) R⁴⁸ R⁴⁸ R³⁶ L_(A793) R⁴⁹ R⁴⁹ R³⁶ L_(A794)R⁵⁰ R⁵⁰ R³⁶ L_(A795) R⁵¹ R⁵¹ R³⁶ L_(A796) R⁵² R⁵² R³⁶ L_(A797) R⁵³ R⁵³R³⁶ L_(A798) R⁵⁴ R⁵⁴ R³⁶ L_(A799) R² R¹ R³⁶ L_(A800) R³ R¹ R³⁶ L_(A801)R⁴ R¹ R³⁶ L_(A802) R⁵ R¹ R³⁶ L_(A803) R⁶ R¹ R³⁶ L_(A804) R⁷ R¹ R³⁶L_(A805) R⁸ R¹ R³⁶ L_(A806) R⁹ R¹ R³⁶ L_(A807) R¹⁰ R¹ R³⁶ L_(A808) R¹¹R¹ R³⁶ L_(A809) R¹² R¹ R³⁶ L_(A810) R¹³ R¹ R³⁶ L_(A811) R¹⁴ R¹ R³⁶L_(A812) R¹⁵ R¹ R³⁶ L_(A813) R¹⁶ R¹ R³⁶ L_(A814) R¹⁷ R¹ R³⁶ L_(A815) R¹⁸R¹ R³⁶ L_(A816) R¹⁹ R¹ R³⁶ L_(A817) R²⁰ R¹ R³⁶ L_(A818) R²¹ R¹ R³⁶L_(A819) R²² R¹ R³⁶ L_(A820) R²³ R¹ R³⁶ L_(A821) R²⁴ R¹ R³⁶ L_(A822) R²⁵R¹ R³⁶ L_(A823) R²⁶ R¹ R³⁶ L_(A824) R²⁷ R¹ R³⁶ L_(A825) R²⁸ R¹ R³⁶L_(A826) R²⁹ R¹ R³⁶ L_(A827) R³⁰ R¹ R³⁶ L_(A828) R³¹ R¹ R³⁶ L_(A829) R³²R¹ R³⁶ L_(A830) R³³ R¹ R³⁶ L_(A831) R³⁴ R¹ R³⁶ L_(A832) R³⁵ R¹ R³⁶L_(A833) R³⁶ R¹ R³⁶ L_(A834) R³⁷ R¹ R³⁶ L_(A835) R³⁸ R¹ R³⁶ L_(A836) R³⁹R¹ R³⁶ L_(A837) R⁴⁰ R¹ R³⁶ L_(A838) R⁴¹ R¹ R³⁶ L_(A839) R⁴² R¹ R³⁶L_(A840) R⁴³ R¹ R³⁶ L_(A841) R⁴⁴ R¹ R³⁶ L_(A842) R⁴⁵ R¹ R³⁶ L_(A843) R⁴⁶R¹ R³⁶ L_(A844) R⁴⁷ R¹ R³⁶ L_(A845) R⁴⁸ R¹ R³⁶ L_(A846) R⁴⁹ R¹ R³⁶L_(A847) R⁵⁰ R¹ R³⁶ L_(A848) R⁵¹ R¹ R³⁶ L_(A849) R⁵² R¹ R³⁶ L_(A850) R⁵³R¹ R³⁶ L_(A851) R⁵⁴ R¹ R³⁶ L_(A852) R¹ R³² R³⁶ L_(A853) R² R³² R³⁶L_(A854) R³ R³² R³⁶ L_(A855) R⁴ R³² R³⁶ L_(A856) R⁵ R³² R³⁶ L_(A857) R⁶R³² R³⁶ L_(A858) R⁷ R³² R³⁶ L_(A859) R⁸ R³² R³⁶ L_(A860) R⁹ R³² R³⁶L_(A861) R¹⁰ R³² R³⁶ L_(A862) R¹¹ R³² R³⁶ L_(A863) R¹² R³² R³⁶ L_(A864)R¹³ R³² R³⁶ L_(A865) R¹⁴ R³² R³⁶ L_(A866) R¹⁵ R³² R³⁶ L_(A867) R¹⁶ R³²R³⁶ L_(A868) R¹⁷ R³² R³⁶ L_(A869) R¹⁸ R³² R³⁶ L_(A870) R¹⁹ R³² R³⁶L_(A871) R²⁰ R³² R³⁶ L_(A872) R²¹ R³² R³⁶ L_(A873) R²² R³² R³⁶ L_(A874)R²³ R³² R³⁶ L_(A875) R²⁴ R³² R³⁶ L_(A876) R²⁵ R³² R³⁶ L_(A877) R²⁶ R³²R³⁶ L_(A878) R²⁷ R³² R³⁶ L_(A879) R²⁸ R³² R³⁶ L_(A880) R²⁹ R³² R³⁶L_(A881) R³⁰ R³² R³⁶ L_(A882) R³¹ R³² R³⁶ L_(A883) R³³ R³² R³⁶ L_(A884)R³⁴ R³² R³⁶ L_(A885) R³⁵ R³² R³⁶ L_(A886) R³⁶ R³² R³⁶ L_(A887) R³⁷ R³²R³⁶ L_(A888) R³⁸ R³² R³⁶ L_(A889) R³⁹ R³² R³⁶ L_(A890) R⁴⁰ R³² R³⁶L_(A891) R⁴¹ R³² R³⁶ L_(A892) R⁴² R³² R³⁶ L_(A893) R⁴³ R³² R³⁶ L_(A894)R⁴⁴ R³² R³⁶ L_(A895) R⁴⁵ R³² R³⁶ L_(A896) R⁴⁶ R³² R³⁶ L_(A897) R⁴⁷ R³²R³⁶ L_(A898) R⁴⁸ R³² R³⁶ L_(A899) R⁴⁹ R³² R³⁶ L_(A900) R⁵⁰ R³² R³⁶L_(A901) R⁵¹ R³² R³⁶ L_(A902) R⁵² R³² R³⁶ L_(A903) R⁵³ R³² R³⁶ L_(A904)R⁵⁴ R³² R³⁶ L_(A905) R¹ R³⁶ R³⁶ L_(A906) R² R³⁶ R³⁶ L_(A907) R³ R³⁶ R³⁶L_(A908) R⁴ R³⁶ R³⁶ L_(A909) R⁵ R³⁶ R³⁶ L_(A910) R⁶ R³⁶ R³⁶ L_(A911) R⁷R³⁶ R³⁶ L_(A912) R⁸ R³⁶ R³⁶ L_(A913) R⁹ R³⁶ R³⁶ L_(A914) R¹⁰ R³⁶ R³⁶L_(A915) R¹¹ R³⁶ R³⁶ L_(A916) R¹² R³⁶ R³⁶ L_(A917) R¹³ R³⁶ R³⁶ L_(A918)R¹⁴ R³⁶ R³⁶ L_(A919) R¹⁵ R³⁶ R³⁶ L_(A920) R¹⁶ R³⁶ R³⁶ L_(A921) R¹⁷ R³⁶R³⁶ L_(A922) R¹⁸ R³⁶ R³⁶ L_(A923) R¹⁹ R³⁶ R³⁶ L_(A924) R²⁰ R³⁶ R³⁶L_(A925) R²¹ R³⁶ R³⁶ L_(A926) R²² R³⁶ R³⁶ L_(A927) R²³ R³⁶ R³⁶ L_(A928)R²⁴ R³⁶ R³⁶ L_(A929) R²⁵ R³⁶ R³⁶ L_(A930) R²⁶ R³⁶ R³⁶ L_(A931) R²⁷ R³⁶R³⁶ L_(A932) R²⁸ R³⁶ R³⁶ L_(A933) R²⁹ R³⁶ R³⁶ L_(A934) R³⁰ R³⁶ R³⁶L_(A935) R³¹ R³⁶ R³⁶ L_(A936) R³² R³⁶ R³⁶ L_(A937) R³³ R³⁶ R³⁶ L_(A938)R³⁴ R³⁶ R³⁶ L_(A939) R³⁵ R³⁶ R³⁶ L_(A940) R³⁷ R³⁶ R³⁶ L_(A941) R³⁸ R³⁶R³⁶ L_(A942) R³⁹ R³⁶ R³⁶ L_(A943) R⁴⁰ R³⁶ R³⁶ L_(A944) R⁴¹ R³⁶ R³⁶L_(A945) R⁴² R³⁶ R³⁶ L_(A946) R⁴³ R³⁶ R³⁶ L_(A947) R⁴⁴ R³⁶ R³⁶ L_(A948)R⁴⁵ R³⁶ R³⁶ L_(A949) R⁴⁶ R³⁶ R³⁶ L_(A950) R⁴⁷ R³⁶ R³⁶ L_(A951) R⁴⁸ R³⁶R³⁶ L_(A952) R⁴⁹ R³⁶ R³⁶ L_(A953) R⁵⁰ R³⁶ R³⁶ L_(A954) R⁵¹ R³⁶ R³⁶L_(A955) R⁵² R³⁶ R³⁶ L_(A956) R⁵³ R³⁶ R³⁶ L_(A957) R⁵⁴ R³⁶ R³⁶ L_(A958)R¹ R² R³⁶ L_(A959) R¹ R³ R³⁶ L_(A960) R¹ R⁴ R³⁶ L_(A961) R¹ R⁵ R³⁶L_(A962) R¹ R⁶ R³⁶ L_(A963) R¹ R⁷ R³⁶ L_(A964) R¹ R⁸ R³⁶ L_(A965) R¹ R⁹R³⁶ L_(A966) R¹ R¹⁰ R³⁶ L_(A967) R¹ R¹¹ R³⁶ L_(A968) R¹ R¹² R³⁶ L_(A969)R¹ R¹³ R³⁶ L_(A970) R¹ R¹⁴ R³⁶ L_(A971) R¹ R¹⁵ R³⁶ L_(A972) R¹ R¹⁶ R³⁶L_(A973) R¹ R¹⁷ R³⁶ L_(A974) R¹ R¹⁸ R³⁶ L_(A975) R¹ R¹⁹ R³⁶ L_(A976) R¹R²⁰ R³⁶ L_(A977) R¹ R²¹ R³⁶ L_(A978) R¹ R²² R³⁶ L_(A979) R¹ R²³ R³⁶L_(A980) R¹ R²⁴ R³⁶ L_(A981) R¹ R²⁵ R³⁶ L_(A982) R¹ R²⁶ R³⁶ L_(A983) R¹R²⁷ R³⁶ L_(A984) R¹ R²⁸ R³⁶ L_(A985) R¹ R²⁹ R³⁶ L_(A986) R¹ R³⁰ R³⁶L_(A987) R¹ R³¹ R³⁶ L_(A988) R¹ R³² R³⁶ L_(A989) R¹ R³³ R³⁶ L_(A990) R¹R³⁴ R³⁶ L_(A991) R¹ R³⁵ R³⁶ L_(A992) R¹ R³⁶ R³⁶ L_(A993) R¹ R³⁷ R³⁶L_(A994) R¹ R³⁸ R³⁶ L_(A995) R¹ R³⁹ R³⁶ L_(A996) R¹ R⁴⁰ R³⁶ L_(A997) R¹R⁴¹ R³⁶ L_(A998) R¹ R⁴² R³⁶ L_(A999) R¹ R⁴³ R³⁶ L_(A1000) R¹ R⁴⁴ R³⁶L_(A1001) R¹ R⁴⁵ R³⁶ L_(A1002) R¹ R⁴⁶ R³⁶ L_(A1003) R¹ R⁴⁷ R³⁶ L_(A1004)R¹ R⁴⁸ R³⁶ L_(A1005) R¹ R⁴⁹ R³⁶ L_(A1006) R¹ R⁵⁰ R³⁶ L_(A1007) R¹ R⁵¹R³⁶ L_(A1008) R¹ R⁵² R³⁶ L_(A1009) R¹ R⁵³ R³⁶ L_(A1010) R¹ R⁵⁴ R³⁶L_(A1011) R³² R¹ R³⁶ L_(A1012) R³² R² R³⁶ L_(A1013) R³² R³ R³⁶ L_(A1014)R³² R⁴ R³⁶ L_(A1015) R³² R⁵ R³⁶ L_(A1016) R³² R⁶ R³⁶ L_(A1017) R³² R⁷R³⁶ L_(A1018) R³² R⁸ R³⁶ L_(A1019) R³² R⁹ R³⁶ L_(A1020) R³² R¹⁰ R³⁶L_(A1021) R³² R¹¹ R³⁶ L_(A1022) R³² R¹² R³⁶ L_(A1023) R³² R¹³ R³⁶L_(A1024) R³² R¹⁴ R³⁶ L_(A1025) R³² R¹⁵ R³⁶ L_(A1026) R³² R¹⁶ R³⁶L_(A1027) R³² R¹⁷ R³⁶ L_(A1028) R³² R¹⁸ R³⁶ L_(A1029) R³² R¹⁹ R³⁶L_(A1030) R³² R²⁰ R³⁶ L_(A1031) R³² R²¹ R³⁶ L_(A1032) R³² R²² R³⁶L_(A1033) R³² R²³ R³⁶ L_(A1034) R³² R²⁴ R³⁶ L_(A1035) R³² R²⁵ R³⁶L_(A1036) R³² R²⁶ R³⁶ L_(A1037) R³² R²⁷ R³⁶ L_(A1038) R³² R²⁸ R³⁶L_(A1039) R³² R²⁹ R³⁶ L_(A1040) R³² R³⁰ R³⁶ L_(A1041) R³² R³¹ R³⁶L_(A1042) R³² R³³ R³⁶ L_(A1043) R³² R³⁴ R³⁶ L_(A1044) R³² R³⁵ R³⁶L_(A1045) R³² R³⁶ R³⁶ L_(A1046) R³² R³⁷ R³⁶ L_(A1047) R³² R³⁸ R³⁶L_(A1048) R³² R³⁹ R³⁶ L_(A1049) R³² R⁴⁰ R³⁶ L_(A1050) R³² R⁴¹ R³⁶L_(A1051) R³² R⁴² R³⁶ L_(A1052) R³² R⁴³ R³⁶ L_(A1053) R³² R⁴⁴ R³⁶L_(A1054) R³² R⁴⁵ R³⁶ L_(A1055) R³² R⁴⁶ R³⁶ L_(A1056) R³² R⁴⁷ R³⁶L_(A1057) R³² R⁴⁸ R³⁶ L_(A1058) R³² R⁴⁹ R³⁶ L_(A1059) R³² R⁵⁰ R³⁶L_(A1060) R³² R⁵¹ R³⁶ L_(A1061) R³² R⁵² R³⁶ L_(A1062) R³² R⁵³ R³⁶L_(A1063) R³² R⁵⁴ R³⁶ L_(A1064) R³⁶ R¹ R³⁶ L_(A1065) R³⁶ R² R³⁶L_(A1066) R³⁶ R³ R³⁶ L_(A1067) R³⁶ R⁴ R³⁶ L_(A1068) R³⁶ R⁵ R³⁶ L_(A1069)R³⁶ R⁶ R³⁶ L_(A1070) R³⁶ R⁷ R³⁶ L_(A1071) R³⁶ R⁸ R³⁶ L_(A1072) R³⁶ R⁹R³⁶ L_(A1073) R³⁶ R¹⁰ R³⁶ L_(A1074) R³⁶ R¹¹ R³⁶ L_(A1075) R³⁶ R¹² R³⁶L_(A1076) R³⁶ R¹³ R³⁶ L_(A1077) R³⁶ R¹⁴ R³⁶ L_(A1078) R³⁶ R¹⁵ R³⁶L_(A1079) R³⁶ R¹⁶ R³⁶ L_(A1080) R³⁶ R¹⁷ R³⁶ L_(A1081) R³⁶ R¹⁸ R³⁶L_(A1082) R³⁶ R¹⁹ R³⁶ L_(A1083) R³⁶ R²⁰ R³⁶ L_(A1084) R³⁶ R²¹ R³⁶L_(A1085) R³⁶ R²² R³⁶ L_(A1086) R³⁶ R²³ R³⁶ L_(A1087) R³⁶ R²⁴ R³⁶L_(A1088) R³⁶ R²⁵ R³⁶ L_(A1089) R³⁶ R²⁶ R³⁶ L_(A1090) R³⁶ R²⁷ R³⁶L_(A1091) R³⁶ R²⁸ R³⁶ L_(A1092) R³⁶ R²⁹ R³⁶ L_(A1093) R³⁶ R³⁰ R³⁶L_(A1094) R³⁶ R³¹ R³⁶ L_(A1095) R³⁶ R³² R³⁶ L_(A1096) R³⁶ R³³ R³⁶L_(A1097) R³⁶ R³⁴ R³⁶ L_(A1098) R³⁶ R³⁵ R³⁶ L_(A1099) R³⁶ R³⁷ R³⁶L_(A1100) R³⁶ R³⁸ R³⁶ L_(A1101) R³⁶ R³⁹ R³⁶ L_(A1102) R³⁶ R⁴⁰ R³⁶L_(A1103) R³⁶ R⁴¹ R³⁶ L_(A1104) R³⁶ R⁴² R³⁶ L_(A1105) R³⁶ R⁴³ R³⁶L_(A1106) R³⁶ R⁴⁴ R³⁶ L_(A1107) R³⁶ R⁴⁵ R³⁶ L_(A1108) R³⁶ R⁴⁶ R³⁶L_(A1109) R³⁶ R⁴⁷ R³⁶ L_(A1110) R³⁶ R⁴⁸ R³⁶ L_(A1111) R³⁶ R⁴⁹ R³⁶L_(A1112) R³⁶ R⁵⁰ R³⁶ L_(A1113) R³⁶ R⁵¹ R³⁶ L_(A1114) R³⁶ R⁵² R³⁶L_(A1115) R³⁶ R⁵³ R³⁶ L_(A1116) R³⁶ R⁵⁴ R³⁶wherein each R^(E), R^(F), and R^(G) is defined as follows:

In some embodiments, the ligand L_(A) of Formula I can be selected fromthe group consisting of the structures in the following LIST 3:

In some embodiments, the iridium compound can have a formula ofIr(L_(A))_(x)(L_(B))_(y)(L_(C))_(z) wherein L_(B) and L_(C) are each abidentate ligand; and wherein x is 1, 2, or 3; y is 0, 1, or 2; z is 0,1, or 2; and x+y+z is 3.

In some embodiments, the compound can have a formula selected from thegroup consisting of Ir(L_(A))₃, Ir(L_(A))(L_(B))₂, Ir(L_(A))₂(L_(B)),Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)), wherein L_(A), L_(B),and L_(C) are different from each other.

In some embodiments, L_(B) and L_(C) can each be independently selectedfrom the group consisting of:

wherein: T is B, Al, Ga, or In; each of Y¹ to Y¹³ is independentlyselected from the group consisting of carbon and nitrogen; Y′ isselected from the group consisting of BR_(e), NR_(e), PR_(e), O, S, Se,C═O, S═O, SO₂, CR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) can befused or joined to form a ring; each R_(a), R_(b), R_(c), and R_(d)independently represents zero, mono, or up to a maximum allowed numberof substitutions to its associated ring; each of R_(a1), R_(b1), R_(c1),R_(d1), R_(a), R_(b), R_(c), R_(d), R_(e) and R_(f) is independently ahydrogen or a substituent selected from the group consisting of thegeneral substituents defined herein; and any two adjacent R_(a), R_(b),R_(c), R_(d), R_(e) and R_(f) can be fused or joined to form a ring orform a multidentate ligand.

In some embodiments, L_(B) and L_(C) may each be independently selectedfrom the group consisting of the structures in the following LIST 4:

wherein:R_(a)′, R_(b)′, and R_(e)′ each independently represents zero, mono, orup to a maximum allowed number of substitutions to its associated ring;each of R_(a1), R_(b1), R_(c1), R_(N), R_(a)′, R_(b)′, and R_(c)′ isindependently hydrogen or a substituent selected from the groupconsisting of the general substituents defined herein; and two adjacentR_(a)′, R_(b)′, and R_(c)′ can be fused or joined to form a ring or forma multidentate ligand.

In some embodiments, the compound can have the formula Ir(L_(A))₃, theformula Ir(L_(A))(L_(Bk))₂, the formula Ir(L_(A))₂(L_(Cj-I)), theformula Ir(L_(A))₂(L_(Cj-II)), the formula Ir(L_(A))(L_(Bk))(L_(C-I)),or the formula Ir(L_(A))(L_(Bk))(L_(Cj-II)), wherein L_(A) is a compoundas described herein; L_(Bk) is selected from the group as describedherein, and L_(Cj-I) and L_(Cj-II) are each independently selected fromthe groups as described herein.

In some embodiments, when the compound has formula Ir(L_(Ah-m))₃, h isan integer from 1 to 1116; m is an integer from 1 to 48; and thecompound is selected from the group consisting of Ir(L_(A1-1))₃ toIr(L_(A1116-48))₃; when the compound has formula Ir(L_(Ah-m))(L_(Bk))₂,h is an integer from 1 to 1116; m is an integer from 1 to 48; k is aninteger from 1 to 264; and the compound is selected from the groupconsisting of Ir(L_(A1-1))(L_(B1))₂ to Ir(L_(A1116-48))(L_(B264))₂;

when the compound has formula Ir(L_(Ah-m))₂(L_(Bk)), h is an integerfrom 1 to 1116; m is an integer from 1 to 48; k is an integer from 1 to264; and the compound is selected from the group consisting ofIr(L_(A1-1))₂(L_(B1)) to Ir(L_(A1116-48))₂(L_(B264));when the compound has formula Ir(L_(Ah-m))₂(L_(Cj-I)), h is an integerfrom 1 to 1116; m is an integer from 1 to 48; j is an integer from 1 to1416; and the compound is selected from the group consisting ofIr(L_(A1-1))₂(L_(C1-I)) to Ir(L_(A1116-48)) (L_(C1416-I)); andwhen the compound has formula Ir(L_(Ah-m))₂(L_(Cj-II)), h is an integerfrom 1 to 1116; m is an integer from 1 to 48; j is an integer from 1 to1416; and the compound is selected from the group consisting ofIr(L_(A1-1))₂(L_(C1-II)) to Ir(L_(A1116-48)) (L_(C1416-II));wherein each structure of L_(Ai-m) is defined herein;wherein each L_(Bk) has the structure defined in the following LIST 5:

andwherein each L_(Cj-I) has a structure based on formula

and each L_(Cj-II) has a structure based on formula

wherein for each L_(Cj) in L_(Cj-I) and L_(Cj-II), R²⁰¹ and R²⁰² areeach independently defined in the following LIST 6:

L_(Cj) R²⁰¹ R²⁰² L_(Cj) R²⁰¹ R²⁰² L_(Cj) R²⁰¹ R²⁰² L_(Cj) R²⁰¹ R²⁰²L_(C1) R^(D1) R^(D1) L_(C193) R^(D1) R^(D3) L_(C385) R^(D17) R^(D40)L_(C577) R^(D143) R^(D120) L_(C2) R^(D2) R^(D2) L_(C194) R^(D1) R^(D4)L_(C386) R^(D17) R^(D41) L_(C578) R^(D143) R^(D133) L_(C3) R^(D3) R^(D3)L_(C195) R^(D1) R^(D5) L_(C387) R^(D17) R^(D42) L_(C579) R^(D143)R^(D134) L_(C4) R^(D4) R^(D4) L_(C196) R^(D1) R^(D9) L_(C388) R^(D17)R^(D43) L_(C580) R^(D143) R^(D135) L_(C5) R^(D5) R^(D5) L_(C197) R^(D1)R^(D10) L_(C389) R^(D17) R^(D48) L_(C581) R^(D143) R^(D136) L_(C6)R^(D6) R^(D6) L_(C198) R^(D1) R^(D17) L_(C390) R^(D17) R^(D49) L_(C582)R^(D143) R^(D144) L_(C7) R^(D7) R^(D7) L_(C199) R^(D1) R^(D18) L_(C391)R^(D17) R^(D50) L_(C583) R^(D143) R^(D145) L_(C8) R^(D8) R^(D8) L_(C200)R^(D1) R^(D20) L_(C392) R^(D17) R^(D54) L_(C584) R^(D143) R^(D146)L_(C9) R^(D9) R^(D9) L_(C201) R^(D1) R^(D22) L_(C393) R^(D17) R^(D55)L_(C585) R^(D143) R^(D147) L_(C10) R^(D10) R^(D10) L_(C202) R^(D1)R^(D37) L_(C394) R^(D17) R^(D58) L_(C586) R^(D143) R^(D149) L_(C11)R^(D11) R^(D11) L_(C203) R^(D1) R^(D40) L_(C395) R^(D17) R^(D59)L_(C587) R^(D143) R^(D151) L_(C12) R^(D12) R^(D12) L_(C204) R^(D1)R^(D41) L_(C396) R^(D17) R^(D78) L_(C588) R^(D143) R^(D154) L_(C13)R^(D13) R^(D13) L_(C205) R^(D1) R^(D42) L_(C397) R^(D17) R^(D79)L_(C589) R^(D143) R^(D155) L_(C14) R^(D14) R^(D14) L_(C206) R^(D1)R^(D43) L_(C398) R^(D17) R^(D81) L_(C590) R^(D143) R^(D161) L_(C15)R^(D15) R^(D15) L_(C207) R^(D1) R^(D48) L_(C399) R^(D17) R^(D87)L_(C591) R^(D143) R^(D175) L_(C16) R^(D16) R^(D16) L_(C208) R^(D1)R^(D49) L_(C400) R^(D17) R^(D88) L_(C592) R^(D144) R^(D3) L_(C17)R^(D17) R^(D17) L_(C209) R^(D1) R^(D50) L_(C401) R^(D17) R^(D89)L_(C593) R^(D144) R^(D5) L_(C18) R^(D18) R^(D18) L_(C210) R^(D1) R^(D54)L_(C402) R^(D17) R^(D93) L_(C594) R^(D144) R^(D17) L_(C19) R^(D19)R^(D19) L_(C211) R^(D1) R^(D55) L_(C403) R^(D17) R^(D116) L_(C595)R^(D144) R^(D18) L_(C20) R^(D20) R^(D20) L_(C212) R^(D1) R^(D58)L_(C404) R^(D17) R^(D117) L_(C596) R^(D144) R^(D20) L_(C21) R^(D21)R^(D21) L_(C213) R^(D1) R^(D59) L_(C405) R^(D17) R^(D118) L_(C597)R^(D144) R^(D22) L_(C22) R^(D22) R^(D22) L_(C214) R^(D1) R^(D78)L_(C406) R^(D17) R^(D119) L_(C598) R^(D144) R^(D37) L_(C23) R^(D23)R^(D23) L_(C215) R^(D1) R^(D79) L_(C407) R^(D17) R^(D120) L_(C599)R^(D144) R^(D40) L_(C24) R^(D24) R^(D24) L_(C216) R^(D1) R^(D81)L_(C408) R^(D17) R^(D133) L_(C600) R^(D144) R^(D41) L_(C25) R^(D25)R^(D25) L_(C217) R^(D1) R^(D87) L_(C409) R^(D17) R^(D134) L_(C601)R^(D144) R^(D42) L_(C26) R^(D26) R^(D26) L_(C218) R^(D1) R^(D88)L_(C410) R^(D17) R^(D135) L_(C602) R^(D144) R^(D43) L_(C27) R^(D27)R^(D27) L_(C219) R^(D1) R^(D89) L_(C411) R^(D17) R^(D136) L_(C603)R^(D144) R^(D48) L_(C28) R^(D28) R^(D28) L_(C220) R^(D1) R^(D93)L_(C412) R^(D17) R^(D143) L_(C604) R^(D144) R^(D49) L_(C29) R^(D29)R^(D29) L_(C221) R^(D1) R^(D116) L_(C413) R^(D17) R^(D144) L_(C605)R^(D144) R^(D54) L_(C30) R^(D30) R^(D30) L_(C222) R^(D1) R^(D117)L_(C414) R^(D17) R^(D145) L_(C606) R^(D144) R^(D58) L_(C31) R^(D31)R^(D31) L_(C223) R^(D1) R^(D118) L_(C415) R^(D17) R^(D146) L_(C607)R^(D144) R^(D59) L_(C32) R^(D32) R^(D32) L_(C224) R^(D1) R^(D119)L_(C416) R^(D17) R^(D147) L_(C608) R^(D144) R^(D78) L_(C33) R^(D33)R^(D33) L_(C225) R^(D1) R^(D120) L_(C417) R^(D17) R^(D149) L_(C609)R^(D144) R^(D79) L_(C34) R^(D34) R^(D34) L_(C226) R^(D1) R^(D133)L_(C418) R^(D17) R^(D151) L_(C610) R^(D144) R^(D81) L_(C35) R^(D35)R^(D35) L_(C227) R^(D1) R^(D134) L_(C419) R^(D17) R^(D154) L_(C611)R^(D144) R^(D87) L_(C36) R^(D36) R^(D36) L_(C228) R^(D1) R^(D135)L_(C420) R^(D17) R^(D155) L_(C612) R^(D144) R^(D88) L_(C37) R^(D37)R^(D37) L_(C229) R^(D1) R^(D136) L_(C421) R^(D17) R^(D161) L_(C613)R^(D144) R^(D89) L_(C38) R^(D38) R^(D38) L_(C230) R^(D1) R^(D143)L_(C422) R^(D17) R^(D175) L_(C614) R^(D144) R^(D93) L_(C39) R^(D39)R^(D39) L_(C231) R^(D1) R^(D144) L_(C423) R^(D50) R^(D3) L_(C615)R^(D144) R^(D116) L_(C40) R^(D40) R^(D40) L_(C232) R^(D1) R^(D145)L_(C424) R^(D50) R^(D5) L_(C616) R^(D144) R^(D117) L_(C41) R^(D41)R^(D41) L_(C233) R^(D1) R^(D146) L_(C425) R^(D50) R^(D18) L_(C617)R^(D144) R^(D118) L_(C42) R^(D42) R^(D42) L_(C234) R^(D1) R^(D147)L_(C426) R^(D50) R^(D20) L_(C618) R^(D144) R^(D119) L_(C43) R^(D43)R^(D43) L_(C235) R^(D1) R^(D149) L_(C427) R^(D50) R^(D22) L_(C619)R^(D144) R^(D120) L_(C44) R^(D44) R^(D44) L_(C236) R^(D1) R^(D151)L_(C428) R^(D50) R^(D37) L_(C620) R^(D144) R^(D133) L_(C45) R^(D45)R^(D45) L_(C237) R^(D1) R^(D154) L_(C429) R^(D50) R^(D40) L_(C621)R^(D144) R^(D134) L_(C46) R^(D46) R^(D46) L_(C238) R^(D1) R^(D155)L_(C430) R^(D50) R^(D41) L_(C622) R^(D144) R^(D135) L_(C47) R^(D47)R^(D47) L_(C239) R^(D1) R^(D161) L_(C431) R^(D50) R^(D42) L_(C623)R^(D144) R^(D136) L_(C48) R^(D48) R^(D48) L_(C240) R^(D1) R^(D175)L_(C432) R^(D50) R^(D43) L_(C624) R^(D144) R^(D145) L_(C49) R^(D49)R^(D49) L_(C241) R^(D4) R^(D3) L_(C433) R^(D50) R^(D48) L_(C625)R^(D144) R^(D146) L_(C50) R^(D50) R^(D50) L_(C242) R^(D4) R^(D5)L_(C434) R^(D50) R^(D49) L_(C626) R^(D144) R^(D147) L_(C51) R^(D51)R^(D51) L_(C243) R^(D4) R^(D9) L_(C435) R^(D50) R^(D54) L_(C627)R^(D144) R^(D149) L_(C52) R^(D52) R^(D52) L_(C244) R^(D4) R^(D10)L_(C436) R^(D50) R^(D55) L_(C628) R^(D144) R^(D151) L_(C53) R^(D53)R^(D53) L_(C245) R^(D4) R^(D17) L_(C437) R^(D50) R^(D58) L_(C629)R^(D144) R^(D154) L_(C54) R^(D54) R^(D54) L_(C246) R^(D4) R^(D18)L_(C438) R^(D50) R^(D59) L_(C630) R^(D144) R^(D155) L_(C55) R^(D55)R^(D55) L_(C247) R^(D4) R^(D20) L_(C439) R^(D50) R^(D78) L_(C631)R^(D144) R^(D161) L_(C56) R^(D56) R^(D56) L_(C248) R^(D4) R^(D22)L_(C440) R^(D50) R^(D79) L_(C632) R^(D144) R^(D175) L_(C57) R^(D57)R^(D57) L_(C249) R^(D4) R^(D37) L_(C441) R^(D50) R^(D81) L_(C633)R^(D145) R^(D3) L_(C58) R^(D58) R^(D58) L_(C250) R^(D4) R^(D40) L_(C442)R^(D50) R^(D87) L_(C634) R^(D145) R^(D5) L_(C59) R^(D59) R^(D59)L_(C251) R^(D4) R^(D41) L_(C443) R^(D50) R^(D88) L_(C635) R^(D145)R^(D17) L_(C60) R^(D60) R^(D60) L_(C252) R^(D4) R^(D42) L_(C444) R^(D50)R^(D89) L_(C636) R^(D145) R^(D18) L_(C61) R^(D61) R^(D61) L_(C253)R^(D4) R^(D43) L_(C445) R^(D50) R^(D93) L_(C637) R^(D145) R^(D20)L_(C62) R^(D62) R^(D62) L_(C254) R^(D4) R^(D48) L_(C446) R^(D50)R^(D116) L_(C638) R^(D145) R^(D22) L_(C63) R^(D63) R^(D63) L_(C255)R^(D4) R^(D49) L_(C447) R^(D50) R^(D117) L_(C639) R^(D145) R^(D37)L_(C64) R^(D64) R^(D64) L_(C256) R^(D4) R^(D50) L_(C448) R^(D50)R^(D118) L_(C640) R^(D145) R^(D40) L_(C65) R^(D65) R^(D65) L_(C257)R^(D4) R^(D54) L_(C449) R^(D50) R^(D119) L_(C641) R^(D145) R^(D41)L_(C66) R^(D66) R^(D66) L_(C258) R^(D4) R^(D55) L_(C450) R^(D50)R^(D120) L_(C642) R^(D145) R^(D42) L_(C67) R^(D67) R^(D67) L_(C259)R^(D4) R^(D58) L_(C451) R^(D50) R^(D133) L_(C643) R^(D145) R^(D43)L_(C68) R^(D68) R^(D68) L_(C260) R^(D4) R^(D59) L_(C452) R^(D50)R^(D134) L_(C644) R^(D145) R^(D48) L_(C69) R^(D69) R^(D69) L_(C261)R^(D4) R^(D78) L_(C453) R^(D50) R^(D135) L_(C645) R^(D145) R^(D49)L_(C70) R^(D70) R^(D70) L_(C262) R^(D4) R^(D79) L_(C454) R^(D50)R^(D136) L_(C646) R^(D145) R^(D54) L_(C71) R^(D71) R^(D71) L_(C263)R^(D4) R^(D81) L_(C455) R^(D50) R^(D143) L_(C647) R^(D145) R^(D58)L_(C72) R^(D72) R^(D72) L_(C264) R^(D4) R^(D87) L_(C456) R^(D50)R^(D144) L_(C648) R^(D145) R^(D59) L_(C73) R^(D73) R^(D73) L_(C265)R^(D4) R^(D88) L_(C457) R^(D50) R^(D145) L_(C649) R^(D145) R^(D78)L_(C74) R^(D74) R^(D74) L_(C266) R^(D4) R^(D89) L_(C458) R^(D50)R^(D146) L_(C650) R^(D145) R^(D79) L_(C75) R^(D75) R^(D75) L_(C267)R^(D4) R^(D93) L_(C459) R^(D50) R^(D147) L_(C651) R^(D145) R^(D81)L_(C76) R^(D76) R^(D76) L_(C268) R^(D4) R^(D116) L_(C460) R^(D50)R^(D149) L_(C652) R^(D145) R^(D87) L_(C77) R^(D77) R^(D77) L_(C269)R^(D4) R^(D117) L_(C461) R^(D50) R^(D151) L_(C653) R^(D145) R^(D88)L_(C78) R^(D78) R^(D78) L_(C270) R^(D4) R^(D118) L_(C462) R^(D50)R^(D154) L_(C654) R^(D145) R^(D89) L_(C79) R^(D79) R^(D79) L_(C271)R^(D4) R^(D119) L_(C463) R^(D50) R^(D155) L_(C655) R^(D145) R^(D93)L_(C80) R^(D80) R^(D80) L_(C272) R^(D4) R^(D120) L_(C464) R^(D50)R^(D161) L_(C656) R^(D145) R^(D116) L_(C81) R^(D81) R^(D81) L_(C273)R^(D4) R^(D133) L_(C465) R^(D50) R^(D175) L_(C657) R^(D145) R^(D117)L_(C82) R^(D82) R^(D82) L_(C274) R^(D4) R^(D134) L_(C466) R^(D55) R^(D3)L_(C658) R^(D145) R^(D118) L_(C83) R^(D83) R^(D83) L_(C275) R^(D4)R^(D135) L_(C467) R^(D55) R^(D5) L_(C659) R^(D145) R^(D119) L_(C84)R^(D84) R^(D84) L_(C276) R^(D4) R^(D136) L_(C468) R^(D55) R^(D18)L_(C660) R^(D145) R^(D120) L_(C85) R^(D85) R^(D85) L_(C277) R^(D4)R^(D143) L_(C469) R^(D55) R^(D20) L_(C661) R^(D145) R^(D133) L_(C86)R^(D86) R^(D86) L_(C278) R^(D4) R^(D144) L_(C470) R^(D55) R^(D22)L_(C662) R^(D145) R^(D134) L_(C87) R^(D87) R^(D87) L_(C279) R^(D4)R^(D145) L_(C471) R^(D55) R^(D37) L_(C663) R^(D145) R^(D135) L_(C88)R^(D88) R^(D88) L_(C280) R^(D4) R^(D146) L_(C472) R^(D55) R^(D40)L_(C664) R^(D145) R^(D136) L_(C89) R^(D89) R^(D89) L_(C281) R^(D4)R^(D147) L_(C473) R^(D55) R^(D41) L_(C665) R^(D145) R^(D146) L_(C90)R^(D90) R^(D90) L_(C282) R^(D4) R^(D149) L_(C474) R^(D55) R^(D42)L_(C666) R^(D145) R^(D147) L_(C91) R^(D91) R^(D91) L_(C283) R^(D4)R^(D151) L_(C475) R^(D55) R^(D43) L_(C667) R^(D145) R^(D149) L_(C92)R^(D92) R^(D92) L_(C284) R^(D4) R^(D154) L_(C476) R^(D55) R^(D48)L_(C668) R^(D145) R^(D151) L_(C93) R^(D93) R^(D93) L_(C285) R^(D4)R^(D155) L_(C477) R^(D55) R^(D49) L_(C669) R^(D145) R^(D154) L_(C94)R^(D94) R^(D94) L_(C286) R^(D4) R^(D161) L_(C478) R^(D55) R^(D54)L_(C670) R^(D145) R^(D155) L_(C95) R^(D95) R^(D95) L_(C287) R^(D4)R^(D175) L_(C479) R^(D55) R^(D58) L_(C671) R^(D145) R^(D161) L_(C96)R^(D96) R^(D96) L_(C288) R^(D9) R^(D3) L_(C480) R^(D55) R^(D59) L_(C672)R^(D145) R^(D175) L_(C97) R^(D97) R^(D97) L_(C289) R^(D9) R^(D5)L_(C481) R^(D55) R^(D78) L_(C673) R^(D146) R^(D3) L_(C98) R^(D98)R^(D98) L_(C290) R^(D9) R^(D10) L_(C482) R^(D55) R^(D79) L_(C674)R^(D146) R^(D5) L_(C99) R^(D99) R^(D99) L_(C291) R^(D9) R^(D17) L_(C483)R^(D55) R^(D81) L_(C675) R^(D146) R^(D17) L_(C100) R^(D100) R^(D100)L_(C292) R^(D9) R^(D18) L_(C484) R^(D55) R^(D87) L_(C676) R^(D146)R^(D18) L_(C101) R^(D101) R^(D101) L_(C293) R^(D9) R^(D20) L_(C485)R^(D55) R^(D88) L_(C677) R^(D146) R^(D20) L_(C102) R^(D102) R^(D102)L_(C294) R^(D9) R^(D22) L_(C486) R^(D55) R^(D89) L_(C678) R^(D146)R^(D22) L_(C103) R^(D103) R^(D103) L_(C295) R^(D9) R^(D37) L_(C487)R^(D55) R^(D93) L_(C679) R^(D146) R^(D37) L_(C104) R^(D104) R^(D104)L_(C296) R^(D9) R^(D40) L_(C488) R^(D55) R^(D116) L_(C680) R^(D146)R^(D40) L_(C105) R^(D105) R^(D105) L_(C297) R^(D9) R^(D41) L_(C489)R^(D55) R^(D117) L_(C681) R^(D146) R^(D41) L_(C106) R^(D106) R^(D106)L_(C298) R^(D9) R^(D42) L_(C490) R^(D55) R^(D118) L_(C682) R^(D146)R^(D42) L_(C107) R^(D107) R^(D107) L_(C299) R^(D9) R^(D43) L_(C491)R^(D55) R^(D119) L_(C683) R^(D146) R^(D43) L_(C108) R^(D108) R^(D108)L_(C300) R^(D9) R^(D48) L_(C492) R^(D55) R^(D120) L_(C684) R^(D146)R^(D48) L_(C109) R^(D109) R^(D109) L_(C301) R^(D9) R^(D49) L_(C493)R^(D55) R^(D133) L_(C685) R^(D146) R^(D49) L_(C110) R^(D110) R^(D110)L_(C302) R^(D9) R^(D50) L_(C494) R^(D55) R^(D134) L_(C686) R^(D146)R^(D54) L_(C111) R^(D111) R^(D111) L_(C303) R^(D9) R^(D54) L_(C495)R^(D55) R^(D135) L_(C687) R^(D146) R^(D58) L_(C112) R^(D112) R^(D112)L_(C304) R^(D9) R^(D55) L_(C496) R^(D55) R^(D136) L_(C688) R^(D146)R^(D59) L_(C113) R^(D113) R^(D113) L_(C305) R^(D9) R^(D58) L_(C497)R^(D55) R^(D143) L_(C689) R^(D146) R^(D78) L_(C114) R^(D114) R^(D114)L_(C306) R^(D9) R^(D59) L_(C498) R^(D55) R^(D144) L_(C690) R^(D146)R^(D79) L_(C115) R^(D115) R^(D115) L_(C307) R^(D9) R^(D78) L_(C499)R^(D55) R^(D145) L_(C691) R^(D146) R^(D81) L_(C116) R^(D116) R^(D116)L_(C308) R^(D9) R^(D79) L_(C500) R^(D55) R^(D146) L_(C692) R^(D146)R^(D87) L_(C117) R^(D117) R^(D117) L_(C309) R^(D9) R^(D81) L_(C501)R^(D55) R^(D147) L_(C693) R^(D146) R^(D88) L_(C118) R^(D118) R^(D118)L_(C310) R^(D9) R^(D87) L_(C502) R^(D55) R^(D149) L_(C694) R^(D146)R^(D89) L_(C119) R^(D119) R^(D119) L_(C311) R^(D9) R^(D88) L_(C503)R^(D55) R^(D151) L_(C695) R^(D146) R^(D93) L_(C120) R^(D120) R^(D120)L_(C312) R^(D9) R^(D89) L_(C504) R^(D55) R^(D154) L_(C696) R^(D146)R^(D117) L_(C121) R^(D121) R^(D121) L_(C313) R^(D9) R^(D93) L_(C505)R^(D55) R^(D155) L_(C697) R^(D146) R^(D118) L_(C122) R^(D122) R^(D122)L_(C314) R^(D9) R^(D116) L_(C506) R^(D55) R^(D161) L_(C698) R^(D146)R^(D119) L_(C123) R^(D123) R^(D123) L_(C315) R^(D9) R^(D117) L_(C507)R^(D55) R^(D175) L_(C699) R^(D146) R^(D120) L_(C124) R^(D124) R^(D124)L_(C316) R^(D9) R^(D118) L_(C508) R^(D116) R^(D3) L_(C700) R^(D146)R^(D133) L_(C125) R^(D125) R^(D125) L_(C317) R^(D9) R^(D119) L_(C509)R^(D116) R^(D5) L_(C701) R^(D146) R^(D134) L_(C126) R^(D126) R^(D126)L_(C318) R^(D9) R^(D120) L_(C510) R^(D116) R^(D17) L_(C702) R^(D146)R^(D135) L_(C127) R^(D127) R^(D127) L_(C319) R^(D9) R^(D133) L_(C511)R^(D116) R^(D18) L_(C703) R^(D146) R^(D136) L_(C128) R^(D128) R^(D128)L_(C320) R^(D9) R^(D134) L_(C512) R^(D116) R^(D20) L_(C704) R^(D146)R^(D146) L_(C129) R^(D129) R^(D129) L_(C321) R^(D9) R^(D135) L_(C513)R^(D116) R^(D22) L_(C705) R^(D146) R^(D147) L_(C130) R^(D130) R^(D130)L_(C322) R^(D9) R^(D136) L_(C514) R^(D116) R^(D37) L_(C706) R^(D146)R^(D149) L_(C131) R^(D131) R^(D131) L_(C323) R^(D9) R^(D143) L_(C515)R^(D116) R^(D40) L_(C707) R^(D146) R^(D151) L_(C132) R^(D132) R^(D132)L_(C324) R^(D9) R^(D144) L_(C516) R^(D116) R^(D41) L_(C708) R^(D146)R^(D154) L_(C133) R^(D133) R^(D133) L_(C325) R^(D9) R^(D145) L_(C517)R^(D116) R^(D42) L_(C709) R^(D146) R^(D155) L_(C134) R^(D134) R^(D134)L_(C326) R^(D9) R^(D146) L_(C518) R^(D116) R^(D43) L_(C710) R^(D146)R^(D161) L_(C135) R^(D135) R^(D135) L_(C327) R^(D9) R^(D147) L_(C519)R^(D116) R^(D48) L_(C711) R^(D146) R^(D175) L_(C136) R^(D136) R^(D136)L_(C328) R^(D9) R^(D149) L_(C520) R^(D116) R^(D49) L_(C712) R^(D133)R^(D3) L_(C137) R^(D137) R^(D137) L_(C329) R^(D9) R^(D151) L_(C521)R^(D116) R^(D54) L_(C713) R^(D133) R^(D5) L_(C138) R^(D138) R^(D138)L_(C330) R^(D9) R^(D154) L_(C522) R^(D116) R^(D58) L_(C714) R^(D133)R^(D3) L_(C139) R^(D139) R^(D139) L_(C331) R^(D9) R^(D155) L_(C523)R^(D116) R^(D59) L_(C715) R^(D133) R^(D18) L_(C140) R^(D140) R^(D140)L_(C332) R^(D9) R^(D161) L_(C524) R^(D116) R^(D78) L_(C716) R^(D133)R^(D20) L_(C141) R^(D141) R^(D141) L_(C333) R^(D9) R^(D175) L_(C525)R^(D116) R^(D79) L_(C717) R^(D133) R^(D22) L_(C142) R^(D142) R^(D142)L_(C334) R^(D10) R^(D3) L_(C526) R^(D116) R^(D81) L_(C718) R^(D133)R^(D37) L_(C143) R^(D143) R^(D143) L_(C335) R^(D10) R^(D5) L_(C527)R^(D116) R^(D87) L_(C719) R^(D133) R^(D40) L_(C144) R^(D144) R^(D144)L_(C336) R^(D10) R^(D17) L_(C528) R^(D116) R^(D88) L_(C720) R^(D133)R^(D41) L_(C145) R^(D145) R^(D145) L_(C337) R^(D10) R^(D18) L_(C529)R^(D116) R^(D89) L_(C721) R^(D133) R^(D42) L_(C146) R^(D146) R^(D146)L_(C338) R^(D10) R^(D20) L_(C530) R^(D116) R^(D93) L_(C722) R^(D133)R^(D43) L_(C147) R^(D147) R^(D147) L_(C339) R^(D10) R^(D22) L_(C531)R^(D116) R^(D117) L_(C723) R^(D133) R^(D48) L_(C148) R^(D148) R^(D148)L_(C340) R^(D10) R^(D37) L_(C532) R^(D116) R^(D118) L_(C724) R^(D133)R^(D49) L_(C149) R^(D149) R^(D149) L_(C341) R^(D10) R^(D40) L_(C533)R^(D116) R^(D119) L_(C725) R^(D133) R^(D54) L_(C150) R^(D150) R^(D150)L_(C342) R^(D10) R^(D41) L_(C534) R^(D116) R^(D120) L_(C726) R^(D133)R^(D58) L_(C151) R^(D151) R^(D151) L_(C343) R^(D10) R^(D42) L_(C535)R^(D116) R^(D133) L_(C727) R^(D133) R^(D59) L_(C152) R^(D152) R^(D152)L_(C344) R^(D10) R^(D43) L_(C536) R^(D116) R^(D134) L_(C728) R^(D133)R^(D78) L_(C153) R^(D153) R^(D153) L_(C345) R^(D10) R^(D48) L_(C537)R^(D116) R^(D135) L_(C729) R^(D133) R^(D79) L_(C154) R^(D154) R^(D154)L_(C346) R^(D10) R^(D49) L_(C538) R^(D116) R^(D136) L_(C730) R^(D133)R^(D81) L_(C155) R^(D155) R^(D155) L_(C347) R^(D10) R^(D50) L_(C539)R^(D116) R^(D143) L_(C731) R^(D133) R^(D87) L_(C156) R^(D156) R^(D156)L_(C348) R^(D10) R^(D54) L_(C540) R^(D116) R^(D144) L_(C732) R^(D133)R^(D88) L_(C157) R^(D157) R^(D157) L_(C349) R^(D10) R^(D55) L_(C541)R^(D116) R^(D145) L_(C733) R^(D133) R^(D89) L_(C158) R^(D158) R^(D158)L_(C350) R^(D10) R^(D58) L_(C542) R^(D116) R^(D146) L_(C734) R^(D133)R^(D93) L_(C159) R^(D159) R^(D159) L_(C351) R^(D10) R^(D59) L_(C543)R^(D116) R^(D147) L_(C735) R^(D133) R^(D117) L_(C160) R^(D160) R^(D160)L_(C352) R^(D10) R^(D78) L_(C544) R^(D116) R^(D149) L_(C736) R^(D133)R^(D118) L_(C161) R^(D161) R^(D161) L_(C353) R^(D10) R^(D79) L_(C545)R^(D116) R^(D151) L_(C737) R^(D133) R^(D119) L_(C162) R^(D162) R^(D162)L_(C354) R^(D10) R^(D81) L_(C546) R^(D116) R^(D154) L_(C738) R^(D133)R^(D120) L_(C163) R^(D163) R^(D163) L_(C355) R^(D10) R^(D87) L_(C547)R^(D116) R^(D155) L_(C739) R^(D133) R^(D133) L_(C164) R^(D164) R^(D164)L_(C356) R^(D10) R^(D88) L_(C548) R^(D116) R^(D161) L_(C740) R^(D133)R^(D134) L_(C165) R^(D165) R^(D165) L_(C357) R^(D10) R^(D89) L_(C549)R^(D116) R^(D175) L_(C741) R^(D133) R^(D135) L_(C166) R^(D166) R^(D166)L_(C358) R^(D10) R^(D93) L_(C550) R^(D143) R^(D3) L_(C742) R^(D133)R^(D136) L_(C167) R^(D167) R^(D167) L_(C359) R^(D10) R^(D116) L_(C551)R^(D143) R^(D5) L_(C743) R^(D133) R^(D146) L_(C168) R^(D168) R^(D168)L_(C360) R^(D10) R^(D117) L_(C552) R^(D143) R^(D17) L_(C744) R^(D133)R^(D147) L_(C169) R^(D169) R^(D169) L_(C361) R^(D10) R^(D118) L_(C553)R^(D143) R^(D18) L_(C745) R^(D133) R^(D149) L_(C170) R^(D170) R^(D170)L_(C362) R^(D10) R^(D119) L_(C554) R^(D143) R^(D20) L_(C746) R^(D133)R^(D151) L_(C171) R^(D171) R^(D171) L_(C363) R^(D10) R^(D120) L_(C555)R^(D143) R^(D22) L_(C747) R^(D133) R^(D154) L_(C172) R^(D172) R^(D172)L_(C364) R^(D10) R^(D133) L_(C556) R^(D143) R^(D37) L_(C748) R^(D133)R^(D155) L_(C173) R^(D173) R^(D173) L_(C365) R^(D10) R^(D134) L_(C557)R^(D143) R^(D40) L_(C749) R^(D133) R^(D161) L_(C174) R^(D174) R^(D174)L_(C366) R^(D10) R^(D135) L_(C558) R^(D143) R^(D41) L_(C750) R^(D133)R^(D175) L_(C175) R^(D175) R^(D175) L_(C367) R^(D10) R^(D136) L_(C559)R^(D143) R^(D42) L_(C751) R^(D175) R^(D3) L_(C176) R^(D176) R^(D176)L_(C368) R^(D10) R^(D143) L_(C560) R^(D143) R^(D43) L_(C752) R^(D175)R^(D5) L_(C177) R^(D177) R^(D177) L_(C369) R^(D10) R^(D144) L_(C561)R^(D143) R^(D48) L_(C753) R^(D175) R^(D18) L_(C178) R^(D178) R^(D178)L_(C370) R^(D10) R^(D145) L_(C562) R^(D143) R^(D49) L_(C754) R^(D175)R^(D20) L_(C179) R^(D179) R^(D179) L_(C371) R^(D10) R^(D146) L_(C563)R^(D143) R^(D54) L_(C755) R^(D175) R^(D22) L_(C180) R^(D180) R^(D180)L_(C372) R^(D10) R^(D147) L_(C564) R^(D143) R^(D58) L_(C756) R^(D175)R^(D37) L_(C181) R^(D181) R^(D181) L_(C373) R^(D10) R^(D149) L_(C565)R^(D143) R^(D59) L_(C757) R^(D175) R^(D40) L_(C182) R^(D182) R^(D182)L_(C374) R^(D10) R^(D151) L_(C566) R^(D143) R^(D78) L_(C758) R^(D175)R^(D41) L_(C183) R^(D183) R^(D183) L_(C375) R^(D10) R^(D154) L_(C567)R^(D143) R^(D79) L_(C759) R^(D175) R^(D42) L_(C184) R^(D184) R^(D184)L_(C376) R^(D10) R^(D155) L_(C568) R^(D143) R^(D81) L_(C760) R^(D175)R^(D43) L_(C185) R^(D185) R^(D185) L_(C377) R^(D10) R^(D161) L_(C569)R^(D143) R^(D87) L_(C761) R^(D175) R^(D48) L_(C186) R^(D186) R^(D186)L_(C378) R^(D10) R^(D175) L_(C570) R^(D143) R^(D88) L_(C762) R^(D175)R^(D49) L_(C187) R^(D187) R^(D187) L_(C379) R^(D17) R^(D3) L_(C571)R^(D143) R^(D89) L_(C763) R^(D175) R^(D54) L_(C188) R^(D188) R^(D188)L_(C380) R^(D17) R^(D5) L_(C572) R^(D143) R^(D93) L_(C764) R^(D175)R^(D58) L_(C189) R^(D189) R^(D189) L_(C381) R^(D17) R^(D18) L_(C573)R^(D143) R^(D116) L_(C765) R^(D175) R^(D59) L_(C190) R^(D190) R^(D190)L_(C382) R^(D17) R^(D20) L_(C574) R^(D143) R^(D117) L_(C766) R^(D175)R^(D78) L_(C191) R^(D191) R^(D191) L_(C383) R^(D17) R^(D22) L_(C575)R^(D143) R^(D118) L_(C767) R^(D175) R^(D79) L_(C192) R^(D192) R^(D192)L_(C384) R^(D17) R^(D37) L_(C576) R^(D143) R^(D119) L_(C768) R^(D175)R^(D81) L_(C769) R^(D193) R^(D193) L_(C877) R^(D1) R^(D193) L_(C985)R^(D4) R^(D193) L_(C1093) R^(D9) R^(D193) L_(C770) R^(D194) R^(D194)L_(C878) R^(D1) R^(D194) L_(C986) R^(D4) R^(D194) L_(C1094) R^(D9)R^(D194) L_(C771) R^(D195) R^(D195) L_(C879) R^(D1) R^(D195) L_(C987)R^(D4) R^(D195) L_(C1095) R^(D9) R^(D195) L_(C772) R^(D196) R^(D196)L_(C880) R^(D1) R^(D196) L_(C988) R^(D4) R^(D196) L_(C1096) R^(D9)R^(D196) L_(C773) R^(D197) R^(D197) L_(C881) R^(D1) R^(D197) L_(C989)R^(D4) R^(D197) L_(C1097) R^(D9) R^(D197) L_(C774) R^(D198) R^(D198)L_(C882) R^(D1) R^(D198) L_(C990) R^(D4) R^(D198) L_(C1098) R^(D9)R^(D198) L_(C775) R^(D199) R^(D199) L_(C883) R^(D1) R^(D199) L_(C991)R^(D4) R^(D199) L_(C1099) R^(D9) R^(D199) L_(C776) R^(D200) R^(D200)L_(C884) R^(D1) R^(D200) L_(C992) R^(D4) R^(D200) L_(C1100) R^(D9)R^(D200) L_(C777) R^(D201) R^(D201) L_(C885) R^(D1) R^(D201) L_(C993)R^(D4) R^(D201) L_(C1101) R^(D9) R^(D201) L_(C778) R^(D202) R^(D202)L_(C886) R^(D1) R^(D202) L_(C994) R^(D4) R^(D202) L_(C1102) R^(D9)R^(D202) L_(C779) R^(D203) R^(D203) L_(C887) R^(D1) R^(D203) L_(C995)R^(D4) R^(D203) L_(C1103) R^(D9) R^(D203) L_(C780) R^(D204) R^(D204)L_(C888) R^(D1) R^(D204) L_(C996) R^(D4) R^(D204) L_(C1104) R^(D9)R^(D204) L_(C781) R^(D205) R^(D205) L_(C889) R^(D1) R^(D205) L_(C997)R^(D4) R^(D205) L_(C1105) R^(D9) R^(D205) L_(C782) R^(D206) R^(D206)L_(C890) R^(D1) R^(D206) L_(C998) R^(D4) R^(D206) L_(C1106) R^(D9)R^(D206) L_(C783) R^(D207) R^(D207) L_(C891) R^(D1) R^(D207) L_(C999)R^(D4) R^(D207) L_(C1107) R^(D9) R^(D207) L_(C784) R^(D208) R^(D208)L_(C892) R^(D1) R^(D208) L_(C1000) R^(D4) R^(D208) L_(C1108) R^(D9)R^(D208) L_(C785) R^(D209) R^(D209) L_(C893) R^(D1) R^(D209) L_(C1001)R^(D4) R^(D209) L_(C1109) R^(D9) R^(D209) L_(C786) R^(D210) R^(D210)L_(C894) R^(D1) R^(D210) L_(C1002) R^(D4) R^(D210) L_(C1110) R^(D9)R^(D210) L_(C787) R^(D211) R^(D211) L_(C895) R^(D1) R^(D211) L_(C1003)R^(D4) R^(D211) L_(C1111) R^(D9) R^(D211) L_(C788) R^(D212) R^(D212)L_(C896) R^(D1) R^(D212) L_(C1004) R^(D4) R^(D212) L_(C1112) R^(D9)R^(D212) L_(C789) R^(D213) R^(D213) L_(C897) R^(D1) R^(D213) L_(C1005)R^(D4) R^(D213) L_(C1113) R^(D9) R^(D213) L_(C790) R^(D214) R^(D214)L_(C898) R^(D1) R^(D214) L_(C1006) R^(D4) R^(D214) L_(C1114) R^(D9)R^(D214) L_(C791) R^(D215) R^(D215) L_(C899) R^(D1) R^(D215) L_(C1007)R^(D4) R^(D215) L_(C1115) R^(D9) R^(D215) L_(C792) R^(D216) R^(D216)L_(C900) R^(D1) R^(D216) L_(C1008) R^(D4) R^(D216) L_(C1116) R^(D9)R^(D216) L_(C793) R^(D217) R^(D217) L_(C901) R^(D1) R^(D217) L_(C1009)R^(D4) R^(D217) L_(C1117) R^(D9) R^(D217) L_(C794) R^(D218) R^(D218)L_(C902) R^(D1) R^(D218) L_(C1010) R^(D4) R^(D218) L_(C1118) R^(D9)R^(D218) L_(C795) R^(D219) R^(D219) L_(C903) R^(D1) R^(D219) L_(C1011)R^(D4) R^(D219) L_(C1119) R^(D9) R^(D219) L_(C796) R^(D220) R^(D220)L_(C904) R^(D1) R^(D220) L_(C1012) R^(D4) R^(D220) L_(C1120) R^(D9)R^(D220) L_(C797) R^(D221) R^(D221) L_(C905) R^(D1) R^(D221) L_(C1013)R^(D4) R^(D221) L_(C1121) R^(D9) R^(D221) L_(C798) R^(D222) R^(D222)L_(C906) R^(D1) R^(D222) L_(C1014) R^(D4) R^(D222) L_(C1122) R^(D9)R^(D222) L_(C799) R^(D223) R^(D223) L_(C907) R^(D1) R^(D223) L_(C1015)R^(D4) R^(D223) L_(C1123) R^(D9) R^(D223) L_(C800) R^(D224) R^(D224)L_(C908) R^(D1) R^(D224) L_(C1016) R^(D4) R^(D224) L_(C1124) R^(D9)R^(D224) L_(C801) R^(D225) R^(D225) L_(C909) R^(D1) R^(D225) L_(C1017)R^(D4) R^(D225) L_(C1125) R^(D9) R^(D225) L_(C802) R^(D226) R^(D226)L_(C910) R^(D1) R^(D226) L_(C1018) R^(D4) R^(D226) L_(C1126) R^(D9)R^(D226) L_(C803) R^(D227) R^(D227) L_(C911) R^(D1) R^(D227) L_(C1019)R^(D4) R^(D227) L_(C1127) R^(D9) R^(D227) L_(C804) R^(D228) R^(D228)L_(C912) R^(D1) R^(D228) L_(C1020) R^(D4) R^(D228) L_(C1128) R^(D9)R^(D228) L_(C805) R^(D229) R^(D229) L_(C913) R^(D1) R^(D229) L_(C1021)R^(D4) R^(D229) L_(C1129) R^(D9) R^(D229) L_(C806) R^(D230) R^(D230)L_(C914) R^(D1) R^(D230) L_(C1022) R^(D4) R^(D230) L_(C1130) R^(D9)R^(D230) L_(C807) R^(D231) R^(D231) L_(C915) R^(D1) R^(D231) L_(C1023)R^(D4) R^(D231) L_(C1131) R^(D9) R^(D231) L_(C808) R^(D232) R^(D232)L_(C916) R^(D1) R^(D232) L_(C1024) R^(D4) R^(D232) L_(C1132) R^(D9)R^(D232) L_(C809) R^(D233) R^(D233) L_(C917) R^(D1) R^(D233) L_(C1025)R^(D4) R^(D233) L_(C1133) R^(D9) R^(D233) L_(C810) R^(D234) R^(D234)L_(C918) R^(D1) R^(D234) L_(C1026) R^(D4) R^(D234) L_(C1134) R^(D9)R^(D234) L_(C811) R^(D235) R^(D235) L_(C919) R^(D1) R^(D235) L_(C1027)R^(D4) R^(D235) L_(C1135) R^(D9) R^(D235) L_(C812) R^(D236) R^(D236)L_(C920) R^(D1) R^(D236) L_(C1028) R^(D4) R^(D236) L_(C1136) R^(D9)R^(D236) L_(C813) R^(D237) R^(D237) L_(C921) R^(D1) R^(D237) L_(C1029)R^(D4) R^(D237) L_(C1137) R^(D9) R^(D237) L_(C814) R^(D238) R^(D238)L_(C922) R^(D1) R^(D238) L_(C1030) R^(D4) R^(D238) L_(C1138) R^(D9)R^(D238) L_(C815) R^(D239) R^(D239) L_(C923) R^(D1) R^(D239) L_(C1031)R^(D4) R^(D239) L_(C1139) R^(D9) R^(D239) L_(C816) R^(D240) R^(D240)L_(C924) R^(D1) R^(D240) L_(C1032) R^(D4) R^(D240) L_(C1140) R^(D9)R^(D240) L_(C817) R^(D241) R^(D241) L_(C925) R^(D1) R^(D241) L_(C1033)R^(D4) R^(D241) L_(C1141) R^(D9) R^(D241) L_(C818) R^(D242) R^(D242)L_(C926) R^(D1) R^(D242) L_(C1034) R^(D4) R^(D242) L_(C1142) R^(D9)R^(D242) L_(C819) R^(D243) R^(D243) L_(C927) R^(D1) R^(D243) L_(C1035)R^(D4) R^(D243) L_(C1143) R^(D9) R^(D243) L_(C820) R^(D244) R^(D244)L_(C928) R^(D1) R^(D244) L_(C1036) R^(D4) R^(D244) L_(C1144) R^(D9)R^(D244) L_(C821) R^(D245) R^(D245) L_(C929) R^(D1) R^(D245) L_(C1037)R^(D4) R^(D245) L_(C1145) R^(D9) R^(D245) L_(C822) R^(D246) R^(D246)L_(C930) R^(D1) R^(D246) L_(C1038) R^(D4) R^(D246) L_(C1146) R^(D9)R^(D246) L_(C823) R^(D17) R^(D193) L_(C931) R^(D50) R^(D193) L_(C1039)R^(D145) R^(D193) L_(C1147) R^(D168) R^(D193) L_(C824) R^(D17) R^(D194)L_(C932) R^(D50) R^(D194) L_(C1040) R^(D145) R^(D194) L_(C1148) R^(D168)R^(D194) L_(C825) R^(D17) R^(D195) L_(C933) R^(D50) R^(D195) L_(C1041)R^(D145) R^(D195) L_(C1149) R^(D168) R^(D195) L_(C826) R^(D17) R^(D196)L_(C934) R^(D50) R^(D196) L_(C1042) R^(D145) R^(D196) L_(C1150) R^(D168)R^(D196) L_(C827) R^(D17) R^(D197) L_(C935) R^(D50) R^(D197) L_(C1043)R^(D145) R^(D197) L_(C1151) R^(D168) R^(D197) L_(C828) R^(D17) R^(D198)L_(C936) R^(D50) R^(D198) L_(C1044) R^(D145) R^(D198) L_(C1152) R^(D168)R^(D198) L_(C829) R^(D17) R^(D199) L_(C937) R^(D50) R^(D199) L_(C1045)R^(D145) R^(D199) L_(C1153) R^(D168) R^(D199) L_(C830) R^(D17) R^(D200)L_(C938) R^(D50) R^(D200) L_(C1046) R^(D145) R^(D200) L_(C1154) R^(D168)R^(D200) L_(C831) R^(D17) R^(D201) L_(C939) R^(D50) R^(D201) L_(C1047)R^(D145) R^(D201) L_(C1155) R^(D168) R^(D201) L_(C832) R^(D17) R^(D202)L_(C940) R^(D50) R^(D202) L_(C1048) R^(D145) R^(D202) L_(C1156) R^(D168)R^(D202) L_(C833) R^(D17) R^(D203) L_(C941) R^(D50) R^(D203) L_(C1049)R^(D145) R^(D203) L_(C1157) R^(D168) R^(D203) L_(C834) R^(D17) R^(D204)L_(C942) R^(D50) R^(D204) L_(C1050) R^(D145) R^(D204) L_(C1158) R^(D168)R^(D204) L_(C835) R^(D17) R^(D205) L_(C943) R^(D50) R^(D205) L_(C1051)R^(D145) R^(D205) L_(C1159) R^(D168) R^(D205) L_(C836) R^(D17) R^(D206)L_(C944) R^(D50) R^(D206) L_(C1052) R^(D145) R^(D206) L_(C1160) R^(D168)R^(D206) L_(C837) R^(D17) R^(D207) L_(C945) R^(D50) R^(D207) L_(C1053)R^(D145) R^(D207) L_(C1161) R^(D168) R^(D207) L_(C838) R^(D17) R^(D208)L_(C946) R^(D50) R^(D208) L_(C1054) R^(D145) R^(D208) L_(C1162) R^(D168)R^(D208) L_(C839) R^(D17) R^(D209) L_(C947) R^(D50) R^(D209) L_(C1055)R^(D145) R^(D209) L_(C1163) R^(D168) R^(D209) L_(C840) R^(D17) R^(D210)L_(C948) R^(D50) R^(D210) L_(C1056) R^(D145) R^(D210) L_(C1164) R^(D168)R^(D210) L_(C841) R^(D17) R^(D211) L_(C949) R^(D50) R^(D211) L_(C1057)R^(D145) R^(D211) L_(C1165) R^(D168) R^(D211) L_(C842) R^(D17) R^(D212)L_(C950) R^(D50) R^(D212) L_(C1058) R^(D145) R^(D212) L_(C1166) R^(D168)R^(D212) L_(C843) R^(D17) R^(D213) L_(C951) R^(D50) R^(D213) L_(C1059)R^(D145) R^(D213) L_(C1167) R^(D168) R^(D213) L_(C844) R^(D17) R^(D214)L_(C952) R^(D50) R^(D214) L_(C1060) R^(D145) R^(D214) L_(C1168) R^(D168)R^(D214) L_(C845) R^(D17) R^(D215) L_(C953) R^(D50) R^(D215) L_(C1061)R^(D145) R^(D215) L_(C1169) R^(D168) R^(D215) L_(C846) R^(D17) R^(D216)L_(C954) R^(D50) R^(D216) L_(C1062) R^(D145) R^(D216) L_(C1170) R^(D168)R^(D216) L_(C847) R^(D17) R^(D217) L_(C955) R^(D50) R^(D217) L_(C1063)R^(D145) R^(D217) L_(C1171) R^(D168) R^(D217) L_(C848) R^(D17) R^(D218)L_(C956) R^(D50) R^(D218) L_(C1064) R^(D145) R^(D218) L_(C1172) R^(D168)R^(D218) L_(C849) R^(D17) R^(D219) L_(C957) R^(D50) R^(D219) L_(C1065)R^(D145) R^(D219) L_(C1173) R^(D168) R^(D219) L_(C850) R^(D17) R^(D220)L_(C958) R^(D50) R^(D220) L_(C1066) R^(D145) R^(D220) L_(C1174) R^(D168)R^(D220) L_(C851) R^(D17) R^(D221) L_(C959) R^(D50) R^(D221) L_(C1067)R^(D145) R^(D221) L_(C1175) R^(D168) R^(D221) L_(C852) R^(D17) R^(D222)L_(C960) R^(D50) R^(D222) L_(C1068) R^(D145) R^(D222) L_(C1176) R^(D168)R^(D222) L_(C853) R^(D17) R^(D223) L_(C961) R^(D50) R^(D223) L_(C1069)R^(D145) R^(D223) L_(C1177) R^(D168) R^(D223) L_(C854) R^(D17) R^(D224)L_(C962) R^(D50) R^(D224) L_(C1070) R^(D145) R^(D224) L_(C1178) R^(D168)R^(D224) L_(C855) R^(D17) R^(D225) L_(C963) R^(D50) R^(D225) L_(C1071)R^(D145) R^(D225) L_(C1179) R^(D168) R^(D225) L_(C856) R^(D17) R^(D226)L_(C964) R^(D50) R^(D226) L_(C1072) R^(D145) R^(D226) L_(C1180) R^(D168)R^(D226) L_(C857) R^(D17) R^(D227) L_(C965) R^(D50) R^(D227) L_(C1073)R^(D145) R^(D227) L_(C1181) R^(D168) R^(D227) L_(C858) R^(D17) R^(D228)L_(C966) R^(D50) R^(D228) L_(C1074) R^(D145) R^(D228) L_(C1182) R^(D168)R^(D228) L_(C859) R^(D17) R^(D229) L_(C967) R^(D50) R^(D229) L_(C1075)R^(D145) R^(D229) L_(C1183) R^(D168) R^(D229) L_(C860) R^(D17) R^(D230)L_(C968) R^(D50) R^(D230) L_(C1076) R^(D145) R^(D230) L_(C1184) R^(D168)R^(D230) L_(C861) R^(D17) R^(D231) L_(C969) R^(D50) R^(D231) L_(C1077)R^(D145) R^(D231) L_(C1185) R^(D168) R^(D231) L_(C862) R^(D17) R^(D232)L_(C970) R^(D50) R^(D232) L_(C1078) R^(D145) R^(D232) L_(C1186) R^(D168)R^(D232) L_(C863) R^(D17) R^(D233) L_(C971) R^(D50) R^(D233) L_(C1079)R^(D145) R^(D233) L_(C1187) R^(D168) R^(D233) L_(C864) R^(D17) R^(D234)L_(C972) R^(D50) R^(D234) L_(C1080) R^(D145) R^(D234) L_(C1188) R^(D168)R^(D234) L_(C865) R^(D17) R^(D235) L_(C973) R^(D50) R^(D235) L_(C1081)R^(D145) R^(D235) L_(C1189) R^(D168) R^(D235) L_(C866) R^(D17) R^(D236)L_(C974) R^(D50) R^(D236) L_(C1082) R^(D145) R^(D236) L_(C1190) R^(D168)R^(D236) L_(C867) R^(D17) R^(D237) L_(C975) R^(D50) R^(D237) L_(C1083)R^(D145) R^(D237) L_(C1191) R^(D168) R^(D237) L_(C868) R^(D17) R^(D238)L_(C976) R^(D50) R^(D238) L_(C1084) R^(D145) R^(D238) L_(C1192) R^(D168)R^(D238) L_(C869) R^(D17) R^(D239) L_(C977) R^(D50) R^(D239) L_(C1085)R^(D145) R^(D239) L_(C1193) R^(D168) R^(D239) L_(C870) R^(D17) R^(D240)L_(C978) R^(D50) R^(D240) L_(C1086) R^(D145) R^(D240) L_(C1194) R^(D168)R^(D240) L_(C871) R^(D17) R^(D241) L_(C979) R^(D50) R^(D241) L_(C1087)R^(D145) R^(D241) L_(C1195) R^(D168) R^(D241) L_(C872) R^(D17) R^(D242)L_(C980) R^(D50) R^(D242) L_(C1088) R^(D145) R^(D242) L_(C1196) R^(D168)R^(D242) L_(C873) R^(D17) R^(D243) L_(C981) R^(D50) R^(D243) L_(C1089)R^(D145) R^(D243) L_(C1197) R^(D168) R^(D243) L_(C874) R^(D17) R^(D244)L_(C982) R^(D50) R^(D244) L_(C1090) R^(D145) R^(D244) L_(C1198) R^(D168)R^(D244) L_(C875) R^(D17) R^(D245) L_(C983) R^(D50) R^(D245) L_(C1091)R^(D145) R^(D245) L_(C1199) R^(D168) R^(D245) L_(C876) R^(D17) R^(D246)L_(C984) R^(D50) R^(D246) L_(C1092) R^(D145) R^(D246) L_(C1200) R^(D168)R^(D246) L_(C1201) R^(D10) R^(D193) L_(C1255) R^(D55) R^(D193) L_(C1309)R^(D37) R^(D193) L_(C1363) R^(D143) R^(D193) L_(C1202) R^(D10) R^(D194)L_(C1256) R^(D55) R^(D194) L_(C1310) R^(D37) R^(D194) L_(C1364) R^(D143)R^(D194) L_(C1203) R^(D10) R^(D195) L_(C1257) R^(D55) R^(D195) L_(C1311)R^(D37) R^(D195) L_(C1365) R^(D143) R^(D195) L_(C1204) R^(D10) R^(D196)L_(C1258) R^(D55) R^(D196) L_(C1312) R^(D37) R^(D196) L_(C1366) R^(D143)R^(D196) L_(C1205) R^(D10) R^(D197) L_(C1259) R^(D55) R^(D197) L_(C1313)R^(D37) R^(D197) L_(C1367) R^(D143) R^(D197) L_(C1206) R^(D10) R^(D198)L_(C1260) R^(D55) R^(D198) L_(C1314) R^(D37) R^(D198) L_(C1368) R^(D143)R^(D198) L_(C1207) R^(D10) R^(D199) L_(C1261) R^(D55) R^(D199) L_(C1315)R^(D37) R^(D199) L_(C1369) R^(D143) R^(D199) L_(C1208) R^(D10) R^(D200)L_(C1262) R^(D55) R^(D200) L_(C1316) R^(D37) R^(D200) L_(C1370) R^(D143)R^(D200) L_(C1209) R^(D10) R^(D201) L_(C1263) R^(D55) R^(D201) L_(C1317)R^(D37) R^(D201) L_(C1371) R^(D143) R^(D201) L_(C1210) R^(D10) R^(D202)L_(C1264) R^(D55) R^(D202) L_(C1318) R^(D37) R^(D202) L_(C1372) R^(D143)R^(D202) L_(C1211) R^(D10) R^(D203) L_(C1265) R^(D55) R^(D203) L_(C1319)R^(D37) R^(D203) L_(C1373) R^(D143) R^(D203) L_(C1212) R^(D10) R^(D204)L_(C1266) R^(D55) R^(D204) L_(C1320) R^(D37) R^(D204) L_(C1374) R^(D143)R^(D204) L_(C1213) R^(D10) R^(D205) L_(C1267) R^(D55) R^(D205) L_(C1321)R^(D37) R^(D205) L_(C1375) R^(D143) R^(D205) L_(C1214) R^(D10) R^(D206)L_(C1268) R^(D55) R^(D206) L_(C1322) R^(D37) R^(D206) L_(C1376) R^(D143)R^(D206) L_(C1215) R^(D10) R^(D207) L_(C1269) R^(D55) R^(D207) L_(C1323)R^(D37) R^(D207) L_(C1377) R^(D143) R^(D207) L_(C1216) R^(D10) R^(D208)L_(C1270) R^(D55) R^(D208) L_(C1324) R^(D37) R^(D208) L_(C1378) R^(D143)R^(D208) L_(C1217) R^(D10) R^(D209) L_(C1271) R^(D55) R^(D209) L_(C1325)R^(D37) R^(D209) L_(C1379) R^(D143) R^(D209) L_(C1218) R^(D10) R^(D210)L_(C1272) R^(D55) R^(D210) L_(C1326) R^(D37) R^(D210) L_(C1380) R^(D143)R^(D210) L_(C1219) R^(D10) R^(D211) L_(C1273) R^(D55) R^(D211) L_(C1327)R^(D37) R^(D211) L_(C1381) R^(D143) R^(D211) L_(C1220) R^(D10) R^(D212)L_(C1274) R^(D55) R^(D212) L_(C1328) R^(D37) R^(D212) L_(C1382) R^(D143)R^(D212) L_(C1221) R^(D10) R^(D213) L_(C1275) R^(D55) R^(D213) L_(C1329)R^(D37) R^(D213) L_(C1383) R^(D143) R^(D213) L_(C1222) R^(D10) R^(D214)L_(C1276) R^(D55) R^(D214) L_(C1330) R^(D37) R^(D214) L_(C1384) R^(D143)R^(D214) L_(C1223) R^(D10) R^(D215) L_(C1277) R^(D55) R^(D215) L_(C1331)R^(D37) R^(D215) L_(C1385) R^(D143) R^(D215) L_(C1224) R^(D10) R^(D216)L_(C1278) R^(D55) R^(D216) L_(C1332) R^(D37) R^(D216) L_(C1386) R^(D143)R^(D216) L_(C1225) R^(D10) R^(D217) L_(C1279) R^(D55) R^(D217) L_(C1333)R^(D37) R^(D217) L_(C1387) R^(D143) R^(D217) L_(C1226) R^(D10) R^(D218)L_(C1280) R^(D55) R^(D218) L_(C1334) R^(D37) R^(D218) L_(C1388) R^(D143)R^(D218) L_(C1227) R^(D10) R^(D219) L_(C1281) R^(D55) R^(D219) L_(C1335)R^(D37) R^(D219) L_(C1389) R^(D143) R^(D219) L_(C1228) R^(D10) R^(D220)L_(C1282) R^(D55) R^(D220) L_(C1336) R^(D37) R^(D220) L_(C1390) R^(D143)R^(D220) L_(C1229) R^(D10) R^(D221) L_(C1283) R^(D55) R^(D221) L_(C1337)R^(D37) R^(D221) L_(C1391) R^(D143) R^(D221) L_(C1230) R^(D10) R^(D222)L_(C1284) R^(D55) R^(D222) L_(C1338) R^(D37) R^(D222) L_(C1392) R^(D143)R^(D222) L_(C1231) R^(D10) R^(D223) L_(C1285) R^(D55) R^(D223) L_(C1339)R^(D37) R^(D223) L_(C1393) R^(D143) R^(D223) L_(C1232) R^(D10) R^(D224)L_(C1286) R^(D55) R^(D224) L_(C1340) R^(D37) R^(D224) L_(C1394) R^(D143)R^(D224) L_(C1233) R^(D10) R^(D225) L_(C1287) R^(D55) R^(D225) L_(C1341)R^(D37) R^(D225) L_(C1395) R^(D143) R^(D225) L_(C1234) R^(D10) R^(D226)L_(C1288) R^(D55) R^(D226) L_(C1342) R^(D37) R^(D226) L_(C1396) R^(D143)R^(D226) L_(C1235) R^(D10) R^(D227) L_(C1289) R^(D55) R^(D227) L_(C1343)R^(D37) R^(D227) L_(C1397) R^(D143) R^(D227) L_(C1236) R^(D10) R^(D228)L_(C1290) R^(D55) R^(D228) L_(C1344) R^(D37) R^(D228) L_(C1398) R^(D143)R^(D228) L_(C1237) R^(D10) R^(D229) L_(C1291) R^(D55) R^(D229) L_(C1345)R^(D37) R^(D229) L_(C1399) R^(D143) R^(D229) L_(C1238) R^(D10) R^(D230)L_(C1292) R^(D55) R^(D230) L_(C1346) R^(D37) R^(D230) L_(C1400) R^(D143)R^(D230) L_(C1239) R^(D10) R^(D231) L_(C1293) R^(D55) R^(D231) L_(C1347)R^(D37) R^(D231) L_(C1401) R^(D143) R^(D231) L_(C1240) R^(D10) R^(D232)L_(C1294) R^(D55) R^(D232) L_(C1348) R^(D37) R^(D232) L_(C1402) R^(D143)R^(D232) L_(C1241) R^(D10) R^(D233) L_(C1295) R^(D55) R^(D233) L_(C1349)R^(D37) R^(D233) L_(C1403) R^(D143) R^(D233) L_(C1242) R^(D10) R^(D234)L_(C1296) R^(D55) R^(D234) L_(C1350) R^(D37) R^(D234) L_(C1404) R^(D143)R^(D234) L_(C1243) R^(D10) R^(D235) L_(C1297) R^(D55) R^(D235) L_(C1351)R^(D37) R^(D235) L_(C1405) R^(D143) R^(D235) L_(C1244) R^(D10) R^(D236)L_(C1298) R^(D55) R^(D236) L_(C1352) R^(D37) R^(D236) L_(C1406) R^(D143)R^(D236) L_(C1245) R^(D10) R^(D237) L_(C1299) R^(D55) R^(D237) L_(C1353)R^(D37) R^(D237) L_(C1407) R^(D143) R^(D237) L_(C1246) R^(D10) R^(D238)L_(C1300) R^(D55) R^(D238) L_(C1354) R^(D37) R^(D238) L_(C1408) R^(D143)R^(D238) L_(C1247) R^(D10) R^(D239) L_(C1301) R^(D55) R^(D239) L_(C1355)R^(D37) R^(D239) L_(C1409) R^(D143) R^(D239) L_(C1248) R^(D10) R^(D240)L_(C1302) R^(D55) R^(D240) L_(C1356) R^(D37) R^(D240) L_(C1410) R^(D143)R^(D240) L_(C1249) R^(D10) R^(D241) L_(C1303) R^(D55) R^(D241) L_(C1357)R^(D37) R^(D241) L_(C1411) R^(D143) R^(D241) L_(C1250) R^(D10) R^(D242)L_(C1304) R^(D55) R^(D242) L_(C1358) R^(D37) R^(D242) L_(C1412) R^(D143)R^(D242) L_(C1251) R^(D10) R^(D243) L_(C1305) R^(D55) R^(D243) L_(C1359)R^(D37) R^(D243) L_(C1413) R^(D143) R^(D243) L_(C1252) R^(D10) R^(D244)L_(C1306) R^(D55) R^(D244) L_(C1360) R^(D37) R^(D244) L_(C1414) R^(D143)R^(D244) L_(C1253) R^(D10) R^(D245) L_(C1307) R^(D55) R^(D245) L_(C1361)R^(D37) R^(D245) L_(C1415) R^(D143) R^(D245) L_(C1254) R^(D10) R^(D246)L_(C1308) R^(D55) R^(D246) L_(C1362) R^(D37) R^(D246) L_(C1416) R^(D143)R^(D246)wherein R^(D1) to R^(D246) have the following structures:

In some embodiments, where the compound has the formulaIr(L_(Ah-m))(L_(Bk))₂ or Ir(L_(Ah-m))₂(L_(Bk)), the compound is selectedfrom the group consisting of only those compound structures that haveone of the L_(Bk) ligand structures in the following LIST 7:

In some embodiments, where the compound has the formulaIr(L_(Ah-m))(L_(Bk))₂ or Ir(L_(Ah-m))₂(L_(Bk)), the compound is selectedfrom the group consisting of only those compound structures that haveone of the L_(Bk) ligand structures in the following LIST 8:

In some embodiments, where the compound has the formulaIr(L_(Ah-m))₂(L_(Cj-I)) or Ir(L_(Ah-m))₂(L_(Cj-II)), the compound isselected from the group consisting of only those compound structuresthat have L_(Cj-I) or L_(Cj-II), ligands whose corresponding R²⁰¹ andR²⁰² are defined to be one the following structures:

In some embodiments, wherein the compound has the formulaIr(L_(Ah-m))₂(L_(Cj-1)) or Ir(L_(Ah-m))₂(L_(Cj-II)), the compound isselected from the group consisting of only those compound structuresthat have L_(Cj-I) or L_(Cj-II) ligands whose corresponding R²⁰¹ andR²⁰² are defined to be one the following structures:

In some embodiments, wherein the compound has the formulaIr(L_(Ah-m))₂(L_(Cj-I)), the compound is selected from the groupconsisting of only those compound structures that have L_(Cj-I) ligandswhose corresponding R²⁰¹ and R²⁰² are defined to be one the followingstructures:

In some embodiments, the compound can be selected from the groupconsisting of the structures in the following LIST 9:

wherein R^(M), R^(N), and R^(Y) are each independently H, D, F, alkyl,cycloalkyl, aryl, heteroaryl, or combinations thereof,

In some embodiments, the compound can be selected from the groupconsisting of the structures in the following LIST 10:

C. The Methods of Preparing the Compounds of the Present Disclosure

The compounds of the present disclosure may be prepared by variousmethods, one of which is illustrated in the following scheme. It shouldbe understood that modifications of the reaction conditions and/orreaction sequences, and/or protected reaction materials may be necessaryin order to prepare some of these compounds.

D. The OLEDs and the Devices of the Present Disclosure

In another aspect, the present disclosure also provides an OLED devicecomprising an organic layer that contains a compound as disclosed in theabove compounds section of the present disclosure.

In some embodiments, the organic layer can comprise an Ir compoundcomprising a ligand L_(A) of

wherein X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of the general substituents defined herein; atleast two adjacent R′ substituents are joined to form a fused 5-memberedcarbocyclic or heterocyclic ring; and additional substituents can bejoined or fused to form a ring, wherein Ir is coordinated to the ligandL_(A) of Formula I by the two dashed lines, and can be coordinated toadditional ligands; and wherein the ligand L_(A) can be joined withadditional ligands to form a tridentate, tetradentate, pentadentate, orhexadentate ligand.

In some embodiments, the organic layer may be an emissive layer and thecompound as described herein may be an emissive dopant or a non-emissivedopant.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a triphenylene containing benzo-fusedthiophene or benzo-fused furan, wherein any substituent in the host isan unfused substituent independently selected from the group consistingof C_(n)H_(2n+1), OC_(n)H_(2n+1), OAr₁, N(C_(n)H_(2n+1))₂, N(Ar₁)(Ar₂),CH═CH—C_(n)H_(2n+1), C≡CC_(n)H_(2n+1), Ar₁, Ar₁—Ar₂, C_(n)H_(2n)—Ar₁, orno substitution, wherein n is from 1 to 10; and wherein Ar₁ and Ar₂ areindependently selected from the group consisting of benzene, biphenyl,naphthalene, triphenylene, carbazole, and heteroaromatic analogsthereof.

In some embodiments, the organic layer may further comprise a host,wherein host comprises at least one chemical moiety selected from thegroup consisting of triphenylene, carbazole, indolocarbazole,dibenzothiphene, dibenzofuran, dibenzoselenophene,5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene,aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene,aza-dibenzofuran, aza-dibenzoselenophene, andaza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).

In some embodiments, the host may be selected from the group consistingof:

and combinations thereof.

In some embodiments, the organic layer may further comprise a host,wherein the host comprises a metal complex.

In some embodiments, the compound as described herein may be asensitizer; wherein the device may further comprise an acceptor; andwherein the acceptor may be selected from the group consisting offluorescent emitter, delayed fluorescence emitter, and combinationthereof.

In yet another aspect, the OLED of the present disclosure may alsocomprise an emissive region containing a compound as disclosed in theabove compounds section of the present disclosure.

In some embodiments, the emissive region may comprise an Ir compoundcomprising a ligand L_(A) of

wherein X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of the general substituents defined herein; atleast two adjacent R′ substituents are joined to form a fused 5-memberedcarbocyclic or heterocyclic ring; and additional substituents can bejoined or fused to form a ring, wherein Ir is coordinated to the ligandL_(A) of Formula I by the two dash lines, and can be coordinated toadditional ligands; and wherein the ligand L_(A) can be joined withadditional ligands to form a tridentate, tetradentate, pentadentate, orhexadentate ligand.

In some embodiments, at least one of the anode, the cathode, or a newlayer disposed over the organic emissive layer functions as anenhancement layer. The enhancement layer comprises a plasmonic materialexhibiting surface plasmon resonance that non-radiatively couples to theemitter material and transfers excited state energy from the emittermaterial to non-radiative mode of surface plasmon polariton. Theenhancement layer is provided no more than a threshold distance awayfrom the organic emissive layer, wherein the emitter material has atotal non-radiative decay rate constant and a total radiative decay rateconstant due to the presence of the enhancement layer and the thresholddistance is where the total non-radiative decay rate constant is equalto the total radiative decay rate constant. In some embodiments, theOLED further comprises an outcoupling layer. In some embodiments, theoutcoupling layer is disposed over the enhancement layer on the oppositeside of the organic emissive layer. In some embodiments, the outcouplinglayer is disposed on opposite side of the emissive layer from theenhancement layer but still outcouples energy from the surface plasmonmode of the enhancement layer. The outcoupling layer scatters the energyfrom the surface plasmon polaritons. In some embodiments this energy isscattered as photons to free space. In other embodiments, the energy isscattered from the surface plasmon mode into other modes of the devicesuch as but not limited to the organic waveguide mode, the substratemode, or another waveguiding mode. If energy is scattered to thenon-free space mode of the OLED other outcoupling schemes could beincorporated to extract that energy to free space. In some embodiments,one or more intervening layer can be disposed between the enhancementlayer and the outcoupling layer. The examples for interventing layer(s)can be dielectric materials, including organic, inorganic, perovskites,oxides, and may include stacks and/or mixtures of these materials.

The enhancement layer modifies the effective properties of the medium inwhich the emitter material resides resulting in any or all of thefollowing: a decreased rate of emission, a modification of emissionline-shape, a change in emission intensity with angle, a change in thestability of the emitter material, a change in the efficiency of theOLED, and reduced efficiency roll-off of the OLED device. Placement ofthe enhancement layer on the cathode side, anode side, or on both sidesresults in OLED devices which take advantage of any of theabove-mentioned effects. In addition to the specific functional layersmentioned herein and illustrated in the various OLED examples shown inthe figures, the OLEDs according to the present disclosure may includeany of the other functional layers often found in OLEDs.

The enhancement layer can be comprised of plasmonic materials, opticallyactive metamaterials, or hyperbolic metamaterials. As used herein, aplasmonic material is a material in which the real part of thedielectric constant crosses zero in the visible or ultraviolet region ofthe electromagnetic spectrum. In some embodiments, the plasmonicmaterial includes at least one metal. In such embodiments the metal mayinclude at least one of Ag, Al, Au, Ir, Pt, Ni, Cu, W, Ta, Fe, Cr, Mg,Ga, Rh, Ti, Ru, Pd, In, Bi, Ca alloys or mixtures of these materials,and stacks of these materials. In general, a metamaterial is a mediumcomposed of different materials where the medium as a whole actsdifferently than the sum of its material parts. In particular, we defineoptically active metamaterials as materials which have both negativepermittivity and negative permeability. Hyperbolic metamaterials, on theother hand, are anisotropic media in which the permittivity orpermeability are of different sign for different spatial directions.Optically active metamaterials and hyperbolic metamaterials are strictlydistinguished from many other photonic structures such as DistributedBragg Reflectors (“DBRs”) in that the medium should appear uniform inthe direction of propagation on the length scale of the wavelength oflight. Using terminology that one skilled in the art can understand: thedielectric constant of the metamaterials in the direction of propagationcan be described with the effective medium approximation. Plasmonicmaterials and metamaterials provide methods for controlling thepropagation of light that can enhance OLED performance in a number ofways.

In some embodiments, the enhancement layer is provided as a planarlayer. In other embodiments, the enhancement layer has wavelength-sizedfeatures that are arranged periodically, quasi-periodically, orrandomly, or sub-wavelength-sized features that are arrangedperiodically, quasi-periodically, or randomly. In some embodiments, thewavelength-sized features and the sub-wavelength-sized features havesharp edges.

In some embodiments, the outcoupling layer has wavelength-sized featuresthat are arranged periodically, quasi-periodically, or randomly, orsub-wavelength-sized features that are arranged periodically,quasi-periodically, or randomly. In some embodiments, the outcouplinglayer may be composed of a plurality of nanoparticles and in otherembodiments the outcoupling layer is composed of a plurality ofnanoparticles disposed over a material. In these embodiments theoutcoupling may be tunable by at least one of varying a size of theplurality of nanoparticles, varying a shape of the plurality ofnanoparticles, changing a material of the plurality of nanoparticles,adjusting a thickness of the material, changing the refractive index ofthe material or an additional layer disposed on the plurality ofnanoparticles, varying a thickness of the enhancement layer, and/orvarying the material of the enhancement layer. The plurality ofnanoparticles of the device may be formed from at least one of metal,dielectric material, semiconductor materials, an alloy of metal, amixture of dielectric materials, a stack or layering of one or morematerials, and/or a core of one type of material and that is coated witha shell of a different type of material. In some embodiments, theoutcoupling layer is composed of at least metal nanoparticles whereinthe metal is selected from the group consisting of Ag, Al, Au, Ir, Pt,Ni, Cu, W, Ta, Fe, Cr, Mg, Ga, Rh, Ti, Ru, Pd, In, Bi, Ca, alloys ormixtures of these materials, and stacks of these materials. Theplurality of nanoparticles may have additional layer disposed over them.In some embodiments, the polarization of the emission can be tuned usingthe outcoupling layer. Varying the dimensionality and periodicity of theoutcoupling layer can select a type of polarization that ispreferentially outcoupled to air. In some embodiments the outcouplinglayer also acts as an electrode of the device.

In yet another aspect, the present disclosure also provides a consumerproduct comprising an organic light-emitting device (OLED) having ananode; a cathode; and an organic layer disposed between the anode andthe cathode, wherein the organic layer may comprise a compound asdisclosed in the above compounds section of the present disclosure.

In some embodiments, the consumer product comprises an organiclight-emitting device (OLED) having an anode; a cathode; and an organiclayer disposed between the anode and the cathode, wherein the organiclayer may comprise an Ir compound comprising a ligand L_(A) of

wherein X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of the general substituents defined herein; atleast two adjacent R′ substituents are joined to form a fused 5-memberedcarbocyclic or heterocyclic ring; and additional substituents can bejoined or fused to form a ring, wherein Ir is coordinated to the ligandL_(A) of Formula I by the two dash lines, and can be coordinated toadditional ligands; and wherein the ligand L_(A) can be joined withadditional ligands to form a tridentate, tetradentate, pentadentate, orhexadentate ligand.

In some embodiments, the consumer product can be one of a flat paneldisplay, a computer monitor, a medical monitor, a television, abillboard, a light for interior or exterior illumination and/orsignaling, a heads-up display, a fully or partially transparent display,a flexible display, a laser printer, a telephone, a cell phone, tablet,a phablet, a personal digital assistant (PDA), a wearable device, alaptop computer, a digital camera, a camcorder, a viewfinder, amicro-display that is less than 2 inches diagonal, a 3-D display, avirtual reality or augmented reality display, a vehicle, a video wallcomprising multiple displays tiled together, a theater or stadiumscreen, a light therapy device, and a sign.

Generally, an OLED comprises at least one organic layer disposed betweenand electrically connected to an anode and a cathode. When a current isapplied, the anode injects holes and the cathode injects electrons intothe organic layer(s). The injected holes and electrons each migratetoward the oppositely charged electrode. When an electron and holelocalize on the same molecule, an “exciton,” which is a localizedelectron-hole pair having an excited energy state, is formed. Light isemitted when the exciton relaxes via a photoemissive mechanism. In somecases, the exciton may be localized on an excimer or an exciplex.Non-radiative mechanisms, such as thermal relaxation, may also occur,but are generally considered undesirable.

Several OLED materials and configurations are described in U.S. Pat.Nos. 5,844,363, 6,303,238, and 5,707,745, which are incorporated hereinby reference in their entirety.

The initial OLEDs used emissive molecules that emitted light from theirsinglet states (“fluorescence”) as disclosed, for example, in U.S. Pat.No. 4,769,292, which is incorporated by reference in its entirety.Fluorescent emission generally occurs in a time frame of less than 10nanoseconds.

More recently, OLEDs having emissive materials that emit light fromtriplet states (“phosphorescence”) have been demonstrated. Baldo et al.,“Highly Efficient Phosphorescent Emission from OrganicElectroluminescent Devices,” Nature, vol. 395, 151-154, 1998;(“Baldo-I”) and Baldo et al., “Very high-efficiency green organiclight-emitting devices based on electrophosphorescence,” Appl. Phys.Lett., vol. 75, No. 3, 4-6 (1999) (“Baldo-II”), are incorporated byreference in their entireties. Phosphorescence is described in moredetail in U.S. Pat. No. 7,279,704 at cols. 5-6, which are incorporatedby reference.

FIG. 1 shows an organic light emitting device 100. The figures are notnecessarily drawn to scale. Device 100 may include a substrate 110, ananode 115, a hole injection layer 120, a hole transport layer 125, anelectron blocking layer 130, an emissive layer 135, a hole blockinglayer 140, an electron transport layer 145, an electron injection layer150, a protective layer 155, a cathode 160, and a barrier layer 170.Cathode 160 is a compound cathode having a first conductive layer 162and a second conductive layer 164. Device 100 may be fabricated bydepositing the layers described, in order. The properties and functionsof these various layers, as well as example materials, are described inmore detail in U.S. Pat. No. 7,279,704 at cols. 6-10, which areincorporated by reference.

More examples for each of these layers are available. For example, aflexible and transparent substrate-anode combination is disclosed inU.S. Pat. No. 5,844,363, which is incorporated by reference in itsentirety. An example of a p-doped hole transport layer is m-MTDATA dopedwith F₄-TCNQ at a molar ratio of 50:1, as disclosed in U.S. PatentApplication Publication No. 2003/0230980, which is incorporated byreference in its entirety. Examples of emissive and host materials aredisclosed in U.S. Pat. No. 6,303,238 to Thompson et al., which isincorporated by reference in its entirety. An example of an n-dopedelectron transport layer is BPhen doped with Li at a molar ratio of 1:1,as disclosed in U.S. Patent Application Publication No. 2003/0230980,which is incorporated by reference in its entirety. U.S. Pat. Nos.5,703,436 and 5,707,745, which are incorporated by reference in theirentireties, disclose examples of cathodes including compound cathodeshaving a thin layer of metal such as Mg:Ag with an overlyingtransparent, electrically-conductive, sputter-deposited ITO layer. Thetheory and use of blocking layers is described in more detail in U.S.Pat. No. 6,097,147 and U.S. Patent Application Publication No.2003/0230980, which are incorporated by reference in their entireties.Examples of injection layers are provided in U.S. Patent ApplicationPublication No. 2004/0174116, which is incorporated by reference in itsentirety. A description of protective layers may be found in U.S. PatentApplication Publication No. 2004/0174116, which is incorporated byreference in its entirety.

FIG. 2 shows an inverted OLED 200. The device includes a substrate 210,a cathode 215, an emissive layer 220, a hole transport layer 225, and ananode 230. Device 200 may be fabricated by depositing the layersdescribed, in order. Because the most common OLED configuration has acathode disposed over the anode, and device 200 has cathode 215 disposedunder anode 230, device 200 may be referred to as an “inverted” OLED.Materials similar to those described with respect to device 100 may beused in the corresponding layers of device 200. FIG. 2 provides oneexample of how some layers may be omitted from the structure of device100.

The simple layered structure illustrated in FIGS. 1 and 2 is provided byway of non-limiting example, and it is understood that embodiments ofthe present disclosure may be used in connection with a wide variety ofother structures. The specific materials and structures described areexemplary in nature, and other materials and structures may be used.Functional OLEDs may be achieved by combining the various layersdescribed in different ways, or layers may be omitted entirely, based ondesign, performance, and cost factors. Other layers not specificallydescribed may also be included. Materials other than those specificallydescribed may be used. Although many of the examples provided hereindescribe various layers as comprising a single material, it isunderstood that combinations of materials, such as a mixture of host anddopant, or more generally a mixture, may be used. Also, the layers mayhave various sublayers. The names given to the various layers herein arenot intended to be strictly limiting. For example, in device 200, holetransport layer 225 transports holes and injects holes into emissivelayer 220, and may be described as a hole transport layer or a holeinjection layer. In one embodiment, an OLED may be described as havingan “organic layer” disposed between a cathode and an anode. This organiclayer may comprise a single layer, or may further comprise multiplelayers of different organic materials as described, for example, withrespect to FIGS. 1 and 2.

Structures and materials not specifically described may also be used,such as OLEDs comprised of polymeric materials (PLEDs) such as disclosedin U.S. Pat. No. 5,247,190 to Friend et al., which is incorporated byreference in its entirety. By way of further example, OLEDs having asingle organic layer may be used. OLEDs may be stacked, for example asdescribed in U.S. Pat. No. 5,707,745 to Forrest et al, which isincorporated by reference in its entirety. The OLED structure maydeviate from the simple layered structure illustrated in FIGS. 1 and 2.For example, the substrate may include an angled reflective surface toimprove out-coupling, such as a mesa structure as described in U.S. Pat.No. 6,091,195 to Forrest et al., and/or a pit structure as described inU.S. Pat. No. 5,834,893 to Bulovic et al., which are incorporated byreference in their entireties.

Unless otherwise specified, any of the layers of the various embodimentsmay be deposited by any suitable method. For the organic layers,preferred methods include thermal evaporation, ink-jet, such asdescribed in U.S. Pat. Nos. 6,013,982 and 6,087,196, which areincorporated by reference in their entireties, organic vapor phasedeposition (OVPD), such as described in U.S. Pat. No. 6,337,102 toForrest et al., which is incorporated by reference in its entirety, anddeposition by organic vapor jet printing (OVJP), such as described inU.S. Pat. No. 7,431,968, which is incorporated by reference in itsentirety. Other suitable deposition methods include spin coating andother solution based processes. Solution based processes are preferablycarried out in nitrogen or an inert atmosphere. For the other layers,preferred methods include thermal evaporation. Preferred patterningmethods include deposition through a mask, cold welding such asdescribed in U.S. Pat. Nos. 6,294,398 and 6,468,819, which areincorporated by reference in their entireties, and patterning associatedwith some of the deposition methods such as ink-jet and organic vaporjet printing (OVJP). Other methods may also be used. The materials to bedeposited may be modified to make them compatible with a particulardeposition method. For example, substituents such as alkyl and arylgroups, branched or unbranched, and preferably containing at least 3carbons, may be used in small molecules to enhance their ability toundergo solution processing. Substituents having 20 carbons or more maybe used, and 3-20 carbons are a preferred range. Materials withasymmetric structures may have better solution processability than thosehaving symmetric structures, because asymmetric materials may have alower tendency to recrystallize. Dendrimer substituents may be used toenhance the ability of small molecules to undergo solution processing.

Devices fabricated in accordance with embodiments of the presentdisclosure may further optionally comprise a barrier layer. One purposeof the barrier layer is to protect the electrodes and organic layersfrom damaging exposure to harmful species in the environment includingmoisture, vapor and/or gases, etc. The barrier layer may be depositedover, under or next to a substrate, an electrode, or over any otherparts of a device including an edge. The barrier layer may comprise asingle layer, or multiple layers. The barrier layer may be formed byvarious known chemical vapor deposition techniques and may includecompositions having a single phase as well as compositions havingmultiple phases. Any suitable material or combination of materials maybe used for the barrier layer. The barrier layer may incorporate aninorganic or an organic compound or both. The preferred barrier layercomprises a mixture of a polymeric material and a non-polymeric materialas described in U.S. Pat. No. 7,968,146, PCT Pat. Application Nos.PCT/US2007/023098 and PCT/US2009/042829, which are herein incorporatedby reference in their entireties. To be considered a “mixture”, theaforesaid polymeric and non-polymeric materials comprising the barrierlayer should be deposited under the same reaction conditions and/or atthe same time. The weight ratio of polymeric to non-polymeric materialmay be in the range of 95:5 to 5:95. The polymeric material and thenon-polymeric material may be created from the same precursor material.In one example, the mixture of a polymeric material and a non-polymericmaterial consists essentially of polymeric silicon and inorganicsilicon.

Devices fabricated in accordance with embodiments of the presentdisclosure can be incorporated into a wide variety of electroniccomponent modules (or units) that can be incorporated into a variety ofelectronic products or intermediate components. Examples of suchelectronic products or intermediate components include display screens,lighting devices such as discrete light source devices or lightingpanels, etc. that can be utilized by the end-user product manufacturers.Such electronic component modules can optionally include the drivingelectronics and/or power source(s). Devices fabricated in accordancewith embodiments of the present disclosure can be incorporated into awide variety of consumer products that have one or more of theelectronic component modules (or units) incorporated therein. A consumerproduct comprising an OLED that includes the compound of the presentdisclosure in the organic layer in the OLED is disclosed. Such consumerproducts would include any kind of products that include one or morelight source(s) and/or one or more of some type of visual displays. Someexamples of such consumer products include flat panel displays, curveddisplays, computer monitors, medical monitors, televisions, billboards,lights for interior or exterior illumination and/or signaling, heads-updisplays, fully or partially transparent displays, flexible displays,rollable displays, foldable displays, stretchable displays, laserprinters, telephones, mobile phones, tablets, phablets, personal digitalassistants (PDAs), wearable devices, laptop computers, digital cameras,camcorders, viewfinders, micro-displays (displays that are less than 2inches diagonal), 3-D displays, virtual reality or augmented realitydisplays, vehicles, video walls comprising multiple displays tiledtogether, theater or stadium screen, a light therapy device, and a sign.Various control mechanisms may be used to control devices fabricated inaccordance with the present disclosure, including passive matrix andactive matrix. Many of the devices are intended for use in a temperaturerange comfortable to humans, such as 18 degrees C. to 30 degrees C., andmore preferably at room temperature (20-25° C.), but could be usedoutside this temperature range, for example, from −40 degree C. to +80°C.

More details on OLEDs, and the definitions described above, can be foundin U.S. Pat. No. 7,279,704, which is incorporated herein by reference inits entirety.

The materials and structures described herein may have applications indevices other than OLEDs. For example, other optoelectronic devices suchas organic solar cells and organic photodetectors may employ thematerials and structures. More generally, organic devices, such asorganic transistors, may employ the materials and structures.

In some embodiments, the OLED has one or more characteristics selectedfrom the group consisting of being flexible, being rollable, beingfoldable, being stretchable, and being curved. In some embodiments, theOLED is transparent or semi-transparent. In some embodiments, the OLEDfurther comprises a layer comprising carbon nanotubes.

In some embodiments, the OLED further comprises a layer comprising adelayed fluorescent emitter. In some embodiments, the OLED comprises aRGB pixel arrangement or white plus color filter pixel arrangement. Insome embodiments, the OLED is a mobile device, a hand held device, or awearable device. In some embodiments, the OLED is a display panel havingless than 10 inch diagonal or 50 square inch area. In some embodiments,the OLED is a display panel having at least 10 inch diagonal or 50square inch area. In some embodiments, the OLED is a lighting panel.

In some embodiments, the compound can bean emissive dopant. In someembodiments, the compound can produce emissions via phosphorescence,fluorescence, thermally activated delayed fluorescence, i.e., TADF (alsoreferred to as E-type delayed fluorescence; see, e.g., U.S. applicationSer. No. 15/700,352, which is hereby incorporated by reference in itsentirety), triplet-triplet annihilation, or combinations of theseprocesses. In some embodiments, the emissive dopant can be a racemicmixture, or can be enriched in one enantiomer. In some embodiments, thecompound can be homoleptic (each ligand is the same). In someembodiments, the compound can be heteroleptic (at least one ligand isdifferent from others). When there are more than one ligand coordinatedto a metal, the ligands can all be the same in some embodiments. In someother embodiments, at least one ligand is different from the otherligands. In some embodiments, every ligand can be different from eachother. This is also true in embodiments where a ligand being coordinatedto a metal can be linked with other ligands being coordinated to thatmetal to form a tridentate, tetradentate, pentadentate, or hexadentateligands. Thus, where the coordinating ligands are being linked together,all of the ligands can be the same in some embodiments, and at least oneof the ligands being linked can be different from the other ligand(s) insome other embodiments.

In some embodiments, the compound can be used as a phosphorescentsensitizer in an OLED where one or multiple layers in the OLED containsan acceptor in the form of one or more fluorescent and/or delayedfluorescence emitters. In some embodiments, the compound can be used asone component of an exciplex to be used as a sensitizer. As aphosphorescent sensitizer, the compound must be capable of energytransfer to the acceptor and the acceptor will emit the energy orfurther transfer energy to a final emitter. The acceptor concentrationscan range from 0.001% to 100%. The acceptor could be in either the samelayer as the phosphorescent sensitizer or in one or more differentlayers. In some embodiments, the acceptor is a TADF emitter. In someembodiments, the acceptor is a fluorescent emitter. In some embodiments,the emission can arise from any or all of the sensitizer, acceptor, andfinal emitter.

According to another aspect, a formulation comprising the compounddescribed herein is also disclosed.

The OLED disclosed herein can be incorporated into one or more of aconsumer product, an electronic component module, and a lighting panel.The organic layer can be an emissive layer and the compound can be anemissive dopant in some embodiments, while the compound can be anon-emissive dopant in other embodiments.

In yet another aspect of the present disclosure, a formulation thatcomprises the novel compound disclosed herein is described. Theformulation can include one or more components selected from the groupconsisting of a solvent, a host, a hole injection material, holetransport material, electron blocking material, hole blocking material,and an electron transport material, disclosed herein.

The present disclosure encompasses any chemical structure comprising thenovel compound of the present disclosure, or a monovalent or polyvalentvariant thereof. In other words, the inventive compound, or a monovalentor polyvalent variant thereof, can be a part of a larger chemicalstructure. Such chemical structure can be selected from the groupconsisting of a monomer, a polymer, a macromolecule, and a supramolecule(also known as supermolecule). As used herein, a “monovalent variant ofa compound” refers to a moiety that is identical to the compound exceptthat one hydrogen has been removed and replaced with a bond to the restof the chemical structure. As used herein, a “polyvalent variant of acompound” refers to a moiety that is identical to the compound exceptthat more than one hydrogen has been removed and replaced with a bond orbonds to the rest of the chemical structure. In the instance of asupramolecule, the inventive compound can also be incorporated into thesupramolecule complex without covalent bonds.

E. Combination of the Compounds of the Present Disclosure with OtherMaterials

The materials described herein as useful for a particular layer in anorganic light emitting device may be used in combination with a widevariety of other materials present in the device. For example, emissivedopants disclosed herein may be used in conjunction with a wide varietyof hosts, transport layers, blocking layers, injection layers,electrodes and other layers that may be present. The materials describedor referred to below are non-limiting examples of materials that may beuseful in combination with the compounds disclosed herein, and one ofskill in the art can readily consult the literature to identify othermaterials that may be useful in combination.

a) Conductivity Dopants:

A charge transport layer can be doped with conductivity dopants tosubstantially alter its density of charge carriers, which will in turnalter its conductivity. The conductivity is increased by generatingcharge carriers in the matrix material, and depending on the type ofdopant, a change in the Fermi level of the semiconductor may also beachieved. Hole-transporting layer can be doped by p-type conductivitydopants and n-type conductivity dopants are used in theelectron-transporting layer.

Non-limiting examples of the conductivity dopants that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:EP01617493, EP01968131, EP2020694, EP2684932, US20050139810,US20070160905, US20090167167, US2010288362, WO06081780, WO2009003455,WO2009008277, WO2009011327, WO2014009310, US2007252140, US2015060804,US20150123047, and US2012146012.

b) HIL/HTL:

A hole injecting/transporting material to be used in the presentdisclosure is not particularly limited, and any compound may be used aslong as the compound is typically used as a hole injecting/transportingmaterial. Examples of the material include, but are not limited to: aphthalocyanine or porphyrin derivative; an aromatic amine derivative; anindolocarbazole derivative; a polymer containing fluorohydrocarbon; apolymer with conductivity dopants; a conducting polymer, such asPEDOT/PSS; a self-assembly monomer derived from compounds such asphosphonic acid and silane derivatives; a metal oxide derivative, suchas MoO_(x); a p-type semiconducting organic compound, such as1,4,5,8,9,12-Hexaazatriphenylenehexacarbonitrile; a metal complex, and across-linkable compounds.

Examples of aromatic amine derivatives used in HIL or HTL include, butnot limit to the following general structures:

Each of Ar¹ to Ar⁹ is selected from the group consisting of aromatichydrocarbon cyclic compounds such as benzene, biphenyl, triphenyl,triphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each Ar may beunsubstituted or may be substituted by a substituent selected from thegroup consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl,heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl,cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylicacids, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl,phosphino, and combinations thereof.

In one aspect, Ar¹ to Ar⁹ is independently selected from the groupconsisting of:

wherein k is an integer from 1 to 20; X¹⁰¹ to X¹⁰⁸ is C (including CH)or N; Z¹⁰¹ is NAr¹, O, or S; Ar¹ has the same group defined above.

Examples of metal complexes used in HIL or HTL include, but are notlimited to the following general formula:

wherein Met is a metal, which can have an atomic weight greater than 40;(Y¹⁰¹-Y¹⁰²) is a bidentate ligand, Y¹⁰¹ and Y¹⁰² are independentlyselected from C, N, O, P, and S; L¹⁰¹ is an ancillary ligand; k′ is aninteger value from 1 to the maximum number of ligands that may beattached to the metal; and k′+k″ is the maximum number of ligands thatmay be attached to the metal.

In one aspect, (Y¹⁰¹-Y¹⁰²) is a 2-phenylpyridine derivative. In anotheraspect, (Y¹⁰¹-Y¹⁰²) is a carbene ligand. In another aspect, Met isselected from Ir, Pt, Os, and Zn. In a further aspect, the metal complexhas a smallest oxidation potential in solution vs. Fc⁺/Fc couple lessthan about 0.6 V.

Non-limiting examples of the HIL and HTL materials that may be used inan OLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN102702075, DE102012005215, EP01624500, EP01698613, EP01806334,EP01930964, EP01972613, EP01997799, EP02011790, EP02055700, EP02055701,EP1725079, EP2085382, EP2660300, EP650955, JP07-073529, JP2005112765,JP2007091719, JP2008021687, JP2014-009196, KR20110088898, KR20130077473,TW201139402, U.S. Ser. No. 06/517,957, US20020158242, US20030162053,US20050123751, US20060182993, US20060240279, US20070145888,US20070181874, US20070278938, US20080014464, US20080091025,US20080106190, US20080124572, US20080145707, US20080220265,US20080233434, US20080303417, US2008107919, US20090115320,US20090167161, US2009066235, US2011007385, US20110163302, US2011240968,US2011278551, US2012205642, US2013241401, US20140117329, US2014183517,U.S. Pat. Nos. 5,061,569, 5,639,914, WO05075451, WO07125714, WO08023550,WO08023759, WO2009145016, WO2010061824, WO2011075644, WO2012177006,WO2013018530, WO2013039073, WO2013087142, WO2013118812, WO2013120577,WO2013157367, WO2013175747, WO2014002873, WO2014015935, WO2014015937,WO2014030872, WO2014030921, WO2014034791, WO2014104514, WO2014157018.

c) EBL:

An electron blocking layer (EBL) may be used to reduce the number ofelectrons and/or excitons that leave the emissive layer. The presence ofsuch a blocking layer in a device may result in substantially higherefficiencies, and/or longer lifetime, as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the EBLmaterial has a higher LUMO (closer to the vacuum level) and/or highertriplet energy than the emitter closest to the EBL interface. In someembodiments, the EBL material has a higher LUMO (closer to the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the EBL interface. In one aspect, the compound used in EBLcontains the same molecule or the same functional groups used as one ofthe hosts described below.

d) Hosts:

The light emitting layer of the organic EL device of the presentdisclosure preferably contains at least a metal complex as lightemitting material, and may contain a host material using the metalcomplex as a dopant material. Examples of the host material are notparticularly limited, and any metal complexes or organic compounds maybe used as long as the triplet energy of the host is larger than that ofthe dopant. Any host material may be used with any dopant so long as thetriplet criteria is satisfied.

Examples of metal complexes used as host are preferred to have thefollowing general formula:

wherein Met is a metal; (Y¹⁰³-Y¹⁰⁴) is a bidentate ligand, Y¹⁰³ and Y¹⁰⁴are independently selected from C, N, O, P, and S; L¹⁰¹ is an anotherligand; k′ is an integer value from 1 to the maximum number of ligandsthat may be attached to the metal; and k′+k″ is the maximum number ofligands that may be attached to the metal.

In one aspect, the metal complexes are:

wherein (O—N) is a bidentate ligand, having metal coordinated to atoms Oand N.

In another aspect, Met is selected from Ir and Pt. In a further aspect,(Y¹⁰³-Y¹⁰⁴) is a carbene ligand.

In one aspect, the host compound contains at least one of the followinggroups selected from the group consisting of aromatic hydrocarbon cycliccompounds such as benzene, biphenyl, triphenyl, triphenylene,tetraphenylene, naphthalene, anthracene, phenalene, phenanthrene,fluorene, pyrene, chrysene, perylene, and azulene; the group consistingof aromatic heterocyclic compounds such as dibenzothiophene,dibenzofuran, dibenzoselenophene, furan, thiophene, benzofuran,benzothiophene, benzoselenophene, carbazole, indolocarbazole,pyridylindole, pyrrolodipyridine, pyrazole, imidazole, triazole,oxazole, thiazole, oxadiazole, oxatriazole, dioxazole, thiadiazole,pyridine, pyridazine, pyrimidine, pyrazine, triazine, oxazine,oxathiazine, oxadiazine, indole, benzimidazole, indazole, indoxazine,benzoxazole, benzisoxazole, benzothiazole, quinoline, isoquinoline,cinnoline, quinazoline, quinoxaline, naphthyridine, phthalazine,pteridine, xanthene, acridine, phenazine, phenothiazine, phenoxazine,benzofuropyridine, furodipyridine, benzothienopyridine,thienodipyridine, benzoselenophenopyridine, and selenophenodipyridine;and the group consisting of 2 to 10 cyclic structural units which aregroups of the same type or different types selected from the aromatichydrocarbon cyclic group and the aromatic heterocyclic group and arebonded to each other directly or via at least one of oxygen atom,nitrogen atom, sulfur atom, silicon atom, phosphorus atom, boron atom,chain structural unit and the aliphatic cyclic group. Each option withineach group may be unsubstituted or may be substituted by a substituentselected from the group consisting of deuterium, halogen, alkyl,cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy,amino, silyl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl,heteroaryl, acyl, carboxylic acids, ether, ester, nitrile, isonitrile,sulfanyl, sulfinyl, sulfonyl, phosphino, and combinations thereof.

In one aspect, the host compound contains at least one of the followinggroups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, and when it is aryl or heteroaryl, it has thesimilar definition as Ar's mentioned above. k is an integer from 0 to 20or 1 to 20. X¹⁰¹ to X¹⁰⁸ are independently selected from C (includingCH) or N. Z¹⁰¹ and Z¹⁰² are independently selected from NR¹⁰¹, or S.

Non-limiting examples of the host materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: EP2034538,EP2034538A, EP2757608, JP2007254297, KR20100079458, KR20120088644,KR20120129733, KR20130115564, TW201329200, US20030175553, US20050238919,US20060280965, US20090017330, US20090030202, US20090167162,US20090302743, US20090309488, US20100012931, US20100084966,US20100187984, US2010187984, US2012075273, US2012126221, US2013009543,US2013105787, US2013175519, US2014001446, US20140183503, US20140225088,US2014034914, U.S. Pat. No. 7,154,114, WO2001039234, WO2004093207,WO2005014551, WO2005089025, WO2006072002, WO2006114966, WO2007063754,WO2008056746, WO2009003898, WO2009021126, WO2009063833, WO2009066778,WO2009066779, WO2009086028, WO2010056066, WO2010107244, WO2011081423,WO2011081431, WO2011086863, WO2012128298, WO2012133644, WO2012133649,WO2013024872, WO2013035275, WO2013081315, WO2013191404, WO2014142472,US20170263869, US20160163995, U.S. Pat. No. 9,466,803,

e) Additional Emitters:

One or more additional emitter dopants may be used in conjunction withthe compound of the present disclosure. Examples of the additionalemitter dopants are not particularly limited, and any compounds may beused as long as the compounds are typically used as emitter materials.Examples of suitable emitter materials include, but are not limited to,compounds which can produce emissions via phosphorescence, fluorescence,thermally activated delayed fluorescence, i.e., TADF (also referred toas E-type delayed fluorescence), triplet-triplet annihilation, orcombinations of these processes.

Non-limiting examples of the emitter materials that may be used in anOLED in combination with materials disclosed herein are exemplifiedbelow together with references that disclose those materials:CN103694277, CN1696137, EB01238981, EP01239526, EP01961743, EP1239526,EP1244155, EP1642951, EP1647554, EP1841834, EP1841834B, EP2062907,EP2730583, JP2012074444, JP2013110263, JP4478555, KR1020090133652,KR20120032054, KR20130043460, TW201332980, U.S. Ser. No. 06/699,599,U.S. Ser. No. 06/916,554, US20010019782, US20020034656, US20030068526,US20030072964, US20030138657, US20050123788, US20050244673,US2005123791, US2005260449, US20060008670, US20060065890, US20060127696,US20060134459, US20060134462, US20060202194, US20060251923,US20070034863, US20070087321, US20070103060, US20070111026,US20070190359, US20070231600, US2007034863, US2007104979, US2007104980,US2007138437, US2007224450, US2007278936, US20080020237, US20080233410,US20080261076, US20080297033, US200805851, US2008161567, US2008210930,US20090039776, US20090108737, US20090115322, US20090179555,US2009085476, US2009104472, US20100090591, US20100148663, US20100244004,US20100295032, US2010102716, US2010105902, US2010244004, US2010270916,US20110057559, US20110108822, US20110204333, US2011215710, US2011227049,US2011285275, US2012292601, US20130146848, US2013033172, US2013165653,US2013181190, US2013334521, US20140246656, US2014103305, U.S. Pat. Nos.6,303,238, 6,413,656, 6,653,654, 6,670,645, 6,687,266, 6,835,469,6,921,915, 7,279,704, 7,332,232, 7,378,162, 7,534,505, 7,675,228,7,728,137, 7,740,957, 7,759,489, 7,951,947, 8,067,099, 8,592,586,8,871,361, WO06081973, WO06121811, WO07018067, WO07108362, WO07115970,WO07115981, WO08035571, WO2002015645, WO2003040257, WO2005019373,WO2006056418, WO2008054584, WO2008078800, WO2008096609, WO2008101842,WO2009000673, WO2009050281, WO2009100991, WO2010028151, WO2010054731,WO2010086089, WO2010118029, WO2011044988, WO2011051404, WO2011107491,WO2012020327, WO2012163471, WO2013094620, WO2013107487, WO2013174471,WO2014007565, WO2014008982, WO2014023377, WO2014024131, WO2014031977,WO2014038456, WO2014112450.

f) HBL:

A hole blocking layer (HBL) may be used to reduce the number of holesand/or excitons that leave the emissive layer. The presence of such ablocking layer in a device may result in substantially higherefficiencies and/or longer lifetime as compared to a similar devicelacking a blocking layer. Also, a blocking layer may be used to confineemission to a desired region of an OLED. In some embodiments, the HBLmaterial has a lower HOMO (further from the vacuum level) and/or highertriplet energy than the emitter closest to the HBL interface. In someembodiments, the HBL material has a lower HOMO (further from the vacuumlevel) and/or higher triplet energy than one or more of the hostsclosest to the HBL interface.

In one aspect, compound used in HBL contains the same molecule or thesame functional groups used as host described above.

In another aspect, compound used in HBL contains at least one of thefollowing groups in the molecule:

wherein k is an integer from 1 to 20; L¹⁰¹ is another ligand, k′ is aninteger from 1 to 3.

g) ETL:

Electron transport layer (ETL) may include a material capable oftransporting electrons. Electron transport layer may be intrinsic(undoped), or doped. Doping may be used to enhance conductivity.Examples of the ETL material are not particularly limited, and any metalcomplexes or organic compounds may be used as long as they are typicallyused to transport electrons.

In one aspect, compound used in ETL contains at least one of thefollowing groups in the molecule:

wherein R¹⁰¹ is selected from the group consisting of hydrogen,deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl,arylalkyl, alkoxy, aryloxy, amino, silyl, alkenyl, cycloalkenyl,heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acids, ether,ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof, when it is aryl or heteroaryl, it has the similardefinition as Ar's mentioned above. Ar¹ to Ar³ has the similardefinition as Ar's mentioned above. k is an integer from 1 to 20. X¹⁰¹to X¹⁰⁸ is selected from C (including CH) or N.

In another aspect, the metal complexes used in ETL contains, but notlimit to the following general formula:

wherein (O—N) or (N—N) is a bidentate ligand, having metal coordinatedto atoms O, N or N, N; L¹⁰¹ is another ligand; k′ is an integer valuefrom 1 to the maximum number of ligands that may be attached to themetal.

Non-limiting examples of the ETL materials that may be used in an OLEDin combination with materials disclosed herein are exemplified belowtogether with references that disclose those materials: CN103508940,EP01602648, EP01734038, EP01956007, JP2004-022334, JP2005149918,JP2005-268199, KR0117693, KR20130108183, US20040036077, US20070104977,US2007018155, US20090101870, US20090115316, US20090140637,US20090179554, US2009218940, US2010108990, US2011156017, US2011210320,US2012193612, US2012214993, US2014014925, US2014014927, US20140284580,U.S. Pat. Nos. 6,656,612, 8,415,031, WO2003060956, WO2007111263,WO2009148269, WO2010067894, WO2010072300, WO2011074770, WO2011105373,WO2013079217, WO2013145667, WO2013180376, WO2014104499, WO2014104535,

h) Charge Generation Layer (CGL)

In tandem or stacked OLEDs, the CGL plays an essential role in theperformance, which is composed of an n-doped layer and a p-doped layerfor injection of electrons and holes, respectively. Electrons and holesare supplied from the CGL and electrodes. The consumed electrons andholes in the CGL are refilled by the electrons and holes injected fromthe cathode and anode, respectively; then, the bipolar currents reach asteady state gradually. Typical CGL materials include n and pconductivity dopants used in the transport layers.

In any above-mentioned compounds used in each layer of the OLED device,the hydrogen atoms can be partially or fully deuterated. Thus, anyspecifically listed substituent, such as, without limitation, methyl,phenyl, pyridyl, etc. may be undeuterated, partially deuterated, andfully deuterated versions thereof. Similarly, classes of substituentssuch as, without limitation, alkyl, aryl, cycloalkyl, heteroaryl, etc.also may be undeuterated, partially deuterated, and fully deuteratedversions thereof.

It is understood that the various embodiments described herein are byway of example only and are not intended to limit the scope of theinvention. For example, many of the materials and structures describedherein may be substituted with other materials and structures withoutdeviating from the spirit of the invention. The present invention asclaimed may therefore include variations from the particular examplesand preferred embodiments described herein, as will be apparent to oneof skill in the art. It is understood that various theories as to whythe invention works are not intended to be limiting.

F. Experimental Section Synthesis of Representative Examples

2,3-Dibromopyridine (20 g, 84 mmol), 2-Chlorophenylboronic acid (13.2 g,84 mmol) and potassium phosphate tribasic (35.8 g, 169 mmol) werecharged into the reaction flask with 240 mL of dimethylacetamide and 60mL of water. This mixture was degassed with nitrogen for 15 minutesfollowed by the addition of tetrakis(triphenylphosphine)palladium(0)(9.76 g, 8.44 mmol). This mixture was then stirred and heated at 120° C.for 7 hours. Heating was discontinued. Then, the reaction mixture wasdiluted with water and was extracted with ethyl acetate. The organicextracts were dried then were filtered and concentrated under vacuum.The crude residue was passed through a silica gel column eluting thecolumn with 5-15% ethyl acetate/heptanes. Product fractions yielded3-bromo-2-(2-chlorophenyl)pyridine (17.2 g, 64.1 mmol, 76% yield).

3-Bromo-2-(2-chlorophenyl)pyridine (17.0 g, 63.3 mmol),Dibenzo[b,d]furan-4-ylboronic acid (13.42 g, 63.3 mmol) and potassiumphosphate tribasic (26.9 g, 127 mmol) were charged into the reactionflask with 340 mL of dimethylacetamide and 85 mL of water. This mixturewas degassed with nitrogen for 15 minutes followed by the addition oftetrakis(triphenylphosphine)palladium(0) (7.32 g, 6.33 mmol). Thismixture was then stirred and heated at reflux overnight. Heating wasdiscontinued. Then, the reaction mixture was diluted with water and wasextracted with ethyl acetate. The organic extracts were dried, filteredand concentrated under vacuum. The crude residue was passed through asilica gel column eluting with 10-20% ethyl acetate/heptanes. Productfractions yielded 2-(2-chlorophenyl)-3-(dibenzo[b,d] furan-4-yl)pyridine(15.8 g, 44.4 mmol, 70.1% yield).

2-(2-Chlorophenyl)-3-(dibenzo[b,d] furan-4-yl)pyridine (14 g, 39.3mmol), potassium phosphate tribasic (25.6 g, 79 mmol) and pivalic acid(1.406 g, 13.77 mmol) were charged into the reaction flask with 380 mLof DMA. This mixture was degassed with nitrogen for 15 minutes followedby the addition of PdCl₂(PCy₃)₂. This mixture was stirred and heated at130° C. overnight. Heating was then discontinued followed by dilutingthe reaction mixture with 1 L of water. A solid was collected viafiltration. This solid was triturated with 1.2 L of DCM. Insolubles wereremoved. The filtrate was passed through a Celite pad. This filtrate wasthen concentrated under vacuum. The crude residue was passed through asilica gel column eluting with 5-20% ethyl acetate/heptanes. Productfractions yielded benzo[h]benzo[2,3]benzofuro[7,6-f]quinoline (10.35 g,32.4 mmol, 82% yield).

Benzo[h]benzo[2,3]benzofuro[7,6-f]quinoline (2.282 g, 7.15 mmol) and theiridium salt (3.5 g, 4.08 mmol) were charged into the reaction flaskwith 60 mL of 2-ethoxyethanol and 60 mL of DMF. This mixture wasdegassed with nitrogen then was heated in an oil bath set at 90° C. for4.5 days. Heating was discontinued. The majority of the solvents wereremoved under vacuum. This crude product was triturated with 250 mL ofmethanol. This product was filtered, rinsed with methanol then was driedunder vacuum. This solid was dissolved in 400 mL of warm DCM and waspassed through a basic alumina column eluting with 50-75% DCM/heptanes.The product fractions were then passed through 9×330 g silica gelcolumns eluting with 75-99% toluene/heptanes. Product fractions werecombined and concentrated under vacuum. This solid was then trituratedwith methanol, collected via filtration and dried under vacuum yieldingthe iridium complex (1.2 g, 1.246 mmol, 30.5% yield). The desired massfor the iridium complex was confirmed by LC/MS analysis.

Device Examples

All example devices were fabricated by high vacuum (<10⁻⁷ Torr) thermalevaporation. The anode electrode was 800 Å of indium tin oxide (ITO).The cathode consisted of 10 Å of Liq (8-hydroxyquinoline lithium)followed by 1,000 Å of Al. All devices were encapsulated with a glasslid sealed with an epoxy resin in a nitrogen glove box (<1 ppm of H₂Oand O₂) immediately after fabrication with a moisture getterincorporated inside the package. The organic stack of the deviceexamples consisted of sequentially, from the ITO Surface: 100 Å ofHAT-CN as the hole injection layer (HIL); 400 Å of HTM as a holetransporting layer (HTL); emissive layer (EML) with thickness 400 Å.Emissive layer containing H-host (H1): E-host (H2) in 6:4 ratio and 12weight % of green emitter. 350 Å of Liq (8-hydroxyquinoline lithium)doped with 35% of ETM as the ETL. Device structure is shown in thetable 1. Table 1 shows the schematic device structure. The chemicalstructures of the device materials used are shown below.

Upon fabrication the devices were measured for electro luminescence(EL), JVL characteristics, and lifetested at DC 80 mA/cm². LT97 at 9,000nits was calculated from 80 mA/cm². LT97 data assumed accelerationfactor of 1.8. Device performance data is shown in Table 2 below.

TABLE 1 schematic device structure Layer Material Thickness [Å] AnodeITO 800 HIL HAT-CN 100 HTL HTM 400 EBL EBM 50 Green EML H1:H2: exampledopant 400 ETL Liq:ETM 35% 350 EIL Liq 10 Cathode Al 1,000

TABLE 2 Device performance 1931 CIE At 10 mA/cm²* At 9K nits* λ max FWHMValtage LE EQE PE calculated 97% Emitter 12% x y [nm] [nm] [V] [cd/A][%] [lm/W] [h]** Inventive Example 0.402 0.581 546 75 4.2 65.9 18.1 48.7247The above data shows that the Inventive Example exhibited high externalquantum efficiency (EQE) (18.1% at 10 mA/cm²) and low voltage (4.2V at10 mA/cm²). Moreover, the stability of the Inventive Example wasexcellent (247 hours. for LT97 at 9000 nits) which is quite suitable forOLED application.

1. An Ir compound comprising a ligand L_(A) of

wherein: X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl,acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl,sulfinyl, sulfonyl, phosphino, and combinations thereof; at least twoadjacent R′ are joined to form a fused 5-membered heterocyclic ring; andadditional substituents can be joined or fused to form a ring, whereinIr is coordinated to the ligand L_(A) of Formula I by the two dashedlines, and can be coordinated to additional ligands; and wherein theligand L_(A) can be joined with additional ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.
 2. The compound ofclaim 1, wherein R′ for each occurrence is independently a hydrogen or asubstituent selected from the group consisting of deuterium, fluorine,alkyl, cycloalkyl, heteroalkyl, alkoxy, aryloxy, amino, silyl, boryl,alkenyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile,isonitrile, sulfanyl, and combinations thereof.
 3. The compound of claim1, wherein X⁴ and X⁵ are both CR′, X⁵ and X⁶ are both CR′, or X⁶ and X⁷are both CR′.
 4. The compound of claim 3, wherein the two R′substituents from X⁴ and X⁵, from X⁵ and X⁶, or from X⁶ and X⁷ arejoined to form a 5-membered heterocyclic ring fused to ring B.
 5. Thecompound of claim 1, wherein X⁸ and X⁹ are both CR′.
 6. The compound ofclaim 5, wherein the two R′ substituents are joined to form a 5-memberedheterocyclic ring fused to ring C.
 7. The compound of claim 1, whereinthe fused 5-membered heterocyclic ring has

wherein Y is selected from the group consisting of O, S, Se, NR″, andSiR″R′″; R^(D), R″, and R′″ are each independently a hydrogen or asubstituent selected from the group consisting of deuterium, halogen,alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl,alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile,isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, and combinationsthereof; R^(D) represents zero, mono, or up to the maximum allowednumber of substitutions to ring D; and two R^(D) can be joined to form afused ring.
 8. The compound of claim 7, wherein Y is O or S.
 9. Thecompound of claim 1, wherein the 5-membered heterocyclic ring is furtherfused to form an extended one or more fused ring.
 10. The compound ofclaim 1, wherein the ligand L_(A) of Formula I is selected from thegroup consisting of:

wherein X¹¹-X¹³ are each independently CR′ or N; R^(A), R^(B), R^(C),and R^(D) are each independently a hydrogen or a substituent selectedfrom the group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl,acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl,sulfinyl, sulfonyl, phosphino, and combinations thereof; and Q¹, and Q²are each independently selected from the group consisting of BR_(e),NR_(e), PR_(e), O, S, Se, C═O, S═, SO₂, CR_(e)R_(f), SiR_(e)R_(f), andGeR_(e)R_(f); wherein R_(e) and R_(f) can be fused or joined to form aring.
 11. The compound of claim 1, wherein the ligand L_(A) of Formula Iis selected from the group consisting of L_(A1-1) to L_(A1116-48) withthe general numbering formula L_(Ah-m), wherein h is an integer from 1to 1116, m is an integer from 1 to 48, and each structure of L_(Ah-m) isdefined in the following LIST 1

and wherein for each L_(Ah) in L_(Ah-m), R^(X), R^(Y) and R^(Z) aredefined in the following LIST 2 L_(Ah) R^(X) R^(Y) R^(Z) L_(A1) R¹ R¹ R¹L_(A2) R² R² R¹ L_(A3) R³ R³ R¹ L_(A4) R⁴ R⁴ R¹ L_(A5) R⁵ R⁵ R¹ L_(A6)R⁶ R⁶ R¹ L_(A7) R⁷ R⁷ R¹ L_(A8) R⁸ R⁸ R¹ L_(A9) R⁹ R⁹ R¹ L_(A10) R¹⁰ R¹⁰R¹ L_(A11) R¹¹ R¹¹ R¹ L_(A12) R¹² R¹² R¹ L_(A13) R¹³ R¹³ R¹ L_(A14) R¹⁴R¹⁴ R¹ L_(A15) R¹⁵ R¹⁵ R¹ L_(A16) R¹⁶ R¹⁶ R¹ L_(A17) R¹⁷ R¹⁷ R¹ L_(A18)R¹⁸ R¹⁸ R¹ L_(A19) R¹⁹ R¹⁹ R¹ L_(A20) R²⁰ R²⁰ R¹ L_(A21) R²¹ R²¹ R¹L_(A22) R²² R²² R¹ L_(A23) R²³ R²³ R¹ L_(A24) R²⁴ R²⁴ R¹ L_(A25) R²⁵ R²⁵R¹ L_(A26) R²⁶ R²⁶ R¹ L_(A27) R²⁷ R²⁷ R¹ L_(A28) R²⁸ R²⁸ R¹ L_(A29) R²⁹R²⁹ R¹ L_(A30) R³⁰ R³⁰ R¹ L_(A31) R³¹ R³¹ R¹ L_(A32) R³² R³² R¹ L_(A33)R³³ R³³ R¹ L_(A34) R³⁴ R³⁴ R¹ L_(A35) R³⁵ R³⁵ R¹ L_(A36) R³⁶ R³⁶ R¹L_(A37) R³⁷ R³⁷ R¹ L_(A38) R³⁸ R³⁸ R¹ L_(A39) R³⁹ R³⁹ R¹ L_(A40) R⁴⁰ R⁴⁰R¹ L_(A41) R⁴¹ R⁴¹ R¹ L_(A42) R⁴² R⁴² R¹ L_(A43) R⁴³ R⁴³ R¹ L_(A44) R⁴⁴R⁴⁴ R¹ L_(A45) R⁴⁵ R⁴⁵ R¹ L_(A46) R⁴⁶ R⁴⁶ R¹ L_(A47) R⁴⁷ R⁴⁷ R¹ L_(A48)R⁴⁸ R⁴⁸ R¹ L_(A49) R⁴⁹ R⁴⁹ R¹ L_(A50) R⁵⁰ R⁵⁰ R¹ L_(A51) R⁵¹ R⁵¹ R¹L_(A52) R⁵² R⁵² R¹ L_(A53) R⁵³ R⁵³ R¹ L_(A54) R⁵⁴ R⁵⁴ R¹ L_(A55) R² R¹R¹ L_(A56) R³ R¹ R¹ L_(A57) R⁴ R¹ R¹ L_(A58) R⁵ R¹ R¹ L_(A59) R⁶ R¹ R¹L_(A60) R⁷ R¹ R¹ L_(A61) R⁸ R¹ R¹ L_(A62) R⁹ R¹ R¹ L_(A63) R¹⁰ R¹ R¹L_(A64) R¹¹ R¹ R¹ L_(A65) R¹² R¹ R¹ L_(A66) R¹³ R¹ R¹ L_(A67) R¹⁴ R¹ R¹L_(A65) R¹⁵ R¹ R¹ L_(A69) R¹⁶ R¹ R¹ L_(A70) R¹⁷ R¹ R¹ L_(A71) R¹⁸ R¹ R¹L_(A72) R¹⁹ R¹ R¹ L_(A73) R²⁰ R¹ R¹ L_(A74) R²¹ R¹ R¹ L_(A75) R²² R¹ R¹L_(A76) R²³ R¹ R¹ L_(A77) R²⁴ R¹ R¹ L_(A78) R²⁵ R¹ R¹ L_(A79) R²⁶ R¹ R¹L_(A80) R²⁷ R¹ R¹ L_(A81) R²⁸ R¹ R¹ L_(A82) R²⁹ R¹ R¹ L_(A83) R³⁰ R¹ R¹L_(A84) R³¹ R¹ R¹ L_(A85) R³² R¹ R¹ L_(A86) R³³ R¹ R¹ L_(A87) R³⁴ R¹ R¹L_(A88) R³⁵ R¹ R¹ L_(A89) R³⁶ R¹ R¹ L_(A90) R³⁷ R¹ R¹ L_(A91) R³⁸ R¹ R¹L_(A92) R³⁹ R¹ R¹ L_(A93) R⁴⁰ R¹ R¹ L_(A94) R⁴¹ R¹ R¹ L_(A95) R⁴² R¹ R¹L_(A96) R⁴³ R¹ R¹ L_(A97) R⁴⁴ R¹ R¹ L_(A98) R⁴⁵ R¹ R¹ L_(A99) R⁴⁶ R¹ R¹L_(A100) R⁴⁷ R¹ R¹ L_(A101) R⁴⁸ R¹ R¹ L_(A102) R⁴⁹ R¹ R¹ L_(A103) R⁵⁰ R¹R¹ L_(A104) R⁵¹ R¹ R¹ L_(A105) R⁵² R¹ R¹ L_(A106) R⁵³ R¹ R¹ L_(A107) R⁵⁴R¹ R¹ L_(A108) R¹ R³² R¹ L_(A109) R² R³² R¹ L_(A110) R³ R³² R¹ L_(A111)R⁴ R³² R¹ L_(A112) R⁵ R³² R¹ L_(A113) R⁶ R³² R¹ L_(A114) R⁷ R³² R¹L_(A115) R⁸ R³² R¹ L_(A116) R⁹ R³² R¹ L_(A117) R¹⁰ R³² R¹ L_(A118) R¹¹R³² R¹ L_(A119) R¹² R³² R¹ L_(A120) R¹³ R³² R¹ L_(A121) R¹⁴ R³² R¹L_(A122) R¹⁵ R³² R¹ L_(A123) R¹⁶ R³² R¹ L_(A124) R¹⁷ R³² R¹ L_(A125) R¹⁸R³² R¹ L_(A126) R¹⁹ R³² R¹ L_(A127) R²⁰ R³² R¹ L_(A128) R²¹ R³² R¹L_(A129) R²² R³² R¹ L_(A130) R²³ R³² R¹ L_(A131) R²⁴ R³² R¹ L_(A132) R²⁵R³² R¹ L_(A133) R²⁶ R³² R¹ L_(A134) R²⁷ R³² R¹ L_(A135) R²⁸ R³² R¹L_(A136) R²⁹ R³² R¹ L_(A137) R³⁰ R³² R¹ L_(A138) R³¹ R³² R¹ L_(A139) R³³R³² R¹ L_(A140) R³⁴ R³² R¹ L_(A141) R³⁵ R³² R¹ L_(A142) R³⁶ R³² R¹L_(A143) R³⁷ R³² R¹ L_(A144) R³⁸ R³² R¹ L_(A145) R³⁹ R³² R¹ L_(A146) R⁴⁰R³² R¹ L_(A147) R⁴¹ R³² R¹ L_(A148) R⁴² R³² R¹ L_(A149) R⁴³ R³² R¹L_(A150) R⁴⁴ R³² R¹ L_(A151) R⁴⁵ R³² R¹ L_(A152) R⁴⁶ R³² R¹ L_(A153) R⁴⁷R³² R¹ L_(A154) R⁴⁸ R³² R¹ L_(A155) R⁴⁹ R³² R¹ L_(A156) R⁵⁰ R³² R¹L_(A157) R⁵¹ R³² R¹ L_(A158) R⁵² R³² R¹ L_(A159) R⁵³ R³² R¹ L_(A160) R⁵⁴R³² R¹ L_(A161) R¹ R³⁶ R¹ L_(A162) R² R³⁶ R¹ L_(A163) R³ R³⁶ R¹ L_(A164)R⁴ R³⁶ R¹ L_(A165) R⁵ R³⁶ R¹ L_(A166) R⁶ R³⁶ R¹ L_(A167) R⁷ R³⁶ R¹L_(A168) R⁸ R³⁶ R¹ L_(A169) R⁹ R³⁶ R¹ L_(A170) R¹⁰ R³⁶ R¹ L_(A171) R¹¹R³⁶ R¹ L_(A172) R¹² R³⁶ R¹ L_(A173) R¹³ R³⁶ R¹ L_(A174) R¹⁴ R³⁶ R¹L_(A175) R¹⁵ R³⁶ R¹ L_(A176) R¹⁶ R³⁶ R¹ L_(A177) R¹⁷ R³⁶ R¹ L_(A178) R¹⁸R³⁶ R¹ L_(A179) R¹⁹ R³⁶ R¹ L_(A180) R²⁰ R³⁶ R¹ L_(A181) R²¹ R³⁶ R¹L_(A182) R²² R³⁶ R¹ L_(A183) R²³ R³⁶ R¹ L_(A184) R²⁴ R³⁶ R¹ L_(A185) R²⁵R³⁶ R¹ L_(A186) R²⁶ R³⁶ R¹ L_(A187) R²⁷ R³⁶ R¹ L_(A188) R²⁸ R³⁶ R¹L_(A189) R²⁹ R³⁶ R¹ L_(A190) R³⁰ R³⁶ R¹ L_(A191) R³¹ R³⁶ R¹ L_(A192) R³²R³⁶ R¹ L_(A193) R³³ R³⁶ R¹ L_(A194) R³⁴ R³⁶ R¹ L_(A195) R³⁵ R³⁶ R¹L_(A196) R³⁷ R³⁶ R¹ L_(A197) R³⁸ R³⁶ R¹ L_(A198) R³⁹ R³⁶ R¹ L_(A199) R⁴⁰R³⁶ R¹ L_(A200) R⁴¹ R³⁶ R¹ L_(A201) R⁴² R³⁶ R¹ L_(A202) R⁴³ R³⁶ R¹L_(A203) R⁴⁴ R³⁶ R¹ L_(A204) R⁴⁵ R³⁶ R¹ L_(A205) R⁴⁶ R³⁶ R¹ L_(A206) R⁴⁷R³⁶ R¹ L_(A207) R⁴⁸ R³⁶ R¹ L_(A208) R⁴⁹ R³⁶ R¹ L_(A209) R⁵⁰ R³⁶ R¹L_(A210) R⁵¹ R³⁶ R¹ L_(A211) R⁵² R³⁶ R¹ L_(A212) R⁵³ R³⁶ R¹ L_(A213) R⁵⁴R³⁶ R¹ L_(A214) R¹ R² R¹ L_(A215) R¹ R³ R¹ L_(A216) R¹ R⁴ R¹ L_(A217) R¹R⁵ R¹ L_(A218) R¹ R⁶ R¹ L_(A219) R¹ R⁷ R¹ L_(A220) R¹ R⁸ R¹ L_(A221) R¹R⁹ R¹ L_(A222) R¹ R¹⁰ R¹ L_(A223) R¹ R¹¹ R¹ L_(A224) R¹ R¹² R¹ L_(A225)R¹ R¹³ R¹ L_(A226) R¹ R¹⁴ R¹ L_(A227) R¹ R¹⁵ R¹ L_(A228) R¹ R¹⁶ R¹L_(A229) R¹ R¹⁷ R¹ L_(A230) R¹ R¹⁸ R¹ L_(A231) R¹ R¹⁹ R¹ L_(A232) R¹ R²⁰R¹ L_(A233) R¹ R²¹ R¹ L_(A234) R¹ R²² R¹ L_(A235) R¹ R²³ R¹ L_(A236) R¹R²⁴ R¹ L_(A237) R¹ R²⁵ R¹ L_(A238) R¹ R²⁶ R¹ L_(A239) R¹ R²⁷ R¹ L_(A240)R¹ R²⁸ R¹ L_(A241) R¹ R²⁹ R¹ L_(A242) R¹ R³⁰ R¹ L_(A243) R¹ R³¹ R¹L_(A244) R¹ R³² R¹ L_(A245) R¹ R³³ R¹ L_(A246) R¹ R³⁴ R¹ L_(A247) R¹ R³⁵R¹ L_(A248) R¹ R³⁶ R¹ L_(A249) R¹ R³⁷ R¹ L_(A250) R¹ R³⁸ R¹ L_(A251) R¹R³⁹ R¹ L_(A252) R¹ R⁴⁰ R¹ L_(A253) R¹ R⁴¹ R¹ L_(A254) R¹ R⁴² R¹ L_(A255)R¹ R⁴³ R¹ L_(A256) R¹ R⁴⁴ R¹ L_(A257) R¹ R⁴⁵ R¹ L_(A258) R¹ R⁴⁶ R¹L_(A259) R¹ R⁴⁷ R¹ L_(A260) R¹ R⁴⁸ R¹ L_(A261) R¹ R⁴⁹ R¹ L_(A262) R¹ R⁵⁰R¹ L_(A263) R¹ R⁵¹ R¹ L_(A264) R¹ R⁵² R¹ L_(A265) R¹ R⁵³ R¹ L_(A266) R¹R⁵⁴ R¹ L_(A267) R³² R¹ R¹ L_(A268) R³² R² R¹ L_(A269) R³² R³ R¹ L_(A270)R³² R⁴ R¹ L_(A271) R³² R⁵ R¹ L_(A272) R³² R⁶ R¹ L_(A273) R³² R⁷ R¹L_(A274) R³² R⁸ R¹ L_(A275) R³² R⁹ R¹ L_(A276) R³² R¹⁰ R¹ L_(A277) R³²R¹¹ R¹ L_(A278) R³² R¹² R¹ L_(A279) R³² R¹³ R¹ L_(A280) R³² R¹⁴ R¹L_(A281) R³² R¹⁵ R¹ L_(A282) R³² R¹⁶ R¹ L_(A283) R³² R¹⁷ R¹ L_(A284) R³²R¹⁸ R¹ L_(A285) R³² R¹⁹ R¹ L_(A286) R³² R²⁰ R¹ L_(A287) R³² R²¹ R¹L_(A288) R³² R²² R¹ L_(A289) R³² R²³ R¹ L_(A290) R³² R²⁴ R¹ L_(A291) R³²R²⁵ R¹ L_(A292) R³² R²⁶ R¹ L_(A293) R³² R²⁷ R¹ L_(A294) R³² R²⁸ R¹L_(A295) R³² R²⁹ R¹ L_(A296) R³² R³⁰ R¹ L_(A297) R³² R³¹ R¹ L_(A295) R³²R³³ R¹ L_(A299) R³² R³⁴ R¹ L_(A300) R³² R³⁵ R¹ L_(A301) R³² R³⁶ R¹L_(A302) R³² R³⁷ R¹ L_(A303) R³² R³⁸ R¹ L_(A304) R³² R³⁹ R¹ L_(A305) R³²R⁴⁰ R¹ L_(A306) R³² R⁴¹ R¹ L_(A307) R³² R⁴² R¹ L_(A308) R³² R⁴³ R¹L_(A309) R³² R⁴⁴ R¹ L_(A310) R³² R⁴⁵ R¹ L_(A311) R³² R⁴⁶ R¹ L_(A312) R³²R⁴⁷ R¹ L_(A313) R³² R⁴⁸ R¹ L_(A314) R³² R⁴⁹ R¹ L_(A315) R³² R⁵⁰ R¹L_(A316) R³² R⁵¹ R¹ L_(A317) R³² R⁵² R¹ L_(A318) R³² R⁵³ R¹ L_(A319) R³²R⁵⁴ R¹ L_(A320) R³⁶ R¹ R¹ L_(A321) R³⁶ R² R¹ L_(A322) R³⁶ R³ R¹ L_(A323)R³⁶ R⁴ R¹ L_(A324) R³⁶ R⁵ R¹ L_(A325) R³⁶ R⁶ R¹ L_(A326) R³⁶ R⁷ R¹L_(A327) R³⁶ R⁸ R¹ L_(A328) R³⁶ R⁹ R¹ L_(A329) R³⁶ R¹⁰ R¹ L_(A330) R³⁶R¹¹ R¹ L_(A331) R³⁶ R¹² R¹ L_(A332) R³⁶ R¹³ R¹ L_(A333) R³⁶ R¹⁴ R¹L_(A334) R³⁶ R¹⁵ R¹ L_(A335) R³⁶ R¹⁶ R¹ L_(A336) R³⁶ R¹⁷ R¹ L_(A337) R³⁶R¹⁸ R¹ L_(A338) R³⁶ R¹⁹ R¹ L_(A339) R³⁶ R²⁰ R¹ L_(A340) R³⁶ R²¹ R¹L_(A341) R³⁶ R²² R¹ L_(A342) R³⁶ R²³ R¹ L_(A343) R³⁶ R²⁴ R¹ L_(A344) R³⁶R²⁵ R¹ L_(A345) R³⁶ R²⁶ R¹ L_(A346) R³⁶ R²⁷ R¹ L_(A347) R³⁶ R²⁸ R¹L_(A348) R³⁶ R²⁹ R¹ L_(A349) R³⁶ R³⁰ R¹ L_(A350) R³⁶ R³¹ R¹ L_(A351) R³⁶R³² R¹ L_(A352) R³⁶ R³³ R¹ L_(A353) R³⁶ R³⁴ R¹ L_(A354) R³⁶ R³⁵ R¹L_(A355) R³⁶ R³⁷ R¹ L_(A356) R³⁶ R³⁸ R¹ L_(A357) R³⁶ R³⁹ R¹ L_(A358) R³⁶R⁴⁰ R¹ L_(A359) R³⁶ R⁴¹ R¹ L_(A360) R³⁶ R⁴² R¹ L_(A361) R³⁶ R⁴³ R¹L_(A362) R³⁶ R⁴⁴ R¹ L_(A363) R³⁶ R⁴⁵ R¹ L_(A364) R³⁶ R⁴⁶ R¹ L_(A365) R³⁶R⁴⁷ R¹ L_(A366) R³⁶ R⁴⁸ R¹ L_(A367) R³⁶ R⁴⁹ R¹ L_(A368) R³⁶ R⁵⁰ R¹L_(A369) R³⁶ R⁵¹ R¹ L_(A370) R³⁶ R⁵² R¹ L_(A371) R³⁶ R⁵³ R¹ L_(A372) R³⁶R⁵⁴ R¹ L_(A373) R¹ R¹ R³² L_(A374) R² R² R³² L_(A375) R³ R³ R³² L_(A376)R⁴ R⁴ R³² L_(A377) R⁵ R⁵ R³² L_(A378) R⁶ R⁶ R³² L_(A379) R⁷ R⁷ R³²L_(A380) R⁸ R⁸ R³² L_(A381) R⁹ R⁹ R³² L_(A382) R¹⁰ R¹⁰ R³² L_(A383) R¹¹R¹¹ R³² L_(A384) R¹² R¹² R³² L_(A385) R¹³ R¹³ R³² L_(A386) R¹⁴ R¹⁴ R³²L_(A387) R¹⁵ R¹⁵ R³² L_(A388) R¹⁶ R¹⁶ R³² L_(A389) R¹⁷ R¹⁷ R³² L_(A390)R¹⁸ R¹⁸ R³² L_(A391) R¹⁹ R¹⁹ R³² L_(A392) R²⁰ R²⁰ R³² L_(A393) R²¹ R²¹R³² L_(A394) R²² R²² R³² L_(A395) R²³ R²³ R³² L_(A396) R²⁴ R²⁴ R³²L_(A397) R²⁵ R²⁵ R³² L_(A398) R²⁶ R²⁶ R³² L_(A399) R²⁷ R²⁷ R³² L_(A400)R²⁸ R²⁸ R³² L_(A401) R²⁹ R²⁹ R³² L_(A402) R³⁰ R³⁰ R³² L_(A403) R³¹ R³¹R³² L_(A404) R³² R³² R³² L_(A405) R³³ R³³ R³² L_(A406) R³⁴ R³⁴ R³²L_(A407) R³⁵ R³⁵ R³² L_(A408) R³⁶ R³⁶ R³² L_(A409) R³⁷ R³⁷ R³² L_(A410)R³⁸ R³⁸ R³² L_(A411) R³⁹ R³⁹ R³² L_(A412) R⁴⁰ R⁴⁰ R³² L_(A413) R⁴¹ R⁴¹R³² L_(A414) R⁴² R⁴² R³² L_(A415) R⁴³ R⁴³ R³² L_(A416) R⁴⁴ R⁴⁴ R³²L_(A417) R⁴⁵ R⁴⁵ R³² L_(A418) R⁴⁶ R⁴⁶ R³² L_(A419) R⁴⁷ R⁴⁷ R³² L_(A420)R⁴⁸ R⁴⁸ R³² L_(A421) R⁴⁹ R⁴⁹ R³² L_(A422) R⁵⁰ R⁵⁰ R³² L_(A423) R⁵¹ R⁵¹R³² L_(A424) R⁵² R⁵² R³² L_(A425) R⁵³ R⁵³ R³² L_(A426) R⁵⁴ R⁵⁴ R³²L_(A427) R² R¹ R³² L_(A428) R³ R¹ R³² L_(A429) R⁴ R¹ R³² L_(A430) R⁵ R¹R³² L_(A431) R⁶ R¹ R³² L_(A432) R⁷ R¹ R³² L_(A433) R⁸ R¹ R³² L_(A434) R⁹R¹ R³² L_(A435) R¹⁰ R¹ R³² L_(A436) R¹¹ R¹ R³² L_(A437) R¹² R¹ R³²L_(A438) R¹³ R¹ R³² L_(A439) R¹⁴ R¹ R³² L_(A440) R¹⁵ R¹ R³² L_(A441) R¹⁶R¹ R³² L_(A442) R¹⁷ R¹ R³² L_(A443) R¹⁸ R¹ R³² L_(A444) R¹⁹ R¹ R³²L_(A445) R²⁰ R¹ R³² L_(A446) R²¹ R¹ R³² L_(A447) R²² R¹ R³² L_(A448) R²³R¹ R³² L_(A449) R²⁴ R¹ R³² L_(A450) R²⁵ R¹ R³² L_(A451) R²⁶ R¹ R³²L_(A452) R²⁷ R¹ R³² L_(A453) R²⁸ R¹ R³² L_(A454) R²⁹ R¹ R³² L_(A455) R³⁰R¹ R³² L_(A456) R³¹ R¹ R³² L_(A457) R³² R¹ R³² L_(A458) R³³ R¹ R³²L_(A459) R³⁴ R¹ R³² L_(A460) R³⁵ R¹ R³² L_(A461) R³⁶ R¹ R³² L_(A462) R³⁷R¹ R³² L_(A463) R³⁸ R¹ R³² L_(A464) R³⁹ R¹ R³² L_(A465) R⁴⁰ R¹ R³²L_(A466) R⁴¹ R¹ R³² L_(A467) R⁴² R¹ R³² L_(A468) R⁴³ R¹ R³² L_(A469) R⁴⁴R¹ R³² L_(A470) R⁴⁵ R¹ R³² L_(A471) R⁴⁶ R¹ R³² L_(A472) R⁴⁷ R¹ R³²L_(A473) R⁴⁸ R¹ R³² L_(A474) R⁴⁹ R¹ R³² L_(A475) R⁵⁰ R¹ R³² L_(A476) R⁵¹R¹ R³² L_(A477) R⁵² R¹ R³² L_(A478) R⁵³ R¹ R³² L_(A479) R⁵⁴ R¹ R³²L_(A480) R¹ R³² R³² L_(A481) R² R³² R³² L_(A482) R³ R³² R³² L_(A483) R⁴R³² R³² L_(A484) R⁵ R³² R³² L_(A485) R⁶ R³² R³² L_(A486) R⁷ R³² R³²L_(A487) R⁸ R³² R³² L_(A488) R⁹ R³² R³² L_(A489) R¹⁰ R³² R³² L_(A490)R¹¹ R³² R³² L_(A491) R¹² R³² R³² L_(A492) R¹³ R³² R³² L_(A493) R¹⁴ R³²R³² L_(A494) R¹⁵ R³² R³² L_(A495) R¹⁶ R³² R³² L_(A496) R¹⁷ R³² R³²L_(A497) R¹⁸ R³² R³² L_(A498) R¹⁹ R³² R³² L_(A499) R²⁰ R³² R³² L_(A500)R²¹ R³² R³² L_(A501) R²² R³² R³² L_(A502) R²³ R³² R³² L_(A503) R²⁴ R³²R³² L_(A504) R²⁵ R³² R³² L_(A505) R²⁶ R³² R³² L_(A506) R²⁷ R³² R³²L_(A507) R²⁸ R³² R³² L_(A508) R²⁹ R³² R³² L_(A509) R³⁰ R³² R³² L_(A510)R³¹ R³² R³² L_(A511) R³³ R³² R³² L_(A512) R³⁴ R³² R³² L_(A513) R³⁵ R³²R³² L_(A514) R³⁶ R³² R³² L_(A515) R³⁷ R³² R³² L_(A516) R³⁸ R³² R³²L_(A517) R³⁹ R³² R³² L_(A518) R⁴⁰ R³² R³² L_(A519) R⁴¹ R³² R³² L_(A520)R⁴² R³² R³² L_(A521) R⁴³ R³² R³² L_(A522) R⁴⁴ R³² R³² L_(A523) R⁴⁵ R³²R³² L_(A524) R⁴⁶ R³² R³² L_(A525) R⁴⁷ R³² R³² L_(A526) R⁴⁸ R³² R³²L_(A527) R⁴⁹ R³² R³² L_(A528) R⁵⁰ R³² R³² L_(A529) R⁵¹ R³² R³² L_(A530)R⁵² R³² R³² L_(A531) R⁵³ R³² R³² L_(A532) R⁵⁴ R³² R³² L_(A533) R¹ R³⁶R³² L_(A534) R² R³⁶ R³² L_(A535) R³ R³⁶ R³² L_(A536) R⁴ R³⁶ R³² L_(A537)R⁵ R³⁶ R³² L_(A538) R⁶ R³⁶ R³² L_(A539) R⁷ R³⁶ R³² L_(A540) R⁸ R³⁶ R³²L_(A541) R⁹ R³⁶ R³² L_(A542) R¹⁰ R³⁶ R³² L_(A543) R¹¹ R³⁶ R³² L_(A544)R¹² R³⁶ R³² L_(A545) R¹³ R³⁶ R³² L_(A546) R¹⁴ R³⁶ R³² L_(A547) R¹⁵ R³⁶R³² L_(A548) R¹⁶ R³⁶ R³² L_(A549) R¹⁷ R³⁶ R³² L_(A550) R¹⁸ R³⁶ R³²L_(A551) R¹⁹ R³⁶ R³² L_(A552) R²⁰ R³⁶ R³² L_(A553) R²¹ R³⁶ R³² L_(A554)R²² R³⁶ R³² L_(A555) R²³ R³⁶ R³² L_(A556) R²⁴ R³⁶ R³² L_(A557) R²⁵ R³⁶R³² L_(A558) R²⁶ R³⁶ R³² L_(A559) R²⁷ R³⁶ R³² L_(A560) R²⁸ R³⁶ R³²L_(A561) R²⁹ R³⁶ R³² L_(A562) R³⁰ R³⁶ R³² L_(A563) R³¹ R³⁶ R³² L_(A564)R³² R³⁶ R³² L_(A565) R³³ R³⁶ R³² L_(A566) R³⁴ R³⁶ R³² L_(A567) R³⁵ R³⁶R³² L_(A568) R³⁷ R³⁶ R³² L_(A569) R³⁸ R³⁶ R³² L_(A570) R³⁹ R³⁶ R³²L_(A571) R⁴⁰ R³⁶ R³² L_(A572) R⁴¹ R³⁶ R³² L_(A573) R⁴² R³⁶ R³² L_(A574)R⁴³ R³⁶ R³² L_(A575) R⁴⁴ R³⁶ R³² L_(A576) R⁴⁵ R³⁶ R³² L_(A577) R⁴⁶ R³⁶R³² L_(A578) R⁴⁷ R³⁶ R³² L_(A579) R⁴⁸ R³⁶ R³² L_(A580) R⁴⁹ R³⁶ R³²L_(A581) R⁵⁰ R³⁶ R³² L_(A582) R⁵¹ R³⁶ R³² L_(A583) R⁵² R³⁶ R³² L_(A584)R⁵³ R³⁶ R³² L_(A585) R⁵⁴ R³⁶ R³² L_(A586) R¹ R² R³² L_(A587) R¹ R³ R³²L_(A588) R¹ R⁴ R³² L_(A589) R¹ R⁵ R³² L_(A590) R¹ R⁶ R³² L_(A591) R¹ R⁷R³² L_(A592) R¹ R⁸ R³² L_(A593) R¹ R⁹ R³² L_(A594) R¹ R¹⁰ R³² L_(A595)R¹ R¹¹ R³² L_(A596) R¹ R¹² R³² L_(A597) R¹ R¹³ R³² L_(A598) R¹ R¹⁴ R³²L_(A599) R¹ R¹⁵ R³² L_(A600) R¹ R¹⁶ R³² L_(A601) R¹ R¹⁷ R³² L_(A602) R¹R¹⁸ R³² L_(A603) R¹ R¹⁹ R³² L_(A604) R¹ R²⁰ R³² L_(A605) R¹ R²¹ R³²L_(A606) R¹ R²² R³² L_(A607) R¹ R²³ R³² L_(A608) R¹ R²⁴ R³² L_(A609) R¹R²⁵ R³² L_(A610) R¹ R²⁶ R³² L_(A611) R¹ R²⁷ R³² L_(A612) R¹ R²⁸ R³²L_(A613) R¹ R²⁹ R³² L_(A614) R¹ R³⁰ R³² L_(A615) R¹ R³¹ R³² L_(A616) R¹R³² R³² L_(A617) R¹ R³³ R³² L_(A618) R¹ R³⁴ R³² L_(A619) R¹ R³⁵ R³²L_(A620) R¹ R³⁶ R³² L_(A621) R¹ R³⁷ R³² L_(A622) R¹ R³⁸ R³² L_(A623) R¹R³⁹ R³² L_(A624) R¹ R⁴⁰ R³² L_(A625) R¹ R⁴¹ R³² L_(A626) R¹ R⁴² R³²L_(A627) R¹ R⁴³ R³² L_(A628) R¹ R⁴⁴ R³² L_(A629) R¹ R⁴⁵ R³² L_(A630) R¹R⁴⁶ R³² L_(A631) R¹ R⁴⁷ R³² L_(A632) R¹ R⁴⁸ R³² L_(A633) R¹ R⁴⁹ R³²L_(A634) R¹ R⁵⁰ R³² L_(A635) R¹ R⁵¹ R³² L_(A636) R¹ R⁵² R³² L_(A637) R¹R⁵³ R³² L_(A638) R¹ R⁵⁴ R³² L_(A639) R³² R¹ R³² L_(A640) R³² R² R³²L_(A641) R³² R³ R³² L_(A642) R³² R⁴ R³² L_(A643) R³² R⁵ R³² L_(A644) R³²R⁶ R³² L_(A645) R³² R⁷ R³² L_(A646) R³² R⁸ R³² L_(A647) R³² R⁹ R³²L_(A645) R³² R¹⁰ R³² L_(A649) R³² R¹¹ R³² L_(A650) R³² R¹² R³² L_(A651)R³² R¹³ R³² L_(A652) R³² R¹⁴ R³² L_(A653) R³² R¹⁵ R³² L_(A654) R³² R¹⁶R³² L_(A655) R³² R¹⁷ R³² L_(A656) R³² R¹⁸ R³² L_(A657) R³² R¹⁹ R³²L_(A658) R³² R²⁰ R³² L_(A659) R³² R²¹ R³² L_(A660) R³² R²² R³² L_(A661)R³² R²³ R³² L_(A662) R³² R²⁴ R³² L_(A663) R³² R²⁵ R³² L_(A664) R³² R²⁶R³² L_(A665) R³² R²⁷ R³² L_(A666) R³² R²⁸ R³² L_(A667) R³² R²⁹ R³²L_(A668) R³² R³⁰ R³² L_(A669) R³² R³¹ R³² L_(A670) R³² R³³ R³² L_(A671)R³² R³⁴ R³² L_(A672) R³² R³⁵ R³² L_(A673) R³² R³⁶ R³² L_(A674) R³² R³⁷R³² L_(A675) R³² R³⁸ R³² L_(A676) R³² R³⁹ R³² L_(A677) R³² R⁴⁰ R³²L_(A678) R³² R⁴¹ R³² L_(A679) R³² R⁴² R³² L_(A680) R³² R⁴³ R³² L_(A681)R³² R⁴⁴ R³² L_(A682) R³² R⁴⁵ R³² L_(A683) R³² R⁴⁶ R³² L_(A684) R³² R⁴⁷R³² L_(A685) R³² R⁴⁸ R³² L_(A686) R³² R⁴⁹ R³² L_(A687) R³² R⁵⁰ R³²L_(A688) R³² R⁵¹ R³² L_(A689) R³² R⁵² R³² L_(A690) R³² R⁵³ R³² L_(A691)R³² R⁵⁴ R³² L_(A692) R³⁶ R¹ R³² L_(A693) R³⁶ R² R³² L_(A694) R³⁶ R³ R³²L_(A695) R³⁶ R⁴ R³² L_(A696) R³⁶ R⁵ R³² L_(A697) R³⁶ R⁶ R³² L_(A698) R³⁶R⁷ R³² L_(A699) R³⁶ R⁸ R³² L_(A700) R³⁶ R⁹ R³² L_(A701) R³⁶ R¹⁰ R³²L_(A702) R³⁶ R¹¹ R³² L_(A703) R³⁶ R¹² R³² L_(A704) R³⁶ R¹³ R³² L_(A705)R³⁶ R¹⁴ R³² L_(A706) R³⁶ R¹⁵ R³² L_(A707) R³⁶ R¹⁶ R³² L_(A708) R³⁶ R¹⁷R³² L_(A709) R³⁶ R¹⁸ R³² L_(A710) R³⁶ R¹⁹ R³² L_(A711) R³⁶ R²⁰ R³²L_(A712) R³⁶ R²¹ R³² L_(A713) R³⁶ R²² R³² L_(A714) R³⁶ R²³ R³² L_(A715)R³⁶ R²⁴ R³² L_(A716) R³⁶ R²⁵ R³² L_(A717) R³⁶ R²⁶ R³² L_(A718) R³⁶ R²⁷R³² L_(A719) R³⁶ R²⁸ R³² L_(A720) R³⁶ R²⁹ R³² L_(A721) R³⁶ R³⁰ R³²L_(A722) R³⁶ R³¹ R³² L_(A723) R³⁶ R³² R³² L_(A724) R³⁶ R³³ R³² L_(A725)R³⁶ R³⁴ R³² L_(A726) R³⁶ R³⁵ R³² L_(A727) R³⁶ R³⁷ R³² L_(A728) R³⁶ R³⁸R³² L_(A729) R³⁶ R³⁹ R³² L_(A730) R³⁶ R⁴⁰ R³² L_(A731) R³⁶ R⁴¹ R³²L_(A732) R³⁶ R⁴² R³² L_(A733) R³⁶ R⁴³ R³² L_(A734) R³⁶ R⁴⁴ R³² L_(A735)R³⁶ R⁴⁵ R³² L_(A736) R³⁶ R⁴⁶ R³² L_(A737) R³⁶ R⁴⁷ R³² L_(A738) R³⁶ R⁴⁸R³² L_(A739) R³⁶ R⁴⁹ R³² L_(A740) R³⁶ R⁵⁰ R³² L_(A741) R³⁶ R⁵¹ R³²L_(A742) R³⁶ R⁵² R³² L_(A743) R³⁶ R⁵³ R³² L_(A744) R³⁶ R⁵⁴ R³² L_(A745)R¹ R¹ R³⁶ L_(A746) R² R² R³⁶ L_(A747) R³ R³ R³⁶ L_(A748) R⁴ R⁴ R³⁶L_(A749) R⁵ R⁵ R³⁶ L_(A750) R⁶ R⁶ R³⁶ L_(A751) R⁷ R⁷ R³⁶ L_(A752) R⁸ R⁸R³⁶ L_(A753) R⁹ R⁹ R³⁶ L_(A754) R¹⁰ R¹⁰ R³⁶ L_(A755) R¹¹ R¹¹ R³⁶L_(A756) R¹² R¹² R³⁶ L_(A757) R¹³ R¹³ R³⁶ L_(A758) R¹⁴ R¹⁴ R³⁶ L_(A759)R¹⁵ R¹⁵ R³⁶ L_(A760) R¹⁶ R¹⁶ R³⁶ L_(A761) R¹⁷ R¹⁷ R³⁶ L_(A762) R¹⁸ R¹⁸R³⁶ L_(A763) R¹⁹ R¹⁹ R³⁶ L_(A764) R²⁰ R²⁰ R³⁶ L_(A765) R²¹ R²¹ R³⁶L_(A766) R²² R²² R³⁶ L_(A767) R²³ R²³ R³⁶ L_(A768) R²⁴ R²⁴ R³⁶ L_(A769)R²⁵ R²⁵ R³⁶ L_(A770) R²⁶ R²⁶ R³⁶ L_(A771) R²⁷ R²⁷ R³⁶ L_(A772) R²⁸ R²⁸R³⁶ L_(A773) R²⁹ R²⁹ R³⁶ L_(A774) R³⁰ R³⁰ R³⁶ L_(A775) R³¹ R³¹ R³⁶L_(A776) R³² R³² R³⁶ L_(A777) R³³ R³³ R³⁶ L_(A778) R³⁴ R³⁴ R³⁶ L_(A779)R³⁵ R³⁵ R³⁶ L_(A780) R³⁶ R³⁶ R³⁶ L_(A781) R³⁷ R³⁷ R³⁶ L_(A782) R³⁸ R³⁸R³⁶ L_(A783) R³⁹ R³⁹ R³⁶ L_(A784) R⁴⁰ R⁴⁰ R³⁶ L_(A785) R⁴¹ R⁴¹ R³⁶L_(A786) R⁴² R⁴² R³⁶ L_(A787) R⁴³ R⁴³ R³⁶ L_(A788) R⁴⁴ R⁴⁴ R³⁶ L_(A789)R⁴⁵ R⁴⁵ R³⁶ L_(A790) R⁴⁶ R⁴⁶ R³⁶ L_(A791) R⁴⁷ R⁴⁷ R³⁶ L_(A792) R⁴⁸ R⁴⁸R³⁶ L_(A793) R⁴⁹ R⁴⁹ R³⁶ L_(A794) R⁵⁰ R⁵⁰ R³⁶ L_(A795) R⁵¹ R⁵¹ R³⁶L_(A796) R⁵² R⁵² R³⁶ L_(A797) R⁵³ R⁵³ R³⁶ L_(A798) R⁵⁴ R⁵⁴ R³⁶ L_(A799)R² R¹ R³⁶ L_(A800) R³ R¹ R³⁶ L_(A801) R⁴ R¹ R³⁶ L_(A802) R⁵ R¹ R³⁶L_(A803) R⁶ R¹ R³⁶ L_(A804) R⁷ R¹ R³⁶ L_(A805) R⁸ R¹ R³⁶ L_(A806) R⁹ R¹R³⁶ L_(A807) R¹⁰ R¹ R³⁶ L_(A808) R¹¹ R¹ R³⁶ L_(A809) R¹² R¹ R³⁶ L_(A810)R¹³ R¹ R³⁶ L_(A811) R¹⁴ R¹ R³⁶ L_(A812) R¹⁵ R¹ R³⁶ L_(A813) R¹⁶ R¹ R³⁶L_(A814) R¹⁷ R¹ R³⁶ L_(A815) R¹⁸ R¹ R³⁶ L_(A816) R¹⁹ R¹ R³⁶ L_(A817) R²⁰R¹ R³⁶ L_(A818) R²¹ R¹ R³⁶ L_(A819) R²² R¹ R³⁶ L_(A820) R²³ R¹ R³⁶L_(A821) R²⁴ R¹ R³⁶ L_(A822) R²⁵ R¹ R³⁶ L_(A823) R²⁶ R¹ R³⁶ L_(A824) R²⁷R¹ R³⁶ L_(A825) R²⁸ R¹ R³⁶ L_(A826) R²⁹ R¹ R³⁶ L_(A827) R³⁰ R¹ R³⁶L_(A828) R³¹ R¹ R³⁶ L_(A829) R³² R¹ R³⁶ L_(A830) R³³ R¹ R³⁶ L_(A831) R³⁴R¹ R³⁶ L_(A832) R³⁵ R¹ R³⁶ L_(A833) R³⁶ R¹ R³⁶ L_(A834) R³⁷ R¹ R³⁶L_(A835) R³⁸ R¹ R³⁶ L_(A836) R³⁹ R¹ R³⁶ L_(A837) R⁴⁰ R¹ R³⁶ L_(A838) R⁴¹R¹ R³⁶ L_(A839) R⁴² R¹ R³⁶ L_(A840) R⁴³ R¹ R³⁶ L_(A841) R⁴⁴ R¹ R³⁶L_(A842) R⁴⁵ R¹ R³⁶ L_(A843) R⁴⁶ R¹ R³⁶ L_(A844) R⁴⁷ R¹ R³⁶ L_(A845) R⁴⁸R¹ R³⁶ L_(A846) R⁴⁹ R¹ R³⁶ L_(A847) R⁵⁰ R¹ R³⁶ L_(A848) R⁵¹ R¹ R³⁶L_(A849) R⁵² R¹ R³⁶ L_(A850) R⁵³ R¹ R³⁶ L_(A851) R⁵⁴ R¹ R³⁶ L_(A852) R¹R³² R³⁶ L_(A853) R² R³² R³⁶ L_(A854) R³ R³² R³⁶ L_(A855) R⁴ R³² R³⁶L_(A856) R⁵ R³² R³⁶ L_(A857) R⁶ R³² R³⁶ L_(A858) R⁷ R³² R³⁶ L_(A859) R⁸R³² R³⁶ L_(A860) R⁹ R³² R³⁶ L_(A861) R¹⁰ R³² R³⁶ L_(A862) R¹¹ R³² R³⁶L_(A863) R¹² R³² R³⁶ L_(A864) R¹³ R³² R³⁶ L_(A865) R¹⁴ R³² R³⁶ L_(A866)R¹⁵ R³² R³⁶ L_(A867) R¹⁶ R³² R³⁶ L_(A868) R¹⁷ R³² R³⁶ L_(A869) R¹⁸ R³²R³⁶ L_(A870) R¹⁹ R³² R³⁶ L_(A871) R²⁰ R³² R³⁶ L_(A872) R²¹ R³² R³⁶L_(A873) R²² R³² R³⁶ L_(A874) R²³ R³² R³⁶ L_(A875) R²⁴ R³² R³⁶ L_(A876)R²⁵ R³² R³⁶ L_(A877) R²⁶ R³² R³⁶ L_(A878) R²⁷ R³² R³⁶ L_(A879) R²⁸ R³²R³⁶ L_(A880) R²⁹ R³² R³⁶ L_(A881) R³⁰ R³² R³⁶ L_(A882) R³¹ R³² R³⁶L_(A883) R³³ R³² R³⁶ L_(A884) R³⁴ R³² R³⁶ L_(A885) R³⁵ R³² R³⁶ L_(A886)R³⁶ R³² R³⁶ L_(A887) R³⁷ R³² R³⁶ L_(A888) R³⁸ R³² R³⁶ L_(A889) R³⁹ R³²R³⁶ L_(A890) R⁴⁰ R³² R³⁶ L_(A891) R⁴¹ R³² R³⁶ L_(A892) R⁴² R³² R³⁶L_(A893) R⁴³ R³² R³⁶ L_(A894) R⁴⁴ R³² R³⁶ L_(A895) R⁴⁵ R³² R³⁶ L_(A896)R⁴⁶ R³² R³⁶ L_(A897) R⁴⁷ R³² R³⁶ L_(A898) R⁴⁸ R³² R³⁶ L_(A899) R⁴⁹ R³²R³⁶ L_(A900) R⁵⁰ R³² R³⁶ L_(A901) R⁵¹ R³² R³⁶ L_(A902) R⁵² R³² R³⁶L_(A903) R⁵³ R³² R³⁶ L_(A904) R⁵⁴ R³² R³⁶ L_(A905) R¹ R³⁶ R³⁶ L_(A906)R² R³⁶ R³⁶ L_(A907) R³ R³⁶ R³⁶ L_(A908) R⁴ R³⁶ R³⁶ L_(A909) R⁵ R³⁶ R³⁶L_(A910) R⁶ R³⁶ R³⁶ L_(A911) R⁷ R³⁶ R³⁶ L_(A912) R⁸ R³⁶ R³⁶ L_(A913) R⁹R³⁶ R³⁶ L_(A914) R¹⁰ R³⁶ R³⁶ L_(A915) R¹¹ R³⁶ R³⁶ L_(A916) R¹² R³⁶ R³⁶L_(A917) R¹³ R³⁶ R³⁶ L_(A918) R¹⁴ R³⁶ R³⁶ L_(A919) R¹⁵ R³⁶ R³⁶ L_(A920)R¹⁶ R³⁶ R³⁶ L_(A921) R¹⁷ R³⁶ R³⁶ L_(A922) R¹⁸ R³⁶ R³⁶ L_(A923) R¹⁹ R³⁶R³⁶ L_(A924) R²⁰ R³⁶ R³⁶ L_(A925) R²¹ R³⁶ R³⁶ L_(A926) R²² R³⁶ R³⁶L_(A927) R²³ R³⁶ R³⁶ L_(A928) R²⁴ R³⁶ R³⁶ L_(A928) R²⁵ R³⁶ R³⁶ L_(A930)R²⁶ R³⁶ R³⁶ L_(A931) R²⁷ R³⁶ R³⁶ L_(A932) R²⁸ R³⁶ R³⁶ L_(A933) R²⁹ R³⁶R³⁶ L_(A934) R³⁰ R³⁶ R³⁶ L_(A935) R³¹ R³⁶ R³⁶ L_(A936) R³² R³⁶ R³⁶L_(A937) R³³ R³⁶ R³⁶ L_(A938) R³⁴ R³⁶ R³⁶ L_(A939) R³⁵ R³⁶ R³⁶ L_(A940)R³⁷ R³⁶ R³⁶ L_(A941) R³⁸ R³⁶ R³⁶ L_(A942) R³⁹ R³⁶ R³⁶ L_(A943) R⁴⁰ R³⁶R³⁶ L_(A944) R⁴¹ R³⁶ R³⁶ L_(A945) R⁴² R³⁶ R³⁶ L_(A946) R⁴³ R³⁶ R³⁶L_(A947) R⁴⁴ R³⁶ R³⁶ L_(A948) R⁴⁵ R³⁶ R³⁶ L_(A949) R⁴⁶ R³⁶ R³⁶ L_(A950)R⁴⁷ R³⁶ R³⁶ L_(A951) R⁴⁸ R³⁶ R³⁶ L_(A952) R⁴⁹ R³⁶ R³⁶ L_(A953) R⁵⁰ R³⁶R³⁶ L_(A954) R⁵¹ R³⁶ R³⁶ L_(A955) R⁵² R³⁶ R³⁶ L_(A956) R⁵³ R³⁶ R³⁶L_(A957) R⁵⁴ R³⁶ R³⁶ L_(A958) R¹ R² R³⁶ L_(A959) R¹ R³ R³⁶ L_(A960) R¹R⁴ R³⁶ L_(A961) R¹ R⁵ R³⁶ L_(A962) R¹ R⁶ R³⁶ L_(A963) R¹ R⁷ R³⁶ L_(A964)R¹ R⁸ R³⁶ L_(A665) R¹ R⁹ R³⁶ L_(A966) R¹ R¹⁰ R³⁶ L_(A967) R¹ R¹¹ R³⁶L_(A968) R¹ R¹² R³⁶ L_(A969) R¹ R¹³ R³⁶ L_(A970) R¹ R¹⁴ R³⁶ L_(A971) R¹R¹⁵ R³⁶ L_(A972) R¹ R¹⁶ R³⁶ L_(A973) R¹ R¹⁷ R³⁶ L_(A974) R¹ R¹⁸ R³⁶L_(A975) R¹ R¹⁹ R³⁶ L_(A976) R¹ R²⁰ R³⁶ L_(A977) R¹ R²¹ R³⁶ L_(A978) R¹R²² R³⁶ L_(A979) R¹ R²³ R³⁶ L_(A980) R¹ R²⁴ R³⁶ L_(A981) R¹ R²⁵ R³⁶L_(A982) R¹ R²⁶ R³⁶ L_(A983) R¹ R²⁷ R³⁶ L_(A984) R¹ R²⁸ R³⁶ L_(A985) R¹R²⁹ R³⁶ L_(A986) R¹ R³⁰ R³⁶ L_(A987) R¹ R³¹ R³⁶ L_(A988) R¹ R³² R³⁶L_(A989) R¹ R³³ R³⁶ L_(A990) R¹ R³⁴ R³⁶ L_(A991) R¹ R³⁵ R³⁶ L_(A992) R¹R³⁶ R³⁶ L_(A993) R¹ R³⁷ R³⁶ L_(A994) R¹ R³⁸ R³⁶ L_(A995) R¹ R³⁹ R³⁶L_(A996) R¹ R⁴⁰ R³⁶ L_(A997) R¹ R⁴¹ R³⁶ L_(A998) R¹ R⁴² R³⁶ L_(A999) R¹R⁴³ R³⁶ L_(A1000) R¹ R⁴⁴ R³⁶ L_(A1001) R¹ R⁴⁵ R³⁶ L_(A1002) R¹ R⁴⁶ R³⁶L_(A1003) R¹ R⁴⁷ R³⁶ L_(A1004) R¹ R⁴⁸ R³⁶ L_(A1005) R¹ R⁴⁹ R³⁶ L_(A1006)R¹ R⁵⁰ R³⁶ L_(A1007) R¹ R⁵¹ R³⁶ L_(A1008) R¹ R⁵² R³⁶ L_(A1009) R¹ R⁵³R³⁶ L_(A1010) R¹ R⁵⁴ R³⁶ L_(A1011) R³² R¹ R³⁶ L_(A1012) R³² R² R³⁶L_(A1013) R³² R³ R³⁶ L_(A1014) R³² R⁴ R³⁶ L_(A1015) R³² R⁵ R³⁶ L_(A1016)R³² R⁶ R³⁶ L_(A1017) R³² R⁷ R³⁶ L_(A1018) R³² R⁸ R³⁶ L_(A1019) R³² R⁹R³⁶ L_(A1020) R³² R¹⁰ R³⁶ L_(A1021) R³² R¹¹ R³⁶ L_(A1022) R³² R¹² R³⁶L_(A1023) R³² R¹³ R³⁶ L_(A1024) R³² R¹⁴ R³⁶ L_(A1025) R³² R¹⁵ R³⁶L_(A1026) R³² R¹⁶ R³⁶ L_(A1027) R³² R¹⁷ R³⁶ L_(A1028) R³² R¹⁸ R³⁶L_(A1029) R³² R¹⁹ R³⁶ L_(A1030) R³² R²⁰ R³⁶ L_(A1031) R³² R²¹ R³⁶L_(A1032) R³² R²² R³⁶ L_(A1033) R³² R²³ R³⁶ L_(A1034) R³² R²⁴ R³⁶L_(A1035) R³² R²⁵ R³⁶ L_(A1036) R³² R²⁶ R³⁶ L_(A1037) R³² R²⁷ R³⁶L_(A1038) R³² R²⁸ R³⁶ L_(A1039) R³² R²⁹ R³⁶ L_(A1040) R³² R³⁰ R³⁶L_(A1041) R³² R³¹ R³⁶ L_(A1042) R³² R³³ R³⁶ L_(A1043) R³² R³⁴ R³⁶L_(A1044) R³² R³⁵ R³⁶ L_(A1045) R³² R³⁶ R³⁶ L_(A1046) R³² R³⁷ R³⁶L_(A1047) R³² R³⁸ R³⁶ L_(A1048) R³² R³⁹ R³⁶ L_(A1049) R³² R⁴⁰ R³⁶L_(A1050) R³² R⁴¹ R³⁶ L_(A1051) R³² R⁴² R³⁶ L_(A1052) R³² R⁴³ R³⁶L_(A1053) R³² R⁴⁴ R³⁶ L_(A1054) R³² R⁴⁵ R³⁶ L_(A1055) R³² R⁴⁶ R³⁶L_(A1056) R³² R⁴⁷ R³⁶ L_(A1057) R³² R⁴⁸ R³⁶ L_(A1058) R³² R⁴⁹ R³⁶L_(A1059) R³² R⁵⁰ R³⁶ L_(A1060) R³² R⁵¹ R³⁶ L_(A1061) R³² R⁵² R³⁶L_(A1062) R³² R⁵³ R³⁶ L_(A1063) R³² R⁵⁴ R³⁶ L_(A1064) R³⁶ R¹ R³⁶L_(A1065) R³⁶ R² R³⁶ L_(A1066) R³⁶ R³ R³⁶ L_(A1067) R³⁶ R⁴ R³⁶ L_(A1068)R³⁶ R⁵ R³⁶ L_(A1069) R³⁶ R⁶ R³⁶ L_(A1070) R³⁶ R⁷ R³⁶ L_(A1071) R³⁶ R⁸R³⁶ L_(A1072) R³⁶ R⁹ R³⁶ L_(A1073) R³⁶ R¹⁰ R³⁶ L_(A1074) R³⁶ R¹¹ R³⁶L_(A1075) R³⁶ R¹² R³⁶ L_(A1076) R³⁶ R¹³ R³⁶ L_(A1077) R³⁶ R¹⁴ R³⁶L_(A1078) R³⁶ R¹⁵ R³⁶ L_(A1079) R³⁶ R¹⁶ R³⁶ L_(A1080) R³⁶ R¹⁷ R³⁶L_(A1081) R³⁶ R¹⁸ R³⁶ L_(A1082) R³⁶ R¹⁹ R³⁶ L_(A1083) R³⁶ R²⁰ R³⁶L_(A1084) R³⁶ R²¹ R³⁶ L_(A1085) R³⁶ R²² R³⁶ L_(A1086) R³⁶ R²³ R³⁶L_(A1087) R³⁶ R²⁴ R³⁶ L_(A1088) R³⁶ R²⁵ R³⁶ L_(A1089) R³⁶ R²⁶ R³⁶L_(A1090) R³⁶ R²⁷ R³⁶ L_(A1091) R³⁶ R²⁸ R³⁶ L_(A1092) R³⁶ R²⁹ R³⁶L_(A1093) R³⁶ R³⁰ R³⁶ L_(A1094) R³⁶ R³¹ R³⁶ L_(A1095) R³⁶ R³² R³⁶L_(A1096) R³⁶ R³³ R³⁶ L_(A1097) R³⁶ R³⁴ R³⁶ L_(A1098) R³⁶ R³⁵ R³⁶L_(A1099) R³⁶ R³⁷ R³⁶ L_(A1100) R³⁶ R³⁸ R³⁶ L_(A1101) R³⁶ R³⁹ R³⁶L_(A1102) R³⁶ R⁴⁰ R³⁶ L_(A1103) R³⁶ R⁴¹ R³⁶ L_(A1104) R³⁶ R⁴² R³⁶L_(A1105) R³⁶ R⁴³ R³⁶ L_(A1106) R³⁶ R⁴⁴ R³⁶ L_(A1107) R³⁶ R⁴⁵ R³⁶L_(A1108) R³⁶ R⁴⁶ R³⁶ L_(A1109) R³⁶ R⁴⁷ R³⁶ L_(A1110) R³⁶ R⁴⁸ R³⁶L_(A1111) R³⁶ R⁴⁹ R³⁶ L_(A1112) R³⁶ R⁵⁰ R³⁶ L_(A1113) R³⁶ R⁵¹ R³⁶L_(A1114) R³⁶ R⁵² R³⁶ L_(A1115) R³⁶ R⁵³ R³⁶ L_(A1116) R³⁶ R⁵⁴ R³⁶

wherein each R^(E), R^(F), and R^(G) is defined as follows:


12. The compound of claim 1, wherein the compound has a formula selectedfrom the group consisting of Ir(L_(A))₃, Ir(L_(A))(L_(B))₂,Ir(L_(A))₂(L_(B)), Ir(L_(A))₂(L_(C)), and Ir(L_(A))(L_(B))(L_(C)),wherein L_(A), L_(B), and L_(C) are different from each other.
 13. Thecompound of claim 12, wherein L_(B) and L_(C) are each independentlyselected from the group consisting of:

wherein: T is B, Al, Ga, In; each of Y¹ to Y¹³ is independently selectedfrom the group consisting of carbon and nitrogen; Y′ is selected fromthe group consisting of BR_(e), NR_(e), PR_(e), O, S, Se, C═O, S═O, SO₂,CR_(e)R_(f), SiR_(e)R_(f), and GeR_(e)R_(f); R_(e) and R_(f) can befused or joined to form a ring; each R_(a), R_(b), R_(c), and R_(d)independently represents zero, mono, or up to a maximum allowed numberof substitutions to its associated ring; each of R_(a1), R_(b1), R_(c1),R_(d1), R_(a), R_(b), R_(c), R_(d), R_(e) and R_(f) is independently ahydrogen or a substituent selected from the group consisting ofdeuterium, halide, alkyl, cycloalkyl, heteroalkyl, arylalkyl, alkoxy,aryloxy, amino, silyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl,alkynyl, aryl, heteroaryl, acyl, carbonyl, carboxylic acid, ester,nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, andcombinations thereof; the general substituents defined herein; and anytwo adjacent R_(a), R_(b), R_(c), R_(d), R_(e) and R_(f) can be fused orjoined to form a ring or form a multidentate ligand.
 14. The compound ofclaim 12, wherein when the compound has formula Ir(L_(Ah-m))₃, h is aninteger from 1 to 1116; m is an integer from 1 to 48; and the compoundis selected from the group consisting of Ir(L_(A1-1))₃ toIr(L_(A1116-48))₃; when the compound has formula Ir(L_(Ah-m))(L_(Bk))₂,h is an integer from 1 to 1116; m is an integer from 1 to 48; k is aninteger from 1 to 264; and the compound is selected from the groupconsisting of Ir(L_(A1-1))(L_(B1))₂ to Ir(L_(A1116-48))(L_(B264))₂, whenthe compound has formula Ir(L_(Ah-m))₂(L_(Bk)), h is an integer from 1to 1116; m is an integer from 1 to 48; k is an integer from 1 to 264;and the compound is selected from the group consisting ofIr(L_(A1-1))₂(L_(B1)) to Ir(L_(A1116-48))₂(L_(B264)), when the compoundhas formula Ir(L_(Ah-m))₂(L_(Cj-I)), h is an integer from 1 to 1116; mis an integer from 1 to 48; j is an integer from 1 to 1416; and thecompound is selected from the group consisting ofIr(L_(A1-1))₂(L_(C1-1)) to Ir(L_(A1116-48)) (L_(C1416-I)); and when thecompound has formula Ir(L_(Ah-m))₂(L_(Cj-II)), h is an integer from 1 to1116; m is an integer from 1 to 48; j is an integer from 1 to 1416; andthe compound is selected from the group consisting ofIr(L_(A1-1))₂(L_(C1-II)) to Ir(L_(A1116-48)) (L_(C1416-II)); whereineach structure of L_(Ai-m) is defined according to claim 22; whereineach structure of L_(Bk) is defined in the following LIST 5

wherein each L_(Cj-I) has a structure based on

and each L_(Cj-II) has a structure based on

wherein for each L_(Cj) in L_(Cj-I) and L_(Cj-II), R²⁰¹ and R²⁰² areeach independently defined in the following LIST 6 L_(Cj) R²⁰¹ R²⁰²L_(Cj) R²⁰¹ R²⁰² L_(Cj) R²⁰¹ R²⁰² L_(Cj) R²⁰¹ R²⁰² L_(C1) R^(D1) R^(D1)L_(C193) R^(D1) R^(D3) L_(C385) R^(D17) R^(D40) L_(C577) R^(D143)R^(D120) L_(C2) R^(D2) R^(D2) L_(C194) R^(D1) R^(D4) L_(C386) R^(D17)R^(D41) L_(C578) R^(D143) R^(D133) L_(C3) R^(D3) R^(D3) L_(C195) R^(D1)R^(D5) L_(C387) R^(D17) R^(D42) L_(C579) R^(D143) R^(D134) L_(C4) R^(D4)R^(D4) L_(C196) R^(D1) R^(D9) L_(C388) R^(D17) R^(D43) L_(C580) R^(D143)R^(D135) L_(C5) R^(D5) R^(D5) L_(C197) R^(D1) R^(D10) L_(C389) R^(D17)R^(D48) L_(C581) R^(D143) R^(D136) L_(C6) R^(D6) R^(D6) L_(C198) R^(D1)R^(D17) L_(C390) R^(D17) R^(D49) L_(C582) R^(D143) R^(D144) L_(C7)R^(D7) R^(D7) L_(C199) R^(D1) R^(D18) L_(C391) R^(D17) R^(D50) L_(C583)R^(D143) R^(D145) L_(C8) R^(D8) R^(D8) L_(C200) R^(D1) R^(D20) L_(C392)R^(D17) R^(D54) L_(C584) R^(D143) R^(D146) L_(C9) R^(D9) R^(D9) L_(C201)R^(D1) R^(D22) L_(C393) R^(D17) R^(D55) L_(C585) R^(D143) R^(D147)L_(C10) R^(D10) R^(D10) L_(C202) R^(D1) R^(D37) L_(C394) R^(D17) R^(D58)L_(C586) R^(D143) R^(D149) L_(C11) R^(D11) R^(D11) L_(C203) R^(D1)R^(D40) L_(C395) R^(D17) R^(D59) L_(C587) R^(D143) R^(D151) L_(C12)R^(D12) R^(D12) L_(C204) R^(D1) R^(D41) L_(C396) R^(D17) R^(D78)L_(C588) R^(D143) R^(D154) L_(C13) R^(D13) R^(D13) L_(C205) R^(D1)R^(D42) L_(C397) R^(D17) R^(D79) L_(C589) R^(D143) R^(D155) L_(C14)R^(D14) R^(D14) L_(C206) R^(D1) R^(D43) L_(C398) R^(D17) R^(D81)L_(C590) R^(D143) R^(D161) L_(C15) R^(D15) R^(D15) L_(C207) R^(D1)R^(D48) L_(C399) R^(D17) R^(D87) L_(C591) R^(D143) R^(D175) L_(C16)R^(D16) R^(D16) L_(C208) R^(D1) R^(D49) L_(C400) R^(D17) R^(D88)L_(C592) R^(D144) R^(D3) L_(C17) R^(D17) R^(D17) L_(C209) R^(D1) R^(D50)L_(C401) R^(D17) R^(D89) L_(C593) R^(D144) R^(D5) L_(C18) R^(D18)R^(D18) L_(C210) R^(D1) R^(D54) L_(C402) R^(D17) R^(D93) L_(C594)R^(D144) R^(D17) L_(C19) R^(D19) R^(D19) L_(C211) R^(D1) R^(D55)L_(C403) R^(D17) R^(D116) L_(C595) R^(D144) R^(D18) L_(C20) R^(D20)R^(D20) L_(C212) R^(D1) R^(D58) L_(C404) R^(D17) R^(D117) L_(C596)R^(D144) R^(D20) L_(C21) R^(D21) R^(D21) L_(C213) R^(D1) R^(D59)L_(C405) R^(D17) R^(D118) L_(C597) R^(D144) R^(D22) L_(C22) R^(D22)R^(D22) L_(C214) R^(D1) R^(D78) L_(C406) R^(D17) R^(D119) L_(C598)R^(D144) R^(D37) L_(C23) R^(D23) R^(D23) L_(C215) R^(D1) R^(D79)L_(C407) R^(D17) R^(D120) L_(C599) R^(D144) R^(D40) L_(C24) R^(D24)R^(D24) L_(C216) R^(D1) R^(D81) L_(C408) R^(D17) R^(D133) L_(C600)R^(D144) R^(D41) L_(C25) R^(D25) R^(D25) L_(C217) R^(D1) R^(D87)L_(C409) R^(D17) R^(D134) L_(C601) R^(D144) R^(D42) L_(C26) R^(D26)R^(D26) L_(C218) R^(D1) R^(D88) L_(C410) R^(D17) R^(D135) L_(C602)R^(D144) R^(D43) L_(C27) R^(D27) R^(D27) L_(C219) R^(D1) R^(D89)L_(C411) R^(D17) R^(D136) L_(C603) R^(D144) R^(D48) L_(C28) R^(D28)R^(D28) L_(C220) R^(D1) R^(D93) L_(C412) R^(D17) R^(D143) L_(C604)R^(D144) R^(D49) L_(C29) R^(D29) R^(D29) L_(C221) R^(D1) R^(D116)L_(C413) R^(D17) R^(D144) L_(C605) R^(D144) R^(D54) L_(C30) R^(D30)R^(D30) L_(C222) R^(D1) R^(D117) L_(C414) R^(D17) R^(D145) L_(C606)R^(D144) R^(D58) L_(C31) R^(D31) R^(D31) L_(C223) R^(D1) R^(D118)L_(C415) R^(D17) R^(D146) L_(C607) R^(D144) R^(D59) L_(C32) R^(D32)R^(D32) L_(C224) R^(D1) R^(D119) L_(C416) R^(D17) R^(D147) L_(C608)R^(D144) R^(D78) L_(C33) R^(D33) R^(D33) L_(C225) R^(D1) R^(D120)L_(C417) R^(D17) R^(D149) L_(C609) R^(D144) R^(D79) L_(C34) R^(D34)R^(D34) L_(C226) R^(D1) R^(D133) L_(C418) R^(D17) R^(D151) L_(C610)R^(D144) R^(D81) L_(C35) R^(D35) R^(D35) L_(C227) R^(D1) R^(D134)L_(C419) R^(D17) R^(D154) L_(C611) R^(D144) R^(D87) L_(C36) R^(D36)R^(D36) L_(C228) R^(D1) R^(D135) L_(C420) R^(D17) R^(D155) L_(C612)R^(D144) R^(D88) L_(C37) R^(D37) R^(D37) L_(C229) R^(D1) R^(D136)L_(C421) R^(D17) R^(D161) L_(C613) R^(D144) R^(D89) L_(C38) R^(D38)R^(D38) L_(C230) R^(D1) R^(D143) L_(C422) R^(D17) R^(D175) L_(C614)R^(D144) R^(D93) L_(C39) R^(D39) R^(D39) L_(C231) R^(D1) R^(D144)L_(C423) R^(D50) R^(D3) L_(C615) R^(D144) R^(D116) L_(C40) R^(D40)R^(D40) L_(C232) R^(D1) R^(D145) L_(C424) R^(D50) R^(D5) L_(C616)R^(D144) R^(D117) L_(C41) R^(D41) R^(D41) L_(C233) R^(D1) R^(D146)L_(C425) R^(D50) R^(D18) L_(C617) R^(D144) R^(D118) L_(C42) R^(D42)R^(D42) L_(C234) R^(D1) R^(D147) L_(C426) R^(D50) R^(D20) L_(C618)R^(D144) R^(D119) L_(C43) R^(D43) R^(D43) L_(C235) R^(D1) R^(D149)L_(C427) R^(D50) R^(D22) L_(C619) R^(D144) R^(D120) L_(C44) R^(D44)R^(D44) L_(C236) R^(D1) R^(D151) L_(C428) R^(D50) R^(D37) L_(C620)R^(D144) R^(D133) L_(C45) R^(D45) R^(D45) L_(C237) R^(D1) R^(D154)L_(C429) R^(D50) R^(D40) L_(C621) R^(D144) R^(D134) L_(C46) R^(D46)R^(D46) L_(C238) R^(D1) R^(D155) L_(C430) R^(D50) R^(D41) L_(C622)R^(D144) R^(D135) L_(C47) R^(D47) R^(D47) L_(C239) R^(D1) R^(D161)L_(C431) R^(D50) R^(D42) L_(C623) R^(D144) R^(D136) L_(C48) R^(D48)R^(D48) L_(C240) R^(D1) R^(D175) L_(C432) R^(D50) R^(D43) L_(C624)R^(D144) R^(D145) L_(C49) R^(D49) R^(D49) L_(C241) R^(D4) R^(D3)L_(C433) R^(D50) R^(D48) L_(C625) R^(D144) R^(D146) L_(C50) R^(D50)R^(D50) L_(C242) R^(D4) R^(D5) L_(C434) R^(D50) R^(D49) L_(C626)R^(D144) R^(D147) L_(C51) R^(D51) R^(D51) L_(C243) R^(D4) R^(D9)L_(C435) R^(D50) R^(D54) L_(C627) R^(D144) R^(D149) L_(C52) R^(D52)R^(D52) L_(C244) R^(D4) R^(D10) L_(C436) R^(D50) R^(D55) L_(C628)R^(D144) R^(D151) L_(C53) R^(D53) R^(D53) L_(C245) R^(D4) R^(D17)L_(C437) R^(D50) R^(D58) L_(C629) R^(D144) R^(D154) L_(C54) R^(D54)R^(D54) L_(C246) R^(D4) R^(D18) L_(C438) R^(D50) R^(D59) L_(C630)R^(D144) R^(D155) L_(C55) R^(D55) R^(D55) L_(C247) R^(D4) R^(D20)L_(C439) R^(D50) R^(D78) L_(C631) R^(D144) R^(D161) L_(C56) R^(D56)R^(D56) L_(C248) R^(D4) R^(D22) L_(C440) R^(D50) R^(D79) L_(C632)R^(D144) R^(D175) L_(C57) R^(D57) R^(D57) L_(C249) R^(D4) R^(D37)L_(C441) R^(D50) R^(D81) L_(C633) R^(D145) R^(D3) L_(C58) R^(D58)R^(D58) L_(C250) R^(D4) R^(D40) L_(C442) R^(D50) R^(D87) L_(C634)R^(D145) R^(D5) L_(C59) R^(D59) R^(D59) L_(C251) R^(D4) R^(D41) L_(C443)R^(D50) R^(D88) L_(C635) R^(D145) R^(D17) L_(C60) R^(D60) R^(D60)L_(C252) R^(D4) R^(D42) L_(C444) R^(D50) R^(D89) L_(C636) R^(D145)R^(D18) L_(C61) R^(D61) R^(D61) L_(C253) R^(D4) R^(D43) L_(C445) R^(D50)R^(D93) L_(C637) R^(D145) R^(D20) L_(C62) R^(D62) R^(D62) L_(C254)R^(D4) R^(D48) L_(C446) R^(D50) R^(D116) L_(C638) R^(D145) R^(D22)L_(C63) R^(D63) R^(D63) L_(C255) R^(D4) R^(D49) L_(C447) R^(D50)R^(D117) L_(C639) R^(D145) R^(D37) L_(C64) R^(D64) R^(D64) L_(C256)R^(D4) R^(D50) L_(C448) R^(D50) R^(D118) L_(C640) R^(D145) R^(D40)L_(C65) R^(D65) R^(D65) L_(C257) R^(D4) R^(D54) L_(C449) R^(D50)R^(D119) L_(C641) R^(D145) R^(D41) L_(C66) R^(D66) R^(D66) L_(C258)R^(D4) R^(D55) L_(C450) R^(D50) R^(D120) L_(C642) R^(D145) R^(D42)L_(C67) R^(D67) R^(D67) L_(C259) R^(D4) R^(D58) L_(C451) R^(D50)R^(D133) L_(C643) R^(D145) R^(D43) L_(C68) R^(D68) R^(D68) L_(C260)R^(D4) R^(D59) L_(C452) R^(D50) R^(D134) L_(C644) R^(D145) R^(D48)L_(C69) R^(D69) R^(D69) L_(C261) R^(D4) R^(D78) L_(C453) R^(D50)R^(D135) L_(C645) R^(D145) R^(D49) L_(C70) R^(D70) R^(D70) L_(C262)R^(D4) R^(D79) L_(C454) R^(D50) R^(D136) L_(C646) R^(D145) R^(D54)L_(C71) R^(D71) R^(D71) L_(C263) R^(D4) R^(D81) L_(C455) R^(D50)R^(D143) L_(C647) R^(D145) R^(D58) L_(C72) R^(D72) R^(D72) L_(C264)R^(D4) R^(D87) L_(C456) R^(D50) R^(D144) L_(C648) R^(D145) R^(D59)L_(C73) R^(D73) R^(D73) L_(C265) R^(D4) R^(D88) L_(C457) R^(D50)R^(D145) L_(C649) R^(D145) R^(D78) L_(C74) R^(D74) R^(D74) L_(C266)R^(D4) R^(D89) L_(C458) R^(D50) R^(D146) L_(C650) R^(D145) R^(D79)L_(C75) R^(D75) R^(D75) L_(C267) R^(D4) R^(D93) L_(C459) R^(D50)R^(D147) L_(C651) R^(D145) R^(D81) L_(C76) R^(D76) R^(D76) L_(C268)R^(D4) R^(D116) L_(C460) R^(D50) R^(D149) L_(C652) R^(D145) R^(D87)L_(C77) R^(D77) R^(D77) L_(C269) R^(D4) R^(D117) L_(C461) R^(D50)R^(D151) L_(C653) R^(D145) R^(D88) L_(C78) R^(D78) R^(D78) L_(C270)R^(D4) R^(D118) L_(C462) R^(D50) R^(D154) L_(C654) R^(D145) R^(D89)L_(C79) R^(D79) R^(D79) L_(C271) R^(D4) R^(D119) L_(C463) R^(D50)R^(D155) L_(C655) R^(D145) R^(D93) L_(C80) R^(D80) R^(D80) L_(C272)R^(D4) R^(D120) L_(C464) R^(D50) R^(D161) L_(C656) R^(D145) R^(D116)L_(C81) R^(D81) R^(D81) L_(C273) R^(D4) R^(D133) L_(C465) R^(D50)R^(D175) L_(C657) R^(D145) R^(D117) L_(C82) R^(D82) R^(D82) L_(C274)R^(D4) R^(D134) L_(C466) R^(D55) R^(D3) L_(C658) R^(D145) R^(D118)L_(C83) R^(D83) R^(D83) L_(C275) R^(D4) R^(D135) L_(C467) R^(D55) R^(D5)L_(C659) R^(D145) R^(D119) L_(C84) R^(D84) R^(D84) L_(C276) R^(D4)R^(D136) L_(C468) R^(D55) R^(D18) L_(C660) R^(D145) R^(D120) L_(C85)R^(D85) R^(D85) L_(C277) R^(D4) R^(D143) L_(C469) R^(D55) R^(D20)L_(C661) R^(D145) R^(D133) L_(C86) R^(D86) R^(D86) L_(C278) R^(D4)R^(D144) L_(C470) R^(D55) R^(D22) L_(C662) R^(D145) R^(D134) L_(C87)R^(D87) R^(D87) L_(C279) R^(D4) R^(D145) L_(C471) R^(D55) R^(D37)L_(C663) R^(D145) R^(C135) L_(C88) R^(D88) R^(D88) L_(C280) R^(D4)R^(D146) L_(C472) R^(D55) R^(D40) L_(C664) R^(D145) R^(D136) L_(C89)R^(D89) R^(D89) L_(C281) R^(D4) R^(D147) L_(C473) R^(D55) R^(D41)L_(C665) R^(D145) R^(D146) L_(C90) R^(D90) R^(D90) L_(C282) R^(D4)R^(D149) L_(C474) R^(D55) R^(D42) L_(C666) R^(D145) R^(D147) L_(C91)R^(D91) R^(D91) L_(C283) R^(D4) R^(D151) L_(C475) R^(D55) R^(D43)L_(C667) R^(D145) R^(D149) L_(C92) R^(D92) R^(D92) L_(C284) R^(D4)R^(D154) L_(C476) R^(D55) R^(D48) L_(C668) R^(D145) R^(D151) L_(C93)R^(D93) R^(D93) L_(C285) R^(D4) R^(D155) L_(C477) R^(D55) R^(D49)L_(C669) R^(D145) R^(D154) L_(C94) R^(D94) R^(D94) L_(C286) R^(D4)R^(D161) L_(C478) R^(D55) R^(D54) L_(C670) R^(D145) R^(D155) L_(C95)R^(D95) R^(D95) L_(C287) R^(D4) R^(D175) L_(C479) R^(D55) R^(D58)L_(C671) R^(D145) R^(D161) L_(C96) R^(D96) R^(D96) L_(C288) R^(D9)R^(D3) L_(C480) R^(D55) R^(D59) L_(C672) R^(D145) R^(D175) L_(C97)R^(D97) R^(D97) L_(C289) R^(D9) R^(D5) L_(C481) R^(D55) R^(D78) L_(C673)R^(D146) R^(D3) L_(C98) R^(D98) R^(D98) L_(C290) R^(D9) R^(D10) L_(C482)R^(D55) R^(D79) L_(C674) R^(D146) R^(D5) L_(C99) R^(D99) R^(D99)L_(C291) R^(D9) R^(D17) L_(C483) R^(D55) R^(D81) L_(C675) R^(D146)R^(D17) L_(C100) R^(D100) R^(D100) L_(C292) R^(D9) R^(D18) L_(C484)R^(D55) R^(D87) L_(C676) R^(D146) R^(D18) L_(C101) R^(D101) R^(D101)L_(C293) R^(D9) R^(D20) L_(C485) R^(D55) R^(D88) L_(C677) R^(D146)R^(D20) L_(C102) R^(D102) R^(D102) L_(C294) R^(D9) R^(D22) L_(C486)R^(D55) R^(D89) L_(C678) R^(D146) R^(D22) L_(C103) R^(D103) R^(D103)L_(C295) R^(D9) R^(D37) L_(C487) R^(D55) R^(D93) L_(C679) R^(D146)R^(D37) L_(C104) R^(D104) R^(D104) L_(C296) R^(D9) R^(D40) L_(C488)R^(D55) R^(D116) L_(C680) R^(D146) R^(D40) L_(C105) R^(D105) R^(D105)L_(C297) R^(D9) R^(D41) L_(C489) R^(D55) R^(D117) L_(C681) R^(D146)R^(D41) L_(C106) R^(D106) R^(D106) L_(C298) R^(D9) R^(D42) L_(C490)R^(D55) R^(D118) L_(C682) R^(D146) R^(D42) L_(C107) R^(D107) R^(D107)L_(C299) R^(D9) R^(D43) L_(C491) R^(D55) R^(D119) L_(C683) R^(D146)R^(D43) L_(C108) R^(D108) R^(D108) L_(C300) R^(D9) R^(D48) L_(C492)R^(D55) R^(D120) L_(C684) R^(D146) R^(D48) L_(C109) R^(D109) R^(D109)L_(C301) R^(D9) R^(D49) L_(C493) R^(D55) R^(D133) L_(C685) R^(D146)R^(D49) L_(C110) R^(D110) R^(D110) L_(C302) R^(D9) R^(D50) L_(C494)R^(D55) R^(D134) L_(C686) R^(D146) R^(D54) L_(C111) R^(D111) R^(D111)L_(C303) R^(D9) R^(D54) L_(C495) R^(D55) R^(D135) L_(C687) R^(D146)R^(D58) L_(C112) R^(D112) R^(D112) L_(C304) R^(D9) R^(D55) L_(C496)R^(D55) R^(D136) L_(C688) R^(D146) R^(D59) L_(C113) R^(D113) R^(D113)L_(C305) R^(D9) R^(D58) L_(C497) R^(D55) R^(D143) L_(C689) R^(D146)R^(D78) L_(C114) R^(D114) R^(D114) L_(C306) R^(D9) R^(D59) L_(C498)R^(D55) R^(D144) L_(C690) R^(D146) R^(D79) L_(C115) R^(D115) R^(D115)L_(C307) R^(D9) R^(D78) L_(C499) R^(D55) R^(D145) L_(C691) R^(D146)R^(D81) L_(C116) R^(D116) R^(D116) L_(C308) R^(D9) R^(D79) L_(C500)R^(D55) R^(D146) L_(C692) R^(D146) R^(D87) L_(C117) R^(D117) R^(D117)L_(C309) R^(D9) R^(D81) L_(C501) R^(D55) R^(D147) L_(C693) R^(D146)R^(D88) L_(C118) R^(D118) R^(D118) L_(C310) R^(D9) R^(D87) L_(C502)R^(D55) R^(D149) L_(C694) R^(D146) R^(D89) L_(C119) R^(D119) R^(D119)L_(C311) R^(D9) R^(D88) L_(C503) R^(D55) R^(D151) L_(C695) R^(D146)R^(D93) L_(C120) R^(D120) R^(D120) L_(C312) R^(D9) R^(D89) L_(C504)R^(D55) R^(D154) L_(C696) R^(D146) R^(D117) L_(C121) R^(D121) R^(D121)L_(C313) R^(D9) R^(D93) L_(C505) R^(D55) R^(D155) L_(C697) R^(D146)R^(D118) L_(C122) R^(D122) R^(D122) L_(C314) R^(D9) R^(D116) L_(C506)R^(D55) R^(D161) L_(C698) R^(D146) R^(D119) L_(C123) R^(D123) R^(D123)L_(C315) R^(D9) R^(D117) L_(C507) R^(D55) R^(D175) L_(C699) R^(D146)R^(D120) L_(C124) R^(D124) R^(D124) L_(C316) R^(D9) R^(D118) L_(C508)R^(D116) R^(D3) L_(C700) R^(D146) R^(D133) L_(C125) R^(D125) R^(D125)L_(C317) R^(D9) R^(D119) L_(C509) R^(D116) R^(D5) L_(C701) R^(D146)R^(D134) L_(C126) R^(D126) R^(D126) L_(C318) R^(D9) R^(D120) L_(C510)R^(D116) R^(D17) L_(C702) R^(D146) R^(D135) L_(C127) R^(D127) R^(D127)L_(C319) R^(D9) R^(D133) L_(C511) R^(D116) R^(D18) L_(C703) R^(D146)R^(D136) L_(C128) R^(D128) R^(D128) L_(C320) R^(D9) R^(D134) L_(C512)R^(D116) R^(D20) L_(C704) R^(D146) R^(D146) L_(C129) R^(D129) R^(D129)L_(C321) R^(D9) R^(D135) L_(C513) R^(D116) R^(D22) L_(C705) R^(D146)R^(D147) L_(C130) R^(D130) R^(D130) L_(C322) R^(D9) R^(D136) L_(C514)R^(D116) R^(D37) L_(C706) R^(D146) R^(D149) L_(C131) R^(D131) R^(D131)L_(C323) R^(D9) R^(D143) L_(C515) R^(D116) R^(D40) L_(C707) R^(D146)R^(D151) L_(C132) R^(D132) R^(D132) L_(C324) R^(D9) R^(D144) L_(C516)R^(D116) R^(D41) L_(C708) R^(D146) R^(D154) L_(C133) R^(D133) R^(D133)L_(C325) R^(D9) R^(D145) L_(C517) R^(D116) R^(D42) L_(C709) R^(D146)R^(D155) L_(C134) R^(D134) R^(D134) L_(C326) R^(D9) R^(D146) L_(C518)R^(D116) R^(D43) L_(C710) R^(D146) R^(D161) L_(C135) R^(D135) R^(D135)L_(C327) R^(D9) R^(D147) L_(C519) R^(D116) R^(D48) L_(C711) R^(D146)R^(D175) L_(C136) R^(D136) R^(D136) L_(C328) R^(D9) R^(D149) L_(C520)R^(D116) R^(D49) L_(C712) R^(D133) R^(D3) L_(C137) R^(D137) R^(D137)L_(C329) R^(D9) R^(D151) L_(C521) R^(D116) R^(D54) L_(C713) R^(D133)R^(D5) L_(C138) R^(D138) R^(D138) L_(C330) R^(D9) R^(D154) L_(C522)R^(D116) R^(D58) L_(C714) R^(D133) R^(D3) L_(C139) R^(D139) R^(D139)L_(C331) R^(D9) R^(D155) L_(C523) R^(D116) R^(D59) L_(C715) R^(D133)R^(D18) L_(C140) R^(D140) R^(D140) L_(C332) R^(D9) R^(D161) L_(C524)R^(D116) R^(D78) L_(C716) R^(D133) R^(D20) L_(C141) R^(D141) R^(D141)L_(C333) R^(D9) R^(D175) L_(C525) R^(D116) R^(D79) L_(C717) R^(D133)R^(D22) L_(C142) R^(D142) R^(D142) L_(C334) R^(D10) R^(D3) L_(C526)R^(D116) R^(D81) L_(C718) R^(D133) R^(D37) L_(C143) R^(D143) R^(D143)L_(C335) R^(D10) R^(D5) L_(C527) R^(D116) R^(D87) L_(C719) R^(D133)R^(D40) L_(C144) R^(D144) R^(D144) L_(C336) R^(D10) R^(D17) L_(C528)R^(D116) R^(D88) L_(C720) R^(D133) R^(D41) L_(C145) R^(D145) R^(D145)L_(C337) R^(D10) R^(D18) L_(C529) R^(D116) R^(D89) L_(C721) R^(D133)R^(D42) L_(C146) R^(D146) R^(D146) L_(C338) R^(D10) R^(D20) L_(C530)R^(D116) R^(D93) L_(C722) R^(D133) R^(D43) L_(C147) R^(D147) R^(D147)L_(C339) R^(D10) R^(D22) L_(C531) R^(D116) R^(D117) L_(C723) R^(D133)R^(D48) L_(C148) R^(D148) R^(D148) L_(C340) R^(D10) R^(D37) L_(C532)R^(D116) R^(D118) L_(C724) R^(D133) R^(D49) L_(C149) R^(D149) R^(D149)L_(C341) R^(D10) R^(D40) L_(C533) R^(D116) R^(D119) L_(C725) R^(D133)R^(D54) L_(C150) R^(D150) R^(D150) L_(C342) R^(D10) R^(D41) L_(C534)R^(D116) R^(D120) L_(C726) R^(D133) R^(D58) L_(C151) R^(D151) R^(D151)L_(C343) R^(D10) R^(D42) L_(C535) R^(D116) R^(D133) L_(C727) R^(D133)R^(D59) L_(C152) R^(D152) R^(D152) L_(C344) R^(D10) R^(D43) L_(C536)R^(D116) R^(D134) L_(C728) R^(D133) R^(D78) L_(C153) R^(D153) R^(D153)L_(C345) R^(D10) R^(D48) L_(C537) R^(D116) R^(D135) L_(C729) R^(D133)R^(D79) L_(C154) R^(D154) R^(D154) L_(C346) R^(D10) R^(D49) L_(C538)R^(D116) R^(D136) L_(C730) R^(D133) R^(D81) L_(C155) R^(D155) R^(D155)L_(C347) R^(D10) R^(D50) L_(C539) R^(D116) R^(D143) L_(C731) R^(D133)R^(D87) L_(C156) R^(D156) R^(D156) L_(C348) R^(D10) R^(D54) L_(C540)R^(D116) R^(D144) L_(C732) R^(D133) R^(D88) L_(C157) R^(D157) R^(D157)L_(C349) R^(D10) R^(D55) L_(C541) R^(D116) R^(D145) L_(C733) R^(D133)R^(D89) L_(C158) R^(D158) R^(D158) L_(C350) R^(D10) R^(D58) L_(C542)R^(D116) R^(D146) L_(C734) R^(D133) R^(D93) L_(C159) R^(D159) R^(D159)L_(C351) R^(D10) R^(D59) L_(C543) R^(D116) R^(D147) L_(C735) R^(D133)R^(D117) L_(C160) R^(D160) R^(D160) L_(C352) R^(D10) R^(D78) L_(C544)R^(D116) R^(D149) L_(C736) R^(D133) R^(D118) L_(C161) R^(D161) R^(D161)L_(C353) R^(D10) R^(D79) L_(C545) R^(D116) R^(D151) L_(C737) R^(D133)R^(D119) L_(C162) R^(D162) R^(D162) L_(C354) R^(D10) R^(D81) L_(C546)R^(D116) R^(D154) L_(C738) R^(D133) R^(D120) L_(C163) R^(D163) R^(D163)L_(C355) R^(D10) R^(D87) L_(C547) R^(D116) R^(D155) L_(C739) R^(D133)R^(D133) L_(C164) R^(D164) R^(D164) L_(C356) R^(D10) R^(D88) L_(C548)R^(D116) R^(D161) L_(C740) R^(D133) R^(D134) L_(C165) R^(D165) R^(D165)L_(C357) R^(D10) R^(D89) L_(C549) R^(D116) R^(D175) L_(C741) R^(D133)R^(D135) L_(C166) R^(D166) R^(D166) L_(C358) R^(D10) R^(D93) L_(C550)R^(D143) R^(D3) L_(C742) R^(D133) R^(D136) L_(C167) R^(D167) R^(D167)L_(C359) R^(D10) R^(D116) L_(C551) R^(D143) R^(D5) L_(C743) R^(D133)R^(D146) L_(C168) R^(D168) R^(D168) L_(C360) R^(D10) R^(D117) L_(C552)R^(D143) R^(D17) L_(C744) R^(D133) R^(D147) L_(C169) R^(D169) R^(D169)L_(C361) R^(D10) R^(D118) L_(C553) R^(D143) R^(D18) L_(C745) R^(D133)R^(D149) L_(C170) R^(D170) R^(D170) L_(C362) R^(D10) R^(D119) L_(C554)R^(D143) R^(D20) L_(C746) R^(D133) R^(D151) L_(C171) R^(D171) R^(D171)L_(C363) R^(D10) R^(D120) L_(C555) R^(D143) R^(D22) L_(C747) R^(D133)R^(D154) L_(C172) R^(D172) R^(D172) L_(C364) R^(D10) R^(D133) L_(C556)R^(D143) R^(D37) L_(C748) R^(D133) R^(D155) L_(C173) R^(D173) R^(D173)L_(C365) R^(D10) R^(D134) L_(C557) R^(D143) R^(D40) L_(C749) R^(D133)R^(D161) L_(C174) R^(D174) R^(D174) L_(C366) R^(D10) R^(D135) L_(C558)R^(D143) R^(D41) L_(C750) R^(D133) R^(D175) L_(C175) R^(D175) R^(D175)L_(C367) R^(D10) R^(D136) L_(C559) R^(D143) R^(D42) L_(C751) R^(D175)R^(D3) L_(C176) R^(D176) R^(D176) L_(C368) R^(D10) R^(D143) L_(C560)R^(D143) R^(D43) L_(C752) R^(D175) R^(D5) L_(C177) R^(D177) R^(D177)L_(C369) R^(D10) R^(D144) L_(C561) R^(D143) R^(D48) L_(C753) R^(D175)R^(D18) L_(C178) R^(D178) R^(D178) L_(C370) R^(D10) R^(D145) L_(C562)R^(D143) R^(D49) L_(C754) R^(D175) R^(D20) L_(C179) R^(D179) R^(D179)L_(C371) R^(D10) R^(D146) L_(C563) R^(D143) R^(D54) L_(C755) R^(D175)R^(D22) L_(C180) R^(D180) R^(D180) L_(C372) R^(D10) R^(D147) L_(C564)R^(D143) R^(D58) L_(C756) R^(D175) R^(D37) L_(C181) R^(D181) R^(D181)L_(C373) R^(D10) R^(D149) L_(C565) R^(D143) R^(D59) L_(C757) R^(D175)R^(D40) L_(C182) R^(D182) R^(D182) L_(C374) R^(D10) R^(D151) L_(C566)R^(D143) R^(D78) L_(C758) R^(D175) R^(D41) L_(C183) R^(D183) R^(D183)L_(C375) R^(D10) R^(D154) L_(C567) R^(D143) R^(D79) L_(C759) R^(D175)R^(D42) L_(C184) R^(D184) R^(D184) L_(C376) R^(D10) R^(D155) L_(C568)R^(D143) R^(D81) L_(C760) R^(D175) R^(D43) L_(C185) R^(D185) R^(D185)L_(C377) R^(D10) R^(D161) L_(C569) R^(D143) R^(D87) L_(C761) R^(D175)R^(D48) L_(C186) R^(D186) R^(D186) L_(C378) R^(D10) R^(D175) L_(C570)R^(D143) R^(D88) L_(C762) R^(D175) R^(D49) L_(C187) R^(D187) R^(D187)L_(C379) R^(D17) R^(D3) L_(C571) R^(D143) R^(D89) L_(C763) R^(D175)R^(D54) L_(C188) R^(D188) R^(D188) L_(C380) R^(D17) R^(D5) L_(C572)R^(D143) R^(D93) L_(C764) R^(D175) R^(D58) L_(C189) R^(D189) R^(D189)L_(C381) R^(D17) R^(D18) L_(C573) R^(D143) R^(D116) L_(C765) R^(D175)R^(D59) L_(C190) R^(D190) R^(D190) L_(C382) R^(D17) R^(D20) L_(C574)R^(D143) R^(D117) L_(C766) R^(D175) R^(D78) L_(C191) R^(D191) R^(D191)L_(C383) R^(D17) R^(D22) L_(C575) R^(D143) R^(D118) L_(C767) R^(D175)R^(D79) L_(C192) R^(D192) R^(D192) L_(C384) R^(D17) R^(D37) L_(C576)R^(D143) R^(D119) L_(C768) R^(D175) R^(D81) L_(C769) R^(D193) R^(D193)L_(C877) R^(D1) R^(D193) L_(C985) R^(D4) R^(D193) L_(C1093) R^(D9)R^(D193) L_(C770) R^(D194) R^(D194) L_(C878) R^(D1) R^(D194) L_(C986)R^(D4) R^(D194) L_(C1094) R^(D9) R^(D194) L_(C771) R^(D195) R^(D195)L_(C879) R^(D1) R^(D195) L_(C987) R^(D4) R^(D195) L_(C1095) R^(D9)R^(D195) L_(C772) R^(D196) R^(D196) L_(C880) R^(D1) R^(D196) L_(C988)R^(D4) R^(D196) L_(C1096) R^(D9) R^(D196) L_(C773) R^(D197) R^(D197)L_(C881) R^(D1) R^(D197) L_(C989) R^(D4) R^(D197) L_(C1097) R^(D9)R^(D197) L_(C774) R^(D198) R^(D198) L_(C882) R^(D1) R^(D198) L_(C990)R^(D4) R^(D198) L_(C1098) R^(D9) R^(D198) L_(C775) R^(D199) R^(D199)L_(C883) R^(D1) R^(D199) L_(C991) R^(D4) R^(D199) L_(C1099) R^(D9)R^(D199) L_(C776) R^(D200) R^(D200) L_(C884) R^(D1) R^(D200) L_(C992)R^(D4) R^(D200) L_(C1100) R^(D9) R^(D200) L_(C777) R^(D201) R^(D201)L_(C885) R^(D1) R^(D201) L_(C993) R^(D4) R^(D201) L_(C1101) R^(D9)R^(D201) L_(C778) R^(D202) R^(D202) L_(C886) R^(D1) R^(D202) L_(C994)R^(D4) R^(D202) L_(C1102) R^(D9) R^(D202) L_(C779) R^(D203) R^(D203)L_(C887) R^(D1) R^(D203) L_(C995) R^(D4) R^(D203) L_(C1103) R^(D9)R^(D203) L_(C780) R^(D204) R^(D204) L_(C888) R^(D1) R^(D204) L_(C996)R^(D4) R^(D204) L_(C1104) R^(D9) R^(D204) L_(C781) R^(D205) R^(D205)L_(C889) R^(D1) R^(D205) L_(C997) R^(D4) R^(D205) L_(C1105) R^(D9)R^(D205) L_(C782) R^(D206) R^(D206) L_(C890) R^(D1) R^(D206) L_(C998)R^(D4) R^(D206) L_(C1106) R^(D9) R^(D206) L_(C783) R^(D207) R^(D207)L_(C891) R^(D1) R^(D207) L_(C999) R^(D4) R^(D207) L_(C1107) R^(D9)R^(D207) L_(C784) R^(D208) R^(D208) L_(C892) R^(D1) R^(D208) L_(C1000)R^(D4) R^(D208) L_(C1108) R^(D9) R^(D208) L_(C785) R^(D209) R^(D209)L_(C893) R^(D1) R^(D209) L_(C1001) R^(D4) R^(D209) L_(C1109) R^(D9)R^(D209) L_(C786) R^(D210) R^(D210) L_(C894) R^(D1) R^(D210) L_(C1002)R^(D4) R^(D210) L_(C1110) R^(D9) R^(D210) L_(C787) R^(D211) R^(D211)L_(C895) R^(D1) R^(D211) L_(C1003) R^(D4) R^(D211) L_(C1111) R^(D9)R^(D211) L_(C788) R^(D212) R^(D212) L_(C896) R^(D1) R^(D212) L_(C1004)R^(D4) R^(D212) L_(C1112) R^(D9) R^(D212) L_(C789) R^(D213) R^(D213)L_(C897) R^(D1) R^(D213) L_(C1005) R^(D4) R^(D213) L_(C1113) R^(D9)R^(D213) L_(C790) R^(D214) R^(D214) L_(C898) R^(D1) R^(D214) L_(C1006)R^(D4) R^(D214) L_(C1114) R^(D9) R^(D214) L_(C791) R^(D215) R^(D215)L_(C899) R^(D1) R^(D215) L_(C1007) R^(D4) R^(D215) L_(C1115) R^(D9)R^(D215) L_(C792) R^(D216) R^(D216) L_(C900) R^(D1) R^(D216) L_(C1008)R^(D4) R^(D216) L_(C1116) R^(D9) R^(D216) L_(C793) R^(D217) R^(D217)L_(C901) R^(D1) R^(D217) L_(C1009) R^(D4) R^(D217) L_(C1117) R^(D9)R^(D217) L_(C794) R^(D218) R^(D218) L_(C902) R^(D1) R^(D218) L_(C1010)R^(D4) R^(D218) L_(C1118) R^(D9) R^(D218) L_(C795) R^(D219) R^(D219)L_(C903) R^(D1) R^(D219) L_(C1011) R^(D4) R^(D219) L_(C1119) R^(D9)R^(D219) L_(C796) R^(D220) R^(D220) L_(C904) R^(D1) R^(D220) L_(C1012)R^(D4) R^(D220) L_(C1120) R^(D9) R^(D220) L_(C797) R^(D221) R^(D221)L_(C905) R^(D1) R^(D221) L_(C1013) R^(D4) R^(D221) L_(C1121) R^(D9)R^(D221) L_(C798) R^(D222) R^(D222) L_(C906) R^(D1) R^(D222) L_(C1014)R^(D4) R^(D222) L_(C1122) R^(D9) R^(D222) L_(C799) R^(D223) R^(D223)L_(C907) R^(D1) R^(D223) L_(C1015) R^(D4) R^(D223) L_(C1123) R^(D9)R^(D223) L_(C800) R^(D224) R^(D224) L_(C908) R^(D1) R^(D224) L_(C1016)R^(D4) R^(D224) L_(C1124) R^(D9) R^(D224) L_(C801) R^(D225) R^(D225)L_(C909) R^(D1) R^(D225) L_(C1017) R^(D4) R^(D225) L_(C1125) R^(D9)R^(D225) L_(C802) R^(D226) R^(D226) L_(C910) R^(D1) R^(D226) L_(C1018)R^(D4) R^(D226) L_(C1126) R^(D9) R^(D226) L_(C803) R^(D227) R^(D227)L_(C911) R^(D1) R^(D227) L_(C1019) R^(D4) R^(D227) L_(C1127) R^(D9)R^(D227) L_(C804) R^(D228) R^(D228) L_(C912) R^(D1) R^(D228) L_(C1020)R^(D4) R^(D228) L_(C1128) R^(D9) R^(D228) L_(C805) R^(D229) R^(D229)L_(C913) R^(D1) R^(D229) L_(C1021) R^(D4) R^(D229) L_(C1129) R^(D9)R^(D229) L_(C806) R^(D230) R^(D230) L_(C914) R^(D1) R^(D230) L_(C1022)R^(D4) R^(D230) L_(C1130) R^(D9) R^(D230) L_(C807) R^(D231) R^(D231)L_(C915) R^(D1) R^(D231) L_(C1023) R^(D4) R^(D231) L_(C1131) R^(D9)R^(D231) L_(C808) R^(D232) R^(D232) L_(C916) R^(D1) R^(D232) L_(C1024)R^(D4) R^(D232) L_(C1132) R^(D9) R^(D232) L_(C809) R^(D233) R^(D233)L_(C917) R^(D1) R^(D233) L_(C1025) R^(D4) R^(D233) L_(C1133) R^(D9)R^(D233) L_(C810) R^(D234) R^(D234) L_(C918) R^(D1) R^(D234) L_(C1026)R^(D4) R^(D234) L_(C1134) R^(D9) R^(D234) L_(C811) R^(D235) R^(D235)L_(C919) R^(D1) R^(D235) L_(C1027) R^(D4) R^(D235) L_(C1135) R^(D9)R^(D235) L_(C812) R^(D236) R^(D236) L_(C920) R^(D1) R^(D236) L_(C1028)R^(D4) R^(D236) L_(C1136) R^(D9) R^(D236) L_(C813) R^(D237) R^(D237)L_(C921) R^(D1) R^(D237) L_(C1029) R^(D4) R^(D237) L_(C1137) R^(D9)R^(D237) L_(C814) R^(D238) R^(D238) L_(C922) R^(D1) R^(D238) L_(C1030)R^(D4) R^(D238) L_(C1138) R^(D9) R^(D238) L_(C815) R^(D239) R^(D239)L_(C923) R^(D1) R^(D239) L_(C1031) R^(D4) R^(D239) L_(C1139) R^(D9)R^(D239) L_(C816) R^(D240) R^(D240) L_(C924) R^(D1) R^(D240) L_(C1032)R^(D4) R^(D240) L_(C1140) R^(D9) R^(D240) L_(C817) R^(D241) R^(D241)L_(C925) R^(D1) R^(D241) L_(C1033) R^(D4) R^(D241) L_(C1141) R^(D9)R^(D241) L_(C818) R^(D242) R^(D242) L_(C926) R^(D1) R^(D242) L_(C1034)R^(D4) R^(D242) L_(C1142) R^(D9) R^(D242) L_(C819) R^(D243) R^(D243)L_(C927) R^(D1) R^(D243) L_(C1035) R^(D4) R^(D243) L_(C1143) R^(D9)R^(D243) L_(C820) R^(D244) R^(D244) L_(C928) R^(D1) R^(D244) L_(C1036)R^(D4) R^(D244) L_(C1144) R^(D9) R^(D244) L_(C821) R^(D245) R^(D245)L_(C929) R^(D1) R^(D245) L_(C1037) R^(D4) R^(D245) L_(C1145) R^(D9)R^(D245) L_(C822) R^(D246) R^(D246) L_(C930) R^(D1) R^(D246) L_(C1038)R^(D4) R^(D246) L_(C1146) R^(D9) R^(D246) L_(C823) R^(D17) R^(D193)L_(C931) R^(D50) R^(D193) L_(C1039) R^(D145) R^(D193) L_(C1147) R^(D168)R^(D193) L_(C824) R^(D17) R^(D194) L_(C932) R^(D50) R^(D194) L_(C1040)R^(D145) R^(D194) L_(C1148) R^(D168) R^(D194) L_(C825) R^(D17) R^(D195)L_(C933) R^(D50) R^(D195) L_(C1041) R^(D145) R^(D195) L_(C1149) R^(D168)R^(D195) L_(C826) R^(D17) R^(D196) L_(C934) R^(D50) R^(D196) L_(C1042)R^(D145) R^(D196) L_(C1150) R^(D168) R^(D196) L_(C827) R^(D17) R^(D197)L_(C935) R^(D50) R^(D197) L_(C1043) R^(D145) R^(D197) L_(C1151) R^(D168)R^(D197) L_(C828) R^(D17) R^(D198) L_(C936) R^(D50) R^(D198) L_(C1044)R^(D145) R^(D198) L_(C1152) R^(D168) R^(D198) L_(C829) R^(D17) R^(D199)L_(C937) R^(D50) R^(D199) L_(C1045) R^(D145) R^(D199) L_(C1153) R^(D168)R^(D199) L_(C830) R^(D17) R^(D200) L_(C938) R^(D50) R^(D200) L_(C1046)R^(D145) R^(D200) L_(C1154) R^(D168) R^(D200) L_(C831) R^(D17) R^(D201)L_(C939) R^(D50) R^(D201) L_(C1047) R^(D145) R^(D201) L_(C1155) R^(D168)R^(D201) L_(C832) R^(D17) R^(D202) L_(C940) R^(D50) R^(D202) L_(C1048)R^(D145) R^(D202) L_(C1156) R^(D168) R^(D202) L_(C833) R^(D17) R^(D203)L_(C941) R^(D50) R^(D203) L_(C1049) R^(D145) R^(D203) L_(C1157) R^(D168)R^(D203) L_(C834) R^(D17) R^(D204) L_(C942) R^(D50) R^(D204) L_(C1050)R^(D145) R^(D204) L_(C1158) R^(D168) R^(D204) L_(C835) R^(D17) R^(D205)L_(C943) R^(D50) R^(D205) L_(C1051) R^(D145) R^(D205) L_(C1159) R^(D168)R^(D205) L_(C836) R^(D17) R^(D206) L_(C944) R^(D50) R^(D206) L_(C1052)R^(D145) R^(D206) L_(C1160) R^(D168) R^(D206) L_(C837) R^(D17) R^(D207)L_(C945) R^(D50) R^(D207) L_(C1053) R^(D145) R^(D207) L_(C1161) R^(D168)R^(D207) L_(C838) R^(D17) R^(D208) L_(C946) R^(D50) R^(D208) L_(C1054)R^(D145) R^(D208) L_(C1162) R^(D168) R^(D208) L_(C839) R^(D17) R^(D209)L_(C947) R^(D50) R^(D209) L_(C1055) R^(D145) R^(D209) L_(C1163) R^(D168)R^(D209) L_(C840) R^(D17) R^(D210) L_(C948) R^(D50) R^(D210) L_(C1056)R^(D145) R^(D210) L_(C1164) R^(D168) R^(D210) L_(C841) R^(D17) R^(D211)L_(C949) R^(D50) R^(D211) L_(C1057) R^(D145) R^(D211) L_(C1165) R^(D168)R^(D211) L_(C842) R^(D17) R^(D212) L_(C950) R^(D50) R^(D212) L_(C1058)R^(D145) R^(D212) L_(C1166) R^(D168) R^(D212) L_(C843) R^(D17) R^(D213)L_(C951) R^(D50) R^(D213) L_(C1059) R^(D145) R^(D213) L_(C1167) R^(D168)R^(D213) L_(C844) R^(D17) R^(D214) L_(C952) R^(D50) R^(D214) L_(C1060)R^(D145) R^(D214) L_(C1168) R^(D168) R^(D214) L_(C845) R^(D17) R^(D215)L_(C953) R^(D50) R^(D215) L_(C1061) R^(D145) R^(D215) L_(C1169) R^(D168)R^(D215) L_(C846) R^(D17) R^(D216) L_(C954) R^(D50) R^(D216) L_(C1062)R^(D145) R^(D216) L_(C1170) R^(D168) R^(D216) L_(C847) R^(D17) R^(D217)L_(C955) R^(D50) R^(D217) L_(C1063) R^(D145) R^(D217) L_(C1171) R^(D168)R^(D217) L_(C848) R^(D17) R^(D218) L_(C956) R^(D50) R^(D218) L_(C1064)R^(D145) R^(D218) L_(C1172) R^(D168) R^(D218) L_(C849) R^(D17) R^(D219)L_(C957) R^(D50) R^(D219) L_(C1065) R^(D145) R^(D219) L_(C1173) R^(D168)R^(D219) L_(C850) R^(D17) R^(D220) L_(C958) R^(D50) R^(D220) L_(C1066)R^(D145) R^(D220) L_(C1174) R^(D168) R^(D220) L_(C851) R^(D17) R^(D221)L_(C959) R^(D50) R^(D221) L_(C1067) R^(D145) R^(D221) L_(C1175) R^(D168)R^(D221) L_(C852) R^(D17) R^(D222) L_(C960) R^(D50) R^(D222) L_(C1068)R^(D145) R^(D222) L_(C1176) R^(D168) R^(D222) L_(C853) R^(D17) R^(D223)L_(C961) R^(D50) R^(D223) L_(C1069) R^(D145) R^(D223) L_(C1177) R^(D168)R^(D223) L_(C854) R^(D17) R^(D224) L_(C962) R^(D50) R^(D224) L_(C1070)R^(D145) R^(D224) L_(C1178) R^(D168) R^(D224) L_(C855) R^(D17) R^(D225)L_(C963) R^(D50) R^(D225) L_(C1071) R^(D145) R^(D225) L_(C1179) R^(D168)R^(D225) L_(C856) R^(D17) R^(D226) L_(C964) R^(D50) R^(D226) L_(C1072)R^(D145) R^(D226) L_(C1180) R^(D168) R^(D226) L_(C857) R^(D17) R^(D227)L_(C965) R^(D50) R^(D227) L_(C1073) R^(D145) R^(D227) L_(C1181) R^(D168)R^(D227) L_(C858) R^(D17) R^(D228) L_(C966) R^(D50) R^(D228) L_(C1074)R^(D145) R^(D228) L_(C1182) R^(D168) R^(D228) L_(C859) R^(D17) R^(D229)L_(C967) R^(D50) R^(D229) L_(C1075) R^(D145) R^(D229) L_(C1183) R^(D168)R^(D229) L_(C860) R^(D17) R^(D230) L_(C968) R^(D50) R^(D230) L_(C1076)R^(D145) R^(D230) L_(C1184) R^(D168) R^(D230) L_(C861) R^(D17) R^(D231)L_(C969) R^(D50) R^(D231) L_(C1077) R^(D145) R^(D231) L_(C1185) R^(D168)R^(D231) L_(C862) R^(D17) R^(D232) L_(C970) R^(D50) R^(D232) L_(C1078)R^(D145) R^(D232) L_(C1186) R^(D168) R^(D232) L_(C863) R^(D17) R^(D233)L_(C971) R^(D50) R^(D233) L_(C1079) R^(D145) R^(D233) L_(C1187) R^(D168)R^(D233) L_(C864) R^(D17) R^(D234) L_(C972) R^(D50) R^(D234) L_(C1080)R^(D145) R^(D234) L_(C1188) R^(D168) R^(D234) L_(C865) R^(D17) R^(D235)L_(C973) R^(D50) R^(D235) L_(C1081) R^(D145) R^(D235) L_(C1189) R^(D168)R^(D235) L_(C866) R^(D17) R^(D236) L_(C974) R^(D50) R^(D236) L_(C1082)R^(D145) R^(D236) L_(C1190) R^(D168) R^(D236) L_(C867) R^(D17) R^(D237)L_(C975) R^(D50) R^(D237) L_(C1083) R^(D145) R^(D237) L_(C1191) R^(D168)R^(D237) L_(C868) R^(D17) R^(D238) L_(C976) R^(D50) R^(D238) L_(C1084)R^(D145) R^(D238) L_(C1192) R^(D168) R^(D238) L_(C869) R^(D17) R^(D239)L_(C977) R^(D50) R^(D239) L_(C1085) R^(D145) R^(D239) L_(C1193) R^(D168)R^(D239) L_(C870) R^(D17) R^(D240) L_(C978) R^(D50) R^(D240) L_(C1086)R^(D145) R^(D240) L_(C1194) R^(D168) R^(D240) L_(C871) R^(D17) R^(D241)L_(C979) R^(D50) R^(D241) L_(C1087) R^(D145) R^(D241) L_(C1195) R^(D168)R^(D241) L_(C872) R^(D17) R^(D242) L_(C980) R^(D50) R^(D242) L_(C1088)R^(D145) R^(D242) L_(C1196) R^(D168) R^(D242) L_(C873) R^(D17) R^(D243)L_(C981) R^(D50) R^(D243) L_(C1089) R^(D145) R^(D243) L_(C1197) R^(D168)R^(D243) L_(C874) R^(D17) R^(D244) L_(C982) R^(D50) R^(D244) L_(C1090)R^(D145) R^(D244) L_(C1198) R^(D168) R^(D244) L_(C875) R^(D17) R^(D245)L_(C983) R^(D50) R^(D245) L_(C1091) R^(D145) R^(D245) L_(C1199) R^(D168)R^(D245) L_(C876) R^(D17) R^(D246) L_(C984) R^(D50) R^(D246) L_(C1092)R^(D145) R^(D246) L_(C1200) R^(D168) R^(D246) L_(C1201) R^(D10) R^(D193)L_(C1255) R^(D55) R^(D193) L_(C1309) R^(D37) R^(D193) L_(C1363) R^(D143)R^(D193) L_(C1202) R^(D10) R^(D194) L_(C1256) R^(D55) R^(D194) L_(C1310)R^(D37) R^(D194) L_(C1364) R^(D143) R^(D194) L_(C1203) R^(D10) R^(D195)L_(C1257) R^(D55) R^(D195) L_(C1311) R^(D37) R^(D195) L_(C1365) R^(D143)R^(D195) L_(C1204) R^(D10) R^(D196) L_(C1258) R^(D55) R^(D196) L_(C1312)R^(D37) R^(D196) L_(C1366) R^(D143) R^(D196) L_(C1205) R^(D10) R^(D197)L_(C1259) R^(D55) R^(D197) L_(C1313) R^(D37) R^(D197) L_(C1367) R^(D143)R^(D197) L_(C1206) R^(D10) R^(D198) L_(C1260) R^(D55) R^(D198) L_(C1314)R^(D37) R^(D198) L_(C1368) R^(D143) R^(D198) L_(C1207) R^(D10) R^(D199)L_(C1261) R^(D55) R^(D199) L_(C1315) R^(D37) R^(D199) L_(C1369) R^(D143)R^(D199) L_(C1208) R^(D10) R^(D200) L_(C1262) R^(D55) R^(D200) L_(C1316)R^(D37) R^(D200) L_(C1370) R^(D143) R^(D200) L_(C1209) R^(D10) R^(D201)L_(C1263) R^(D55) R^(D201) L_(C1317) R^(D37) R^(D201) L_(C1371) R^(D143)R^(D201) L_(C1210) R^(D10) R^(D202) L_(C1264) R^(D55) R^(D202) L_(C1318)R^(D37) R^(D202) L_(C1372) R^(D143) R^(D202) L_(C1211) R^(D10) R^(D203)L_(C1265) R^(D55) R^(D203) L_(C1319) R^(D37) R^(D203) L_(C1373) R^(D143)R^(D203) L_(C1212) R^(D10) R^(D204) L_(C1266) R^(D55) R^(D204) L_(C1320)R^(D37) R^(D204) L_(C1374) R^(D143) R^(D204) L_(C1213) R^(D10) R^(D205)L_(C1267) R^(D55) R^(D205) L_(C1321) R^(D37) R^(D205) L_(C1375) R^(D143)R^(D205) L_(C1214) R^(D10) R^(D206) L_(C1268) R^(D55) R^(D206) L_(C1322)R^(D37) R^(D206) L_(C1376) R^(D143) R^(D206) L_(C1215) R^(D10) R^(D207)L_(C1269) R^(D55) R^(D207) L_(C1323) R^(D37) R^(D207) L_(C1377) R^(D143)R^(D207) L_(C1216) R^(D10) R^(D208) L_(C1270) R^(D55) R^(D208) L_(C1324)R^(D37) R^(D208) L_(C1378) R^(D143) R^(D208) L_(C1217) R^(D10) R^(D209)L_(C1271) R^(D55) R^(D209) L_(C1325) R^(D37) R^(D209) L_(C1379) R^(D143)R^(D209) L_(C1218) R^(D10) R^(D210) L_(C1272) R^(D55) R^(D210) L_(C1326)R^(D37) R^(D210) L_(C1380) R^(D143) R^(D210) L_(C1219) R^(D10) R^(D211)L_(C1273) R^(D55) R^(D211) L_(C1327) R^(D37) R^(D211) L_(C1381) R^(D143)R^(D211) L_(C1220) R^(D10) R^(D212) L_(C1274) R^(D55) R^(D212) L_(C1328)R^(D37) R^(D212) L_(C1382) R^(D143) R^(D212) L_(C1221) R^(D10) R^(D213)L_(C1275) R^(D55) R^(D213) L_(C1329) R^(D37) R^(D213) L_(C1383) R^(D143)R^(D213) L_(C1222) R^(D10) R^(D214) L_(C1276) R^(D55) R^(D214) L_(C1330)R^(D37) R^(D214) L_(C1384) R^(D143) R^(D214) L_(C1223) R^(D10) R^(D215)L_(C1277) R^(D55) R^(D215) L_(C1331) R^(D37) R^(D215) L_(C1385) R^(D143)R^(D215) L_(C1224) R^(D10) R^(D216) L_(C1278) R^(D55) R^(D216) L_(C1332)R^(D37) R^(D216) L_(C1386) R^(D143) R^(D216) L_(C1225) R^(D10) R^(D217)L_(C1279) R^(D55) R^(D217) L_(C1333) R^(D37) R^(D217) L_(C1387) R^(D143)R^(D217) L_(C1226) R^(D10) R^(D218) L_(C1280) R^(D55) R^(D218) L_(C1334)R^(D37) R^(D218) L_(C1388) R^(D143) R^(D218) L_(C1227) R^(D10) R^(D219)L_(C1281) R^(D55) R^(D219) L_(C1335) R^(D37) R^(D219) L_(C1389) R^(D143)R^(D219) L_(C1228) R^(D10) R^(D220) L_(C1282) R^(D55) R^(D220) L_(C1336)R^(D37) R^(D220) L_(C1390) R^(D143) R^(D220) L_(C1229) R^(D10) R^(D221)L_(C1283) R^(D55) R^(D221) L_(C1337) R^(D37) R^(D221) L_(C1391) R^(D143)R^(D221) L_(C1230) R^(D10) R^(D222) L_(C1284) R^(D55) R^(D222) L_(C1338)R^(D37) R^(D222) L_(C1392) R^(D143) R^(D222) L_(C1231) R^(D10) R^(D223)L_(C1285) R^(D55) R^(D223) L_(C1339) R^(D37) R^(D223) L_(C1393) R^(D143)R^(D223) L_(C1232) R^(D10) R^(D224) L_(C1286) R^(D55) R^(D224) L_(C1340)R^(D37) R^(D224) L_(C1394) R^(D143) R^(D224) L_(C1233) R^(D10) R^(D225)L_(C1287) R^(D55) R^(D225) L_(C1341) R^(D37) R^(D225) L_(C1395) R^(D143)R^(D225) L_(C1234) R^(D10) R^(D226) L_(C1288) R^(D55) R^(D226) L_(C1342)R^(D37) R^(D226) L_(C1396) R^(D143) R^(D226) L_(C1235) R^(D10) R^(D227)L_(C1289) R^(D55) R^(D227) L_(C1343) R^(D37) R^(D227) L_(C1397) R^(D143)R^(D227) L_(C1236) R^(D10) R^(D228) L_(C1290) R^(D55) R^(D228) L_(C1344)R^(D37) R^(D228) L_(C1398) R^(D143) R^(D228) L_(C1237) R^(D10) R^(D229)L_(C1291) R^(D55) R^(D229) L_(C1345) R^(D37) R^(D229) L_(C1399) R^(D143)R^(D229) L_(C1238) R^(D10) R^(D230) L_(C1292) R^(D55) R^(D230) L_(C1346)R^(D37) R^(D230) L_(C1400) R^(D143) R^(D230) L_(C1239) R^(D10) R^(D231)L_(C1293) R^(D55) R^(D231) L_(C1347) R^(D37) R^(D231) L_(C1401) R^(D143)R^(D231) L_(C1240) R^(D10) R^(D232) L_(C1294) R^(D55) R^(D232) L_(C1348)R^(D37) R^(D232) L_(C1402) R^(D143) R^(D232) L_(C1241) R^(D10) R^(D233)L_(C1295) R^(D55) R^(D233) L_(C1349) R^(D37) R^(D233) L_(C1403) R^(D143)R^(D233) L_(C1242) R^(D10) R^(D234) L_(C1296) R^(D55) R^(D234) L_(C1350)R^(D37) R^(D234) L_(C1404) R^(D143) R^(D234) L_(C1243) R^(D10) R^(D235)L_(C1297) R^(D55) R^(D235) L_(C1351) R^(D37) R^(D235) L_(C1405) R^(D143)R^(D235) L_(C1244) R^(D10) R^(D236) L_(C1298) R^(D55) R^(D236) L_(C1352)R^(D37) R^(D236) L_(C1406) R^(D143) R^(D236) L_(C1245) R^(D10) R^(D237)L_(C1299) R^(D55) R^(D237) L_(C1353) R^(D37) R^(D237) L_(C1407) R^(D143)R^(D237) L_(C1246) R^(D10) R^(D238) L_(C1300) R^(D55) R^(D238) L_(C1354)R^(D37) R^(D238) L_(C1408) R^(D143) R^(D238) L_(C1247) R^(D10) R^(D239)L_(C1301) R^(D55) R^(D239) L_(C1355) R^(D37) R^(D239) L_(C1409) R^(D143)R^(D239) L_(C1248) R^(D10) R^(D240) L_(C1302) R^(D55) R^(D240) L_(C1356)R^(D37) R^(D240) L_(C1410) R^(D143) R^(D240) L_(C1249) R^(D10) R^(D241)L_(C1303) R^(D55) R^(D241) L_(C1357) R^(D37) R^(D241) L_(C1411) R^(D143)R^(D241) L_(C1250) R^(D10) R^(D242) L_(C1304) R^(D55) R^(D242) L_(C1358)R^(D37) R^(D242) L_(C1412) R^(D143) R^(D242) L_(C1251) R^(D10) R^(D243)L_(C1305) R^(D55) R^(D243) L_(C1359) R^(D37) R^(D243) L_(C1413) R^(D143)R^(D243) L_(C1252) R^(D10) R^(D244) L_(C1306) R^(D55) R^(D244) L_(C1360)R^(D37) R^(D244) L_(C1414) R^(D143) R^(D244) L_(C1253) R^(D10) R^(D245)L_(C1307) R^(D55) R^(D245) L_(C1361) R^(D37) R^(D245) L_(C1415) R^(D143)R^(D245) L_(C1254) R^(D10) R^(D246) L_(C1308) R^(D55) R^(D246) L_(C1362)R^(D37) R^(D246) L_(C1416) R^(D143) R^(D246)

wherein R^(D1) to R^(D246) have the following structures:


15. The compound of claim 14, wherein the compound is selected from thegroup consisting of the following structures:

wherein R^(M), R^(N), and R^(Y) are each independently H, D, F, alkyl,cycloalkyl, aryl, heteroaryl, or combinations thereof.
 16. The compoundof claim 1, wherein the compound is selected from the group consistingof the following structures:


17. An organic light emitting device (OLED) comprising: an anode; acathode; and an organic layer disposed between the anode and thecathode, wherein the organic layer comprises an Ir compound comprising aligand L_(A) of

wherein: X¹-X¹⁰ are each independently CR′ or N; the maximum number of Natoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl,acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl,sulfinyl, sulfonyl, phosphino, and combinations thereof; at least twoadjacent R′ are joined to form a fused 5-membered heterocyclic ring; andadditional substituents can be joined or fused to form a ring, whereinIr is coordinated to the ligand L_(A) of Formula I by the two dashlines, and can be coordinated to additional ligands; and wherein theligand L_(A) can be joined with additional ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.
 18. The OLED of claim17, wherein the organic layer further comprises a host, wherein hostcomprises at least one chemical moiety selected from the groupconsisting of triphenylene, carbazole, indolocarbazole, dibenzothiphene,dibenzofuran, dibenzoselenophene,5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene, aza-triphenylene,aza-carbazole, aza-indolocarbazole, aza-dibenzothiophene,aza-dibenzofuran, aza-dibenzoselenophene, andaza-(5,9-dioxa-13b-boranaphtho[3,2,1-de]anthracene).
 19. The OLED ofclaim 18, wherein the host is selected from the group consisting of:

and combinations thereof.
 20. A consumer product comprising an organiclight-emitting device (OLED) comprising: an anode; a cathode; and anorganic layer disposed between the anode and the cathode, wherein theorganic layer comprises an Ir compound comprising a ligand L_(A) of

wherein: X¹-X¹⁰¹ are each independently CR′ or N; the maximum number ofN atoms that can connect to each other within a ring is two; R′ for eachoccurrence is independently a hydrogen or a substituent selected fromthe group consisting of deuterium, halogen, alkyl, cycloalkyl,heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl,boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl,acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl,sulfinyl, sulfonyl, phosphino, and combinations thereof; at least twoadjacent R′ are joined to form a fused 5-membered heterocyclic ring; andadditional substituents can be joined or fused to form a ring, whereinIr is coordinated to the ligand L_(A) of Formula I by the two dashlines, and can be coordinated to additional ligands; and wherein theligand L_(A) can be joined with additional ligands to form a tridentate,tetradentate, pentadentate, or hexadentate ligand.